HESI A2
Chemistry HESI A2 Practice Test
1. What is the correct electron configuration for lithium?
- A. 1s²2s¹
- B. 1s²2s²
- C. 1s²2s¹2p¹
- D. 1s¹2s¹2p²
Correct answer: A
Rationale: The electron configuration for lithium is 1s²2s¹. Lithium has 3 electrons, and the configuration indicates that the first two electrons fill the 1s orbital, while the third electron fills the 2s orbital. Therefore, the correct electron configuration for lithium is 1s²2s¹. Choice B (1s²2s²) is incorrect as it represents the electron configuration for beryllium, not lithium. Choice C (1s²2s¹2p¹) includes the 2p orbital, which is not involved in lithium's electron configuration. Choice D (1s¹2s¹2p²) is incorrect as it does not accurately represent lithium's electron configuration.
2. A chemist takes 100 mL of a 40 g NaCl solution and dilutes it to 1L. What is the concentration (molarity) of the new solution?
- A. 0.04 M NaCl
- B. 0.25 M NaCl
- C. 0.40 M NaCl
- D. 2.5 M NaCl
Correct answer: C
Rationale: Initially, the chemist has 40 g of NaCl in 100 mL of solution. To find the initial molarity, we need to calculate the number of moles of NaCl using the molar mass of NaCl (58.44 g/mol). After dilution to 1 L, the molarity of the new solution can be calculated by dividing the moles of NaCl by the total volume in liters. Therefore, the concentration (molarity) of the new solution is 0.40 M NaCl. Choice A (0.04 M NaCl) is incorrect because it doesn't consider the correct molar concentration after dilution. Choice B (0.25 M NaCl) is incorrect as it also doesn't account for the correct molar concentration post-dilution. Choice D (2.5 M NaCl) is incorrect as it is too concentrated given the initial amount of NaCl and the dilution factor.
3. What type of chemical reaction involves the combination of two elements to form a product?
- A. Decomposition
- B. Combustion
- C. Synthesis
- D. Double replacement
Correct answer: C
Rationale: A synthesis reaction involves the combination of two or more substances to form a single, more complex product. In the context of chemical reactions, it specifically refers to the combination of two elements to form a compound. Therefore, the correct answer is C. Decomposition reactions involve the breakdown of a single compound into simpler substances (opposite of synthesis). Combustion reactions involve a substance reacting with oxygen to produce heat and light, not the combination of elements. Double replacement reactions involve the exchange of ions between two compounds, leading to the formation of two new compounds, not the combination of two elements.
4. What is the oxidation state of the sulfur atom in sulfuric acid H2SO4?
- A. 4
- B. 6
- C. 8
- D. 10
Correct answer: B
Rationale: In sulfuric acid (H2SO4), sulfur has an oxidation state of +6. The oxidation state is determined by considering the overall charge of the compound and the known oxidation states of other elements. In this case, hydrogen is typically +1, and oxygen is -2. To balance the charges and match the compound's overall charge of 0, sulfur must have an oxidation state of +6. Choice A (4) is incorrect because it doesn't balance the charges in the compound. Choices C (8) and D (10) are also incorrect as they are not valid oxidation states for sulfur in this compound.
5. Which element is a metalloid?
- A. Silicon
- B. Lead
- C. Helium
- D. Aluminum
Correct answer: A
Rationale: The correct answer is 'Silicon.' Silicon is a metalloid, which means it has properties of both metals and nonmetals. It is commonly used in electronic devices due to its semiconductor properties. Lead (Choice B) is a metal, Helium (Choice C) is a noble gas, and Aluminum (Choice D) is a metal.
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