HESI A2
HESI A2 Chemistry Practice Test
1. Which of the following is defined as the number of cycles of a wave that move past a fixed observation point per second?
- A. Wave
- B. Wavelength
- C. Frequency
- D. Wavefunction
Correct answer: C
Rationale: Frequency is defined as the number of cycles of a wave that pass a fixed observation point per second. It is a fundamental characteristic of a wave and is measured in Hertz (Hz). The frequency of a wave determines its pitch in the case of sound waves and its color in the case of light waves. Choice A, 'Wave,' is incorrect because a wave refers to the disturbance or oscillation that travels through a medium. Choice B, 'Wavelength,' is incorrect as it represents the distance between two corresponding points on a wave (e.g., crest to crest). Choice D, 'Wavefunction,' is not the correct answer as it is a mathematical function used in quantum mechanics to describe the behavior of particles and systems.
2. One factor that affects rates of reaction is concentration. Which of these statements about concentration is/are correct?
- A. A higher concentration of reactants causes more effective collisions per unit time, leading to an increased reaction rate
- B. A lower concentration of reactants causes fewer effective collisions per unit time, leading to a decreased reaction rate
- C. A higher concentration of reactants causes more effective collisions per unit time, leading to a decreased reaction rate
- D. A higher concentration of reactants causes fewer effective collisions per unit time, leading to an increased reaction rate
Correct answer: A
Rationale: A higher concentration of reactants causes more effective collisions per unit time, leading to an increased reaction rate. This is because a higher concentration means there are more reactant molecules in a given volume, increasing the likelihood of collisions between them. With more collisions occurring, there is a greater chance of successful collisions leading to the formation of products, hence increasing the reaction rate. Choice B is incorrect as a lower concentration decreases the number of collisions, reducing the reaction rate. Choice C is incorrect as a higher concentration increases collision frequency, which typically results in a higher reaction rate. Choice D is incorrect as a higher concentration usually leads to more collisions, thus increasing the reaction rate.
3. What is the oxidation state of the sulfur atom in sulfuric acid H2SO4?
- A. 4
- B. 6
- C. 8
- D. 10
Correct answer: B
Rationale: In sulfuric acid (H2SO4), sulfur has an oxidation state of +6. The oxidation state is determined by considering the overall charge of the compound and the known oxidation states of other elements. In this case, hydrogen is typically +1, and oxygen is -2. To balance the charges and match the compound's overall charge of 0, sulfur must have an oxidation state of +6. Choice A (4) is incorrect because it doesn't balance the charges in the compound. Choices C (8) and D (10) are also incorrect as they are not valid oxidation states for sulfur in this compound.
4. Which of the following statements, if any, are correct?
- A. pH is a measure of the effective concentration of hydrogen ions in a solution and is approximately related to the molarity of H+ by pH = - log [H+]
- B. pH is a measure of the effective concentration of oxygen ions in a solution and is not related to the molarity of O+ by pH = - log [O+]
- C. pH is a measure of the effective concentration of hydrogen atoms in a solution and is not directly related to the polarity of H+ by pH = - log [H+]
- D. Acidity is a measure of the effective concentration of hydrogen ions in a solution and is not directly related to the molarity of H+ by pH = - log [H+]
Correct answer: A
Rationale: Statement A is correct. pH is a measure of the effective concentration of hydrogen ions in a solution, and it is related to the molarity of H+ by the formula pH = - log [H+]. This equation illustrates the logarithmic relationship between pH and the concentration of hydrogen ions. Oxygen ions and hydrogen atoms are not directly related to pH in the same manner as hydrogen ions. Acidity is determined by the concentration of hydrogen ions in a solution, and this concentration is what pH measures. Therefore, option A is the only statement that correctly defines the relationship between pH and the concentration of hydrogen ions in a solution. Choices B, C, and D are incorrect as they provide inaccurate information about the relationship between pH and the ions/atoms mentioned. Option B incorrectly associates pH with oxygen ions, option C mentions hydrogen atoms instead of hydrogen ions, and option D confuses acidity with pH, which is a measure of hydrogen ion concentration, not molarity.
5. What type of bonds involve an especially strong dipole-dipole force between molecules and are responsible for the unique properties of water and pin DNA into its characteristic shape?
- A. Oxygen links
- B. Hydrogen bonds
- C. Dipolar bonds
- D. N/A
Correct answer: B
Rationale: Hydrogen bonds involve an especially strong dipole-dipole force between molecules. These bonds are responsible for the unique properties of water, such as its high surface tension and ability to form droplets. Additionally, hydrogen bonds help hold DNA strands together in its characteristic double helix shape, playing a crucial role in DNA structure and stability. Choice A, 'Oxygen links,' is incorrect as it does not accurately describe the type of bonds involved. Choice C, 'Dipolar bonds,' is also incorrect as it is a generalized term and does not specifically refer to the bonds described in the question. Choice D, 'N/A,' is irrelevant and does not provide an answer to the question.
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