HESI A2
HESI A2 Chemistry Practice Test
1. Which, if any, of these statements about solubility is correct?
- A. The solubility of a substance is defined as its concentration in a saturated solution
- B. Substances with solubilities much less than 1 g/100 mL of solvent are generally considered insoluble
- C. A saturated solution is one that cannot dissolve any more solute
- D. All of these statements are correct
Correct answer: D
Rationale: A. The solubility of a substance is indeed defined as the concentration of a solute that can be dissolved in a solvent to form a saturated solution at a specific temperature and pressure. B. Substances with solubilities much less than 1 g/100 mL of solvent are generally considered insoluble because they do not dissolve in significant amounts in the solvent. C. A saturated solution is one that cannot dissolve any more solute as it has reached its maximum capacity at a specific temperature and pressure. Therefore, all the statements provided are correct, making option D the correct answer.
2. What is the oxidation state of the sulfur atom in sulfuric acid H2SO4?
- A. 4
- B. 6
- C. 8
- D. 10
Correct answer: B
Rationale: In sulfuric acid (H2SO4), sulfur has an oxidation state of +6. The oxidation state is determined by considering the overall charge of the compound and the known oxidation states of other elements. In this case, hydrogen is typically +1, and oxygen is -2. To balance the charges and match the compound's overall charge of 0, sulfur must have an oxidation state of +6. Choice A (4) is incorrect because it doesn't balance the charges in the compound. Choices C (8) and D (10) are also incorrect as they are not valid oxidation states for sulfur in this compound.
3. What type of bonds involve an especially strong dipole-dipole force between molecules and are responsible for the unique properties of water and pin DNA into its characteristic shape?
- A. Oxygen links
- B. Hydrogen bonds
- C. Dipolar bonds
- D. N/A
Correct answer: B
Rationale: Hydrogen bonds involve an especially strong dipole-dipole force between molecules. These bonds are responsible for the unique properties of water, such as its high surface tension and ability to form droplets. Additionally, hydrogen bonds help hold DNA strands together in its characteristic double helix shape, playing a crucial role in DNA structure and stability. Choice A, 'Oxygen links,' is incorrect as it does not accurately describe the type of bonds involved. Choice C, 'Dipolar bonds,' is also incorrect as it is a generalized term and does not specifically refer to the bonds described in the question. Choice D, 'N/A,' is irrelevant and does not provide an answer to the question.
4. The volume of a gas is directly proportional to its absolute temperature at constant pressure. This is a statement of:
- A. Combined Gas Law
- B. Boyle's Law
- C. Charles' Law
- D. The Ideal Gas Law
Correct answer: C
Rationale: Charles' Law states that the volume of a gas is directly proportional to its absolute temperature at constant pressure. This means that as the temperature of a gas increases, its volume also increases proportionally, and vice versa. This relationship between temperature and volume is a key feature of Charles' Law. The Combined Gas Law involves the relationships between pressure, volume, and temperature of a gas. Boyle's Law describes the inverse relationship between the pressure and volume of a gas at constant temperature. The Ideal Gas Law combines Boyle's Law, Charles' Law, and Avogadro's Law into a single expression. Therefore, the correct answer is Charles' Law, as it specifically describes the direct relationship between the temperature and volume of a gas.
5. What is a mathematical function that gives the amplitude of a wave as a function of position (and sometimes, as a function of time and/or electron spin)?
- A. Wavelength
- B. Frequency
- C. Wavenumber
- D. Wavefunction
Correct answer: D
Rationale: The correct answer is D, Wavefunction. The wavefunction is a mathematical function that gives the amplitude of a wave as a function of position (and sometimes, as a function of time and/or electron spin). It is commonly used in quantum mechanics to describe the behavior of particles, particularly electrons, in atomic and molecular systems. The wavefunction provides information about the probability of finding a particle in a particular state or position. Wavelength (Choice A), Frequency (Choice B), and Wavenumber (Choice C) are properties of waves, but they do not directly represent the mathematical function that describes the wave's behavior as the wavefunction does.
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