HESI A2
HESI A2 Chemistry
1. What is 0 K equal to in °C?
- A. -300°C
- B. -273°C
- C. -250°C
- D. -200°C
Correct answer: B
Rationale: 0 Kelvin, also known as absolute zero, is equal to -273°C. This is the point at which all molecular motion stops, making it the lowest possible temperature on the Kelvin scale. Choice A (-300°C) is incorrect as it is not the correct conversion of 0 K to °C. Choice C (-250°C) and Choice D (-200°C) are also incorrect as they do not correspond to the accurate conversion of 0 K to °C.
2. Which compound contains a polar covalent bond?
- A. O
- B. F
- C. Br
- D. H₂O
Correct answer: D
Rationale: The compound 'H₂O' (water) contains a polar covalent bond. In a water molecule, the oxygen atom is more electronegative than the hydrogen atoms. As a result, the electrons in the O-H bonds are unevenly shared, leading to a partial negative charge on the oxygen atom and partial positive charges on the hydrogen atoms. This unequal sharing of electrons creates a polar covalent bond in water. Choices A, B, and C are incorrect because they represent individual elements, not compounds, and do not involve the concept of polar covalent bonds.
3. What is the molarity of a solution containing 45 moles of NaCl in 4 liters?
- A. 0.11 M NaCl
- B. 0.45 M NaCl
- C. 1.8 M NaCl
- D. 8.9 M NaCl
Correct answer: A
Rationale: To calculate the molarity of a solution, you use the formula: Molarity (M) = moles of solute / liters of solution. In this case, M = 45 moles / 4 L = 11.25 M. The correct answer is 0.11 M NaCl. Choice B is incorrect as it doesn't match the calculated value. Choice C is also incorrect as it is significantly higher than the correct molarity. Choice D is incorrect as it is excessively high compared to the calculated value.
4. How many neutrons are in an atom of carbon-12?
- A. 2
- B. 4
- C. 6
- D. 24
Correct answer: C
Rationale: An atom of carbon-12 has 6 neutrons. The atomic number of carbon is 6, representing the number of protons. The atomic mass of carbon-12 is 12. To find the number of neutrons, subtract the atomic number from the atomic mass: 12 - 6 = 6 neutrons. Choice A, 2, is incorrect as it does not reflect the correct calculation for neutrons in carbon-12. Choice B, 4, is incorrect as it does not match the correct number of neutrons in carbon-12. Choice D, 24, is incorrect as it is significantly higher than the actual number of neutrons in carbon-12.
5. How much concentrated HCl should be used to prepare 500 mL of a 0.100 M HCl solution?
- A. 75 mL
- B. 100 mL
- C. 125 mL
- D. 150 mL
Correct answer: B
Rationale: To prepare a 0.100 M HCl solution with a volume of 500 mL, you can use the formula C1V1 = C2V2, where C1 is the concentration of the concentrated HCl solution, V1 is the volume of concentrated HCl solution used, C2 is the desired concentration (0.100 M), and V2 is the final volume (500 mL). Rearranging the formula to solve for V1, you get V1 = (C2V2) / C1. Plugging in the values (0.100 M)(500 mL) / C1 = 100 mL, which means 100 mL of concentrated HCl should be used to prepare 500 mL of a 0.100 M HCl solution. Therefore, the correct answer is 100 mL. Choice A (75 mL), Choice C (125 mL), and Choice D (150 mL) are incorrect as they do not match the calculated volume needed to prepare the desired concentration of HCl solution.
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