HESI A2
HESI A2 Chemistry Practice Test
1. Which scientific principle predicts that the solubility of a gas or volatile substance in a liquid is proportional to the partial pressure of the substance over the liquid (P = kC)?
- A. Boyle's Law
- B. Gay-Lussac's Law
- C. Henry's Law
- D. Charles' Law
Correct answer: C
Rationale: Henry's Law states that the solubility of a gas in a liquid is directly proportional to the partial pressure of the gas above the liquid. The equation P = kC represents Henry's Law, where P is the partial pressure of the gas, C is the concentration of the gas in the liquid, and k is a constant. This law is applicable to dilute solutions where the gas does not significantly affect the liquid's volume. Therefore, in the context of gas solubility in liquids, Henry's Law is the appropriate principle that describes the relationship between solubility and partial pressure. Boyle's Law relates the pressure and volume of a gas at constant temperature, Gay-Lussac's Law deals with the pressure and temperature relationship of a gas at constant volume, and Charles' Law describes the relationship between the volume and temperature of a gas at constant pressure. These laws are not directly related to the solubility of gases in liquids, making them incorrect choices for this question.
2. Which law is expressed by the equation: Ptot = Pa + Pb, where P represents pressure, Ptot is the total pressure, and Pa and Pb are component pressures?
- A. Henry's law
- B. Dalton's law
- C. Boyle's law
- D. Gay-Lussac's law
Correct answer: B
Rationale: The correct answer is B, Dalton's law. Dalton's law states that in a mixture of non-reacting gases, the total pressure is equal to the sum of the partial pressures of the individual gases. The equation Ptot = Pa + Pb represents Dalton's law, where Ptot is the total pressure, and Pa and Pb are the component pressures. Choice A, Henry's law, deals with the solubility of gases in liquids. Choice C, Boyle's law, describes the inverse relationship between the pressure and volume of a gas at constant temperature. Choice D, Gay-Lussac's law, states that the pressure of a gas is directly proportional to its absolute temperature when volume is constant.
3. What is defined as the distance between adjacent peaks or adjacent troughs on a wave?
- A. Frequency
- B. Wavenumber
- C. Wave oscillation
- D. Wavelength
Correct answer: D
Rationale: Wavelength is correctly defined as the distance between adjacent peaks or adjacent troughs on a wave. It is a crucial characteristic of waves, influencing properties such as color in light waves and pitch in sound waves. By altering the wavelength, significant changes in the wave's perception and attributes can be observed. Choice A, Frequency, refers to the number of occurrences of a repeating event per unit of time and is not related to the distance between peaks or troughs. Choice B, Wavenumber, represents the spatial frequency of a wave in terms of cycles per unit distance, not the distance between adjacent peaks. Choice C, Wave oscillation, does not specifically define the distance between adjacent peaks or troughs but rather the movement of a wave back and forth.
4. What is the spontaneous, random movement of small particles suspended in a liquid, caused by the unbalanced impacts of molecules on the particle?
- A. Brownian motion
- B. Grey's kinesis
- C. Boyle's wave
- D. None of the above
Correct answer: A
Rationale: Brownian motion is the correct choice as it specifically refers to the spontaneous, random movement of small particles suspended in a liquid, caused by the unbalanced impacts of molecules on the particle. This phenomenon was observed and documented by Robert Brown, leading to the discovery of the existence of molecules. Grey's kinesis and Boyle's wave are not scientifically recognized terms related to this concept.
5. One factor that affects rates of reaction is concentration. Which of these statements about concentration is/are correct?
- A. A higher concentration of reactants causes more effective collisions per unit time, leading to an increased reaction rate
- B. A lower concentration of reactants causes fewer effective collisions per unit time, leading to a decreased reaction rate
- C. A higher concentration of reactants causes more effective collisions per unit time, leading to a decreased reaction rate
- D. A higher concentration of reactants causes fewer effective collisions per unit time, leading to an increased reaction rate
Correct answer: A
Rationale: A higher concentration of reactants causes more effective collisions per unit time, leading to an increased reaction rate. This is because a higher concentration means there are more reactant molecules in a given volume, increasing the likelihood of collisions between them. With more collisions occurring, there is a greater chance of successful collisions leading to the formation of products, hence increasing the reaction rate. Choice B is incorrect as a lower concentration decreases the number of collisions, reducing the reaction rate. Choice C is incorrect as a higher concentration increases collision frequency, which typically results in a higher reaction rate. Choice D is incorrect as a higher concentration usually leads to more collisions, thus increasing the reaction rate.
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