HESI A2
HESI A2 Chemistry
1. You contain two odorous gases in vials with porous plugs. Gas A has twice the mass of Gas B. Which observation is most likely?
- A. You will smell Gas A before you smell Gas B.
- B. You will smell Gas B before you smell Gas A.
- C. You will smell Gas A but not Gas B.
- D. You will smell Gas B but not Gas A.
Correct answer: A
Rationale: The rate of effusion of a gas is inversely proportional to the square root of its molar mass. Since Gas A has twice the mass of Gas B, Gas A will effuse more slowly than Gas B. Therefore, you will likely smell Gas A before you smell Gas B as Gas A will escape and diffuse through the porous plug at a slower rate compared to Gas B. Choice A is correct because Gas A, with its higher molar mass, will take longer to effuse through the porous plug, causing you to smell it first. Choices B, C, and D are incorrect as they do not consider the relationship between molar mass and effusion rate.
2. Which compound contains a polar covalent bond?
- A. O
- B. F
- C. Br
- D. H₂O
Correct answer: D
Rationale: The compound 'H₂O' (water) contains a polar covalent bond. In a water molecule, the oxygen atom is more electronegative than the hydrogen atoms. As a result, the electrons in the O-H bonds are unevenly shared, leading to a partial negative charge on the oxygen atom and partial positive charges on the hydrogen atoms. This unequal sharing of electrons creates a polar covalent bond in water. Choices A, B, and C are incorrect because they represent individual elements, not compounds, and do not involve the concept of polar covalent bonds.
3. If fifty-six kilograms of a radioactive substance has a half-life of 12 days, how many days will it take the substance to decay naturally to only 7 kilograms?
- A. 8
- B. 12
- C. 36
- D. 48
Correct answer: C
Rationale: To decay from 56 kg to 7 kg, the substance needs to go through 3 half-lives (56 kg ÷ 2 ÷ 2 ÷ 2 = 7 kg). Since each half-life is 12 days, the total time required is 12 days per half-life x 3 half-lives = 36 days. Choice A is incorrect because it does not consider the concept of half-lives. Choice B is incorrect because it represents the duration of a single half-life, not the total time required for the decay. Choice D is incorrect as it does not account for the multiple half-lives needed for the substance to decay from 56 kg to 7 kg.
4. How many neutrons are in an atom of carbon-12?
- A. 2
- B. 4
- C. 6
- D. 24
Correct answer: C
Rationale: An atom of carbon-12 has 6 neutrons. The atomic number of carbon is 6, representing the number of protons. The atomic mass of carbon-12 is 12. To find the number of neutrons, subtract the atomic number from the atomic mass: 12 - 6 = 6 neutrons. Choice A, 2, is incorrect as it does not reflect the correct calculation for neutrons in carbon-12. Choice B, 4, is incorrect as it does not match the correct number of neutrons in carbon-12. Choice D, 24, is incorrect as it is significantly higher than the actual number of neutrons in carbon-12.
5. What is the energy required to remove the outermost electron from an atom called?
- A. covalent bonding
- B. electronegativity
- C. atomic radius
- D. ionization energy
Correct answer: D
Rationale: Ionization energy is the energy needed to remove the outermost electron from an atom, resulting in the formation of a positively charged ion. The higher the ionization energy, the more difficult it is to extract an electron. Electronegativity, however, measures an atom's ability to attract shared electrons in a chemical bond. Atomic radius refers to the distance from the nucleus to the outermost electron. Covalent bonding involves sharing electron pairs between atoms to create a stable bond. Therefore, the correct answer is ionization energy as it specifically relates to the energy needed to remove an electron from an atom.
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