HESI A2
HESI A2 Chemistry Practice Test
1. One factor that affects rates of reaction is concentration. Which of these statements about concentration is/are correct?
- A. A higher concentration of reactants causes more effective collisions per unit time, leading to an increased reaction rate
- B. A lower concentration of reactants causes fewer effective collisions per unit time, leading to a decreased reaction rate
- C. A higher concentration of reactants causes more effective collisions per unit time, leading to a decreased reaction rate
- D. A higher concentration of reactants causes fewer effective collisions per unit time, leading to an increased reaction rate
Correct answer: A
Rationale: A higher concentration of reactants causes more effective collisions per unit time, leading to an increased reaction rate. This is because a higher concentration means there are more reactant molecules in a given volume, increasing the likelihood of collisions between them. With more collisions occurring, there is a greater chance of successful collisions leading to the formation of products, hence increasing the reaction rate. Choice B is incorrect as a lower concentration decreases the number of collisions, reducing the reaction rate. Choice C is incorrect as a higher concentration increases collision frequency, which typically results in a higher reaction rate. Choice D is incorrect as a higher concentration usually leads to more collisions, thus increasing the reaction rate.
2. If oxygen is in a compound, what would its oxidation number be?
- A. 2
- B. -2
- C. 0
- D. -1
Correct answer: B
Rationale: Oxygen typically has an oxidation number of -2 in compounds because it tends to gain electrons. This is due to its high electronegativity, which leads to oxygen attracting electrons towards itself in a chemical bond. Choice A (2) is incorrect because oxygen doesn't have a +2 oxidation number in compounds. Choice C (0) is incorrect as oxygen rarely has an oxidation number of 0 in compounds. Choice D (-1) is incorrect as oxygen's oxidation number in compounds is typically -2, not -1.
3. What is a balanced equation?
- A. A description where reactants and products are not equal
- B. An equation where the number of each type of atom is the same on both sides
- C. A chemical formula showing only reactants
- D. An equation without coefficients
Correct answer: B
Rationale: A balanced equation is one where the number of each type of atom is the same on both sides, fulfilling the law of conservation of mass. This principle ensures that the total number of atoms of each element is equal in both reactants and products, signifying that no atoms are created or destroyed, but rather rearranged. Choice A is incorrect because a balanced equation has equal numbers of atoms in the reactants and products. Choice C is incorrect as a balanced equation includes both reactants and products. Choice D is incorrect because coefficients are essential in balancing equations by adjusting the number of atoms present.
4. Which, if any, of these statements about solubility is correct?
- A. The solubility of a substance is defined as its concentration in a saturated solution
- B. Substances with solubilities much less than 1 g/100 mL of solvent are generally considered insoluble
- C. A saturated solution is one that cannot dissolve any more solute
- D. All of these statements are correct
Correct answer: D
Rationale: A. The solubility of a substance is indeed defined as the concentration of a solute that can be dissolved in a solvent to form a saturated solution at a specific temperature and pressure. B. Substances with solubilities much less than 1 g/100 mL of solvent are generally considered insoluble because they do not dissolve in significant amounts in the solvent. C. A saturated solution is one that cannot dissolve any more solute as it has reached its maximum capacity at a specific temperature and pressure. Therefore, all the statements provided are correct, making option D the correct answer.
5. Which law states that the pressure of an ideal gas is inversely proportional to its volume, given that the temperature and amount of gas remain constant?
- A. Henry's law
- B. Dalton's law
- C. Brown's law
- D. Boyle's law
Correct answer: D
Rationale: Boyle's law describes the relationship between the pressure and volume of an ideal gas when the temperature and amount of gas are constant. According to Boyle's law, if the pressure of a gas increases, its volume decreases proportionally, and vice versa. This law is expressed by the equation P1V1 = P2V2, where P1 and V1 represent the initial pressure and volume, while P2 and V2 represent the final pressure and volume when the temperature and amount of gas remain unchanged. Understanding Boyle's law is essential in comprehending the behavior of gases under varying conditions and is fundamental in the study of thermodynamics. The other choices are incorrect: - Henry's law deals with the solubility of gases in liquids, not the relationship between pressure and volume of gases. - Dalton's law states that the total pressure exerted by a mixture of gases is equal to the sum of the partial pressures of individual gases, not the pressure-volume relationship. - Brown's law is a fabricated concept and does not exist in the context of gas laws.
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