HESI A2
HESI A2 Chemistry Practice Test
1. Which, if any, of these statements about solubility is correct?
- A. The solubility of a substance is defined as its concentration in a saturated solution
- B. Substances with solubilities much less than 1 g/100 mL of solvent are generally considered insoluble
- C. A saturated solution is one that cannot dissolve any more solute
- D. All of these statements are correct
Correct answer: D
Rationale: A. The solubility of a substance is indeed defined as the concentration of a solute that can be dissolved in a solvent to form a saturated solution at a specific temperature and pressure. B. Substances with solubilities much less than 1 g/100 mL of solvent are generally considered insoluble because they do not dissolve in significant amounts in the solvent. C. A saturated solution is one that cannot dissolve any more solute as it has reached its maximum capacity at a specific temperature and pressure. Therefore, all the statements provided are correct, making option D the correct answer.
2. Which scientific principle predicts that the solubility of a gas or volatile substance in a liquid is proportional to the partial pressure of the substance over the liquid (P = kC)?
- A. Boyle's Law
- B. Gay-Lussac's Law
- C. Henry's Law
- D. Charles' Law
Correct answer: C
Rationale: Henry's Law states that the solubility of a gas in a liquid is directly proportional to the partial pressure of the gas above the liquid. The equation P = kC represents Henry's Law, where P is the partial pressure of the gas, C is the concentration of the gas in the liquid, and k is a constant. This law is applicable to dilute solutions where the gas does not significantly affect the liquid's volume. Therefore, in the context of gas solubility in liquids, Henry's Law is the appropriate principle that describes the relationship between solubility and partial pressure. Boyle's Law relates the pressure and volume of a gas at constant temperature, Gay-Lussac's Law deals with the pressure and temperature relationship of a gas at constant volume, and Charles' Law describes the relationship between the volume and temperature of a gas at constant pressure. These laws are not directly related to the solubility of gases in liquids, making them incorrect choices for this question.
3. At what temperature does water boil in °F?
- A. 210°F
- B. 212°F
- C. 215°F
- D. 220°F
Correct answer: B
Rationale: Water boils at 212°F under standard atmospheric pressure. This is the point at which water changes from a liquid to a gas phase. Choice A (210°F) is incorrect as it is below the boiling point of water. Choice C (215°F) and Choice D (220°F) are also incorrect as they are above the boiling point of water.
4. Which of the following lists four factors that affect rates of reaction?
- A. Barometric pressure, particle size, concentration, and the presence of a facilitator
- B. Temperature, particle size, concentration, and the presence of a catalyst
- C. Temperature, container material, elevation, and the presence of instability
- D. Volatility, particle size, concentration, and the presence of a catalyst
Correct answer: B
Rationale: The correct answer is B. The factors that influence rates of reaction are temperature, particle size, concentration, and the presence of a catalyst. Temperature affects the speed of molecules, particle size impacts the available surface area for reactions, concentration influences the collision frequency between reactant molecules, and catalysts accelerate reactions by providing an alternative pathway with lower activation energy. Choices A, C, and D are incorrect as they either include irrelevant factors that do not affect reaction rates (barometric pressure, container material, elevation, and volatility) or lack important factors that do influence reaction rates (like a catalyst).
5. What is defined as the distance between adjacent peaks or adjacent troughs on a wave?
- A. Frequency
- B. Wavenumber
- C. Wave oscillation
- D. Wavelength
Correct answer: D
Rationale: Wavelength is correctly defined as the distance between adjacent peaks or adjacent troughs on a wave. It is a crucial characteristic of waves, influencing properties such as color in light waves and pitch in sound waves. By altering the wavelength, significant changes in the wave's perception and attributes can be observed. Choice A, Frequency, refers to the number of occurrences of a repeating event per unit of time and is not related to the distance between peaks or troughs. Choice B, Wavenumber, represents the spatial frequency of a wave in terms of cycles per unit distance, not the distance between adjacent peaks. Choice C, Wave oscillation, does not specifically define the distance between adjacent peaks or troughs but rather the movement of a wave back and forth.
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