HESI A2
Chemistry HESI A2 Practice Test
1. Which is a property of an ionic compound?
- A. Low melting point
- B. Poor conductivity
- C. Shared electrons
- D. Crystalline shape
Correct answer: D
Rationale: Ionic compounds are composed of positively and negatively charged ions that are held together by strong electrostatic forces. These ions arrange themselves in a repeating pattern to form a stable and orderly structure known as a crystalline shape. This is a characteristic property of ionic compounds, making choice D the correct answer. Choices A, B, and C are incorrect because ionic compounds typically have high melting points, good conductivity in the molten or dissolved state, and do not involve shared electrons but rather the transfer of electrons between atoms.
2. Which substance shows a decrease in solubility in water with an increase in temperature?
- A. NaCl
- B. O
- C. KI
- D. CaCl
Correct answer: C
Rationale: Potassium iodide (KI) shows a decrease in solubility in water with an increase in temperature. This is due to the dissolution of KI in water being an endothermic process. When the temperature rises, the equilibrium shifts toward the solid state, leading to a decrease in solubility. Therefore, as the temperature increases, KI becomes less soluble in water. Choice A (NaCl) and Choice D (CaCl) do not exhibit a decrease in solubility with an increase in temperature. NaCl and CaCl are generally more soluble in water at higher temperatures. Choice B (Oxygen) is a gas and not typically considered in solubility discussions involving solids or liquids dissolving in water.
3. Which type of change occurs when no change is made to the chemical composition of a substance?
- A. Chemical
- B. Physical
- C. Nuclear
- D. Mechanical
Correct answer: B
Rationale: A physical change refers to alterations in the state of matter without modifying the chemical composition of the substance. Examples of physical changes include changes in state (solid, liquid, gas), shape, size, or phase. In a physical change, the substance may look different or behave differently, but its chemical structure remains the same. On the other hand, chemical changes involve the breaking and forming of chemical bonds, resulting in the creation of entirely new substances with different chemical properties. Nuclear changes involve alterations in the nucleus of an atom, such as radioactive decay. Mechanical changes refer to changes in the position or motion of an object caused by applied forces, like pushing, pulling, or twisting.
4. Which of the following compounds is ionic?
- A. NaCl
- B. Hâ‚‚O
- C. HCl
- D. NH₃
Correct answer: A
Rationale: The correct answer is NaCl (sodium chloride). Ionic compounds are formed by the transfer of electrons between a metal and a nonmetal. In NaCl, sodium (Na) is a metal, and chlorine (Cl) is a nonmetal. Sodium donates an electron to chlorine, leading to the formation of the ionic bond between them. This results in the formation of an ionic compound, where positively charged sodium ions are attracted to negatively charged chloride ions, creating a crystal lattice structure. Choices B, C, and D are not ionic compounds. H₂O (water) is a covalent compound formed by the sharing of electrons between two nonmetals (oxygen and hydrogen). HCl (hydrogen chloride) and NH₃ (ammonia) are also covalent compounds involving nonmetals sharing electrons, not transferring them.
5. What is the oxidation state of the oxygen atom in the compound NaOH?
- A. -2
- B. -1
- C. 0
- D. +2
Correct answer: B
Rationale: In the compound NaOH (sodium hydroxide), the oxidation state of the sodium ion (Na) is +1 as it commonly has a +1 charge in ionic compounds. Oxygen (O) typically has an oxidation state of -2 in most compounds. Since the compound is electrically neutral and the overall charge is zero, the sum of the oxidation states of all atoms in the compound must be zero. Therefore, considering that sodium has an oxidation state of +1, the oxygen atom in NaOH must have an oxidation state of -1 to balance the charges and overall neutrality of the compound. Choice A (-2) is incorrect as this is not the oxidation state of oxygen in this compound. Choice C (0) is incorrect as oxygen in NaOH does not have an oxidation state of 0. Choice D (+2) is incorrect as oxygen typically has a negative oxidation state in compounds, not a positive one.
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