HESI A2
HESI A2 Chemistry Practice Test
1. At what temperature does water boil in °F?
- A. 210°F
- B. 212°F
- C. 215°F
- D. 220°F
Correct answer: B
Rationale: Water boils at 212°F under standard atmospheric pressure. This is the point at which water changes from a liquid to a gas phase. Choice A (210°F) is incorrect as it is below the boiling point of water. Choice C (215°F) and Choice D (220°F) are also incorrect as they are above the boiling point of water.
2. When elements with low electronegativity (almost empty outer shells) react with elements with high electronegativity (mostly full outer shells), they tend to transfer electrons from the low electronegative element to the high electronegative element. This transfer results in the formation of what type of bonds?
- A. Hydrogen
- B. Covalent
- C. Ionic
- D. Nuclear
Correct answer: C
Rationale: The correct answer is C: Ionic. When elements with low electronegativity (almost empty outer shells) react with elements with high electronegativity (mostly full outer shells), they tend to transfer electrons from the low electronegative element to the high electronegative element. This transfer results in the formation of ionic bonds, where one element becomes positively charged (cation) and the other element becomes negatively charged (anion). Ionic bonds are formed through the attraction between these opposite charges, leading to a strong bond between the two elements. Choice A, Hydrogen, is incorrect because hydrogen is not involved in the described electron transfer process to form ionic bonds. Choice B, Covalent, is incorrect because covalent bonds involve the sharing of electrons between atoms, not the transfer of electrons as seen in the formation of ionic bonds. Choice D, Nuclear, is incorrect as nuclear bonds are not a recognized type of chemical bond. Therefore, the most appropriate answer is C: Ionic bonds.
3. What is a mathematical function that gives the amplitude of a wave as a function of position (and sometimes, as a function of time and/or electron spin)?
- A. Wavelength
- B. Frequency
- C. Wavenumber
- D. Wavefunction
Correct answer: D
Rationale: The correct answer is D, Wavefunction. The wavefunction is a mathematical function that gives the amplitude of a wave as a function of position (and sometimes, as a function of time and/or electron spin). It is commonly used in quantum mechanics to describe the behavior of particles, particularly electrons, in atomic and molecular systems. The wavefunction provides information about the probability of finding a particle in a particular state or position. Wavelength (Choice A), Frequency (Choice B), and Wavenumber (Choice C) are properties of waves, but they do not directly represent the mathematical function that describes the wave's behavior as the wavefunction does.
4. Under which of the following conditions do real gases approach ideal behavior?
- A. At high pressure and high temperature
- B. At low pressure and high temperature
- C. Near the boiling point of water
- D. Real gases can never exhibit ideal behavior
Correct answer: A
Rationale: Real gases approach ideal behavior at high pressure and high temperature. At these conditions, the volume of the gas molecules becomes negligible compared to the total volume of the gas. Additionally, the average distance between molecules becomes small enough for intermolecular forces to become less significant, leading to behavior that closely mirrors the assumptions of the ideal gas law. Choice B is incorrect because low pressure does not favor ideal behavior as the volume of gas molecules becomes more significant. Choice C is incorrect as the boiling point of water does not directly relate to ideal gas behavior. Choice D is incorrect because real gases can approach ideal behavior under specific conditions, such as high pressure and high temperature.
5. Which of the following lists four factors that affect rates of reaction?
- A. Barometric pressure, particle size, concentration, and the presence of a facilitator
- B. Temperature, particle size, concentration, and the presence of a catalyst
- C. Temperature, container material, elevation, and the presence of instability
- D. Volatility, particle size, concentration, and the presence of a catalyst
Correct answer: B
Rationale: The correct answer is B. The factors that influence rates of reaction are temperature, particle size, concentration, and the presence of a catalyst. Temperature affects the speed of molecules, particle size impacts the available surface area for reactions, concentration influences the collision frequency between reactant molecules, and catalysts accelerate reactions by providing an alternative pathway with lower activation energy. Choices A, C, and D are incorrect as they either include irrelevant factors that do not affect reaction rates (barometric pressure, container material, elevation, and volatility) or lack important factors that do influence reaction rates (like a catalyst).
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