HESI A2
Chemistry Hesi A2
1. What is the oxidation state of the nitrogen atom in the compound NH3?
- A. -3
- B. -1
- C. +1
- D. +3
Correct answer: B
Rationale: In the compound NH3, nitrogen is bonded to three hydrogen atoms. Hydrogen is always assigned an oxidation state of +1. Since the overall charge of NH3 is zero, the oxidation state of nitrogen must be -1 to balance out the hydrogen's +1 oxidation state. Therefore, the correct oxidation state of the nitrogen atom in NH3 is -1. Choice A (-3) is incorrect because it does not account for the electronegativity of hydrogen. Choice C (+1) and Choice D (+3) are incorrect as the nitrogen atom in NH3 needs to balance the +1 oxidation state of each hydrogen atom, resulting in a total of -3 to maintain the compound's charge neutrality.
2. Why does fluorine have a higher ionization energy than oxygen?
- A. Fluorine has a smaller number of neutrons.
- B. Fluorine has a larger number of neutrons.
- C. Fluorine has a smaller nuclear charge.
- D. Fluorine has a larger nuclear charge.
Correct answer: D
Rationale: Fluorine has a higher ionization energy than oxygen because fluorine has a larger nuclear charge. The greater number of protons in the nucleus of fluorine attracts its electrons more strongly, making it harder to remove an electron from a fluorine atom compared to an oxygen atom. Choice A is incorrect as the number of neutrons does not directly affect ionization energy. Choice B is also incorrect for the same reason. Choice C is incorrect because a smaller nuclear charge would result in lower ionization energy, not higher.
3. The molar mass of some gases is as follows: carbon monoxide—28.01 g/mol; helium—4.00 g/mol; nitrogen—28.01 g/mol; and oxygen—32.00 g/mol. Which would you expect to diffuse most rapidly?
- A. Carbon monoxide
- B. Helium
- C. Nitrogen
- D. Oxygen
Correct answer: B
Rationale: The rate of diffusion is inversely proportional to the molar mass of the gas. Helium has the lowest molar mass among the given gases, making it the lightest and fastest gas to diffuse. Therefore, helium would be expected to diffuse most rapidly compared to carbon monoxide, nitrogen, and oxygen. Carbon monoxide, nitrogen, and oxygen have higher molar masses than helium, so they would diffuse more slowly. Therefore, the correct answer is helium.
4. Which substance shows a decrease in solubility in water with an increase in temperature?
- A. NaCl
- B. O
- C. KI
- D. CaCl
Correct answer: C
Rationale: Potassium iodide (KI) shows a decrease in solubility in water with an increase in temperature. This is due to the dissolution of KI in water being an endothermic process. When the temperature rises, the equilibrium shifts toward the solid state, leading to a decrease in solubility. Therefore, as the temperature increases, KI becomes less soluble in water. Choice A (NaCl) and Choice D (CaCl) do not exhibit a decrease in solubility with an increase in temperature. NaCl and CaCl are generally more soluble in water at higher temperatures. Choice B (Oxygen) is a gas and not typically considered in solubility discussions involving solids or liquids dissolving in water.
5. What is the correct name of MgO?
- A. Manganese oxide
- B. Magnesium oxide
- C. Magnesium oxate
- D. Magnesium hydroxide
Correct answer: B
Rationale: The correct name of MgO is Magnesium oxide. Mg represents the chemical symbol for magnesium, and O represents the chemical symbol for oxygen. When these elements combine, they form magnesium oxide. Option A, Manganese oxide, is incorrect as it refers to a compound of manganese and oxygen, not magnesium. Option C, Magnesium oxate, is not a valid chemical compound name. Option D, Magnesium hydroxide, refers to a different compound consisting of magnesium, oxygen, and hydrogen.
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