HESI A2
HESI A2 Chemistry Practice Test
1. At what temperature does water boil in °F?
- A. 210°F
- B. 212°F
- C. 215°F
- D. 220°F
Correct answer: B
Rationale: Water boils at 212°F under standard atmospheric pressure. This is the point at which water changes from a liquid to a gas phase. Choice A (210°F) is incorrect as it is below the boiling point of water. Choice C (215°F) and Choice D (220°F) are also incorrect as they are above the boiling point of water.
2. A molecule of water contains hydrogen and oxygen in a 1:8 ratio by mass. This is a statement of _____.
- A. The law of multiple proportions
- B. The law of conservation of mass
- C. The law of conservation of energy
- D. The law of constant composition
Correct answer: D
Rationale: The statement that a molecule of water contains hydrogen and oxygen in a 1:8 ratio by mass is an example of the law of constant composition. This law states that all samples of a given chemical compound have the same elemental composition. In the case of water (H2O), no matter where you obtain a sample of water, it will always be composed of hydrogen and oxygen in a 1:8 ratio by mass. The law of multiple proportions deals with compounds that can be formed by the combination of elements in different ratios. The law of conservation of mass states that mass is neither created nor destroyed in a chemical reaction. The law of conservation of energy states that energy cannot be created or destroyed, only transferred or converted.
3. The volume of a gas is directly proportional to its absolute temperature at constant pressure. This is a statement of:
- A. Combined Gas Law
- B. Boyle's Law
- C. Charles' Law
- D. The Ideal Gas Law
Correct answer: C
Rationale: Charles' Law states that the volume of a gas is directly proportional to its absolute temperature at constant pressure. This means that as the temperature of a gas increases, its volume also increases proportionally, and vice versa. This relationship between temperature and volume is a key feature of Charles' Law. The Combined Gas Law involves the relationships between pressure, volume, and temperature of a gas. Boyle's Law describes the inverse relationship between the pressure and volume of a gas at constant temperature. The Ideal Gas Law combines Boyle's Law, Charles' Law, and Avogadro's Law into a single expression. Therefore, the correct answer is Charles' Law, as it specifically describes the direct relationship between the temperature and volume of a gas.
4. Under which of the following conditions do real gases approach ideal behavior?
- A. At high pressure and high temperature
- B. At low pressure and high temperature
- C. Near the boiling point of water
- D. Real gases can never exhibit ideal behavior
Correct answer: A
Rationale: Real gases approach ideal behavior at high pressure and high temperature. At these conditions, the volume of the gas molecules becomes negligible compared to the total volume of the gas. Additionally, the average distance between molecules becomes small enough for intermolecular forces to become less significant, leading to behavior that closely mirrors the assumptions of the ideal gas law. Choice B is incorrect because low pressure does not favor ideal behavior as the volume of gas molecules becomes more significant. Choice C is incorrect as the boiling point of water does not directly relate to ideal gas behavior. Choice D is incorrect because real gases can approach ideal behavior under specific conditions, such as high pressure and high temperature.
5. Which law is expressed by the equation: Ptot = Pa + Pb, where P represents pressure, Ptot is the total pressure, and Pa and Pb are component pressures?
- A. Henry's law
- B. Dalton's law
- C. Boyle's law
- D. Gay-Lussac's law
Correct answer: B
Rationale: The correct answer is B, Dalton's law. Dalton's law states that in a mixture of non-reacting gases, the total pressure is equal to the sum of the partial pressures of the individual gases. The equation Ptot = Pa + Pb represents Dalton's law, where Ptot is the total pressure, and Pa and Pb are the component pressures. Choice A, Henry's law, deals with the solubility of gases in liquids. Choice C, Boyle's law, describes the inverse relationship between the pressure and volume of a gas at constant temperature. Choice D, Gay-Lussac's law, states that the pressure of a gas is directly proportional to its absolute temperature when volume is constant.
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