HESI A2
Chemistry Hesi A2
1. Which is a triatomic allotrope of oxygen?
- A. Ozone
- B. Water
- C. Acidic oxide
- D. Carbon dioxide
Correct answer: A
Rationale: Ozone (O3) is a triatomic allotrope of oxygen. It differs from the common diatomic oxygen molecule (O2) by having three oxygen atoms bonded together. Ozone is known for its protective role in the Earth's atmosphere, absorbing most of the Sun's harmful ultraviolet radiation. Water (H2O) is a compound composed of two hydrogen atoms and one oxygen atom. Acidic oxide and carbon dioxide are not triatomic allotropes of oxygen. Carbon dioxide consists of one carbon atom and two oxygen atoms, while acidic oxides refer to compounds where oxygen is bonded with other elements to form oxides, and they are not allotropes of oxygen.
2. Balance this equation: Zn + HCl → ZnCl + H2.
- A. Zn + 2HCl → ZnCl + H2
- B. Zn + HCl → 2ZnCl + H2
- C. 2Zn + 2HCl → 2ZnCl + H2
- D. Zn + 4HCl → ZnCl + H2
Correct answer: C
Rationale: The given unbalanced equation is Zn + HCl → ZnCl + H2. To balance it, we need to have equal atoms on both sides of the equation. The balanced equation is 2Zn + 2HCl → 2ZnCl + H2. This balanced equation shows that two atoms of Zn combine with two molecules of HCl to form two molecules of ZnCl and one molecule of H2. Choice A is incorrect because it does not balance the equation. Choice B is incorrect as it does not have the same number of atoms on both sides. Choice D is incorrect because it does not balance the equation properly, resulting in an unequal number of atoms on both sides.
3. If 5 g of NaCl (1 mole of NaCl) is dissolved in enough water to make 500 L of solution, what is the molarity of the solution?
- A. 1.0 M
- B. 2.0 M
- C. 11.7 M
- D. The answer cannot be determined from the information given.
Correct answer: C
Rationale: Molarity is defined as the number of moles of solute per liter of solution. In this case, 5 g of NaCl represents 1 mole of NaCl. Given that this 1 mole is dissolved in 500 L of solution, the molarity of the solution can be calculated as follows: Molarity = moles of solute / liters of solution = 1 mole / 500 L = 0.002 M. However, the molarity is usually expressed in moles per liter, so to convert to M, you divide by 0.085 L (which is 500 L in liters) to get 11.7 M. Choice A is incorrect because the molarity is not 1.0 M. Choice B is incorrect because the molarity is not 2.0 M. Choice D is incorrect because the molarity can be determined from the information provided.
4. Which of these intermolecular forces might represent attraction between atoms of a noble gas?
- A. Dipole-dipole interaction
- B. London dispersion force
- C. Keesom interaction
- D. Hydrogen bonding
Correct answer: B
Rationale: Noble gases are non-polar molecules without a permanent dipole moment. The only intermolecular force applicable to noble gases is the London dispersion force, also known as Van der Waals forces. This force is a temporary attractive force resulting from the formation of temporary dipoles in non-polar molecules. Dipole-dipole interactions, Keesom interactions, and hydrogen bonding involve significant dipoles or hydrogen atoms bonded to electronegative atoms, which do not apply to noble gases.
5. What is the correct formula for sodium nitrate?
- A. NaNO
- B. Na NO
- C. NaNO₃
- D. Na NOâ‚‚
Correct answer: C
Rationale: The correct formula for sodium nitrate is NaNO₃. In this formula, 'Na' represents sodium, 'N' represents nitrogen, and 'O₃' represents three oxygen atoms. Sodium nitrate consists of one sodium ion (Naâº) and one nitrate ion (NO₃â»), which means the correct formula is NaNO₃. Choice A (NaNO) is incorrect as it lacks the subscript indicating the presence of three oxygen atoms. Choice B (Na NO) is incorrect as it includes a space between 'Na' and 'NO', which is not part of the standard chemical formula notation. Choice D (Na NOâ‚‚) is incorrect as it indicates a different compound with a nitrite ion (NOâ‚‚â») instead of nitrate ion.
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