HESI A2
HESI A2 Chemistry
1. Which of these intermolecular forces would result in the lowest boiling point?
- A. Dipole-dipole interaction
- B. London dispersion force
- C. Keesom interaction
- D. Hydrogen bonding
Correct answer: B
Rationale: The London dispersion force is the weakest intermolecular force among the options provided. These forces are present in all molecules and are caused by temporary fluctuations in electron density, resulting in temporary dipoles. Since London dispersion forces are generally weaker than dipole-dipole interactions, Keesom interactions, and hydrogen bonding, a substance with London dispersion forces as the primary intermolecular force would have the lowest boiling point due to the weaker intermolecular forces holding the molecules together. Dipole-dipole interactions, Keesom interactions, and hydrogen bonding are stronger intermolecular forces compared to London dispersion forces, resulting in higher boiling points for substances that exhibit these interactions.
2. What is the name of the compound CH₃-CH₂-CH₂-CH₃?
- A. Cyclobutane
- B. Butane
- C. Butene
- D. Butyne
Correct answer: B
Rationale: The compound CH₃-CH₂-CH₂-CH₃ is named butane. Butane is a straight-chain alkane comprising four carbon atoms connected by single bonds. The prefix 'but-' denotes the presence of four carbon atoms, while the suffix '-ane' indicates it is an alkane with single bonds between the carbon atoms. Choice A, Cyclobutane, is incorrect as it refers to a cyclic hydrocarbon with four carbon atoms in a ring structure. Choice C, Butene, is incorrect because it is an alkene with a double bond between two carbon atoms, not a saturated hydrocarbon like butane. Choice D, Butyne, is also incorrect as it is an alkyne with a triple bond between two carbon atoms, unlike the single bonds in butane.
3. Where would you expect tap water to fall on the pH scale?
- A. Between 1 and 3
- B. Between 4 and 6
- C. Between 6 and 8
- D. Between 8 and 10
Correct answer: C
Rationale: Tap water typically falls within the pH range of 6 to 8, making it slightly acidic to neutral. Most municipal water systems aim to provide water that is safe for consumption and falls within this pH range. A pH level of 7 is considered neutral, so tap water may vary slightly on either side of this number but typically remains within the 6 to 8 range to ensure it is safe for consumption. Choices A, B, and D are incorrect because tap water is not expected to have a pH as low as 1-3 (highly acidic) or as high as 8-10 (alkaline); it usually falls within the slightly acidic to neutral range, hence falling between 6 and 8 on the pH scale.
4. What are the 3 types of radiation in nuclear chemistry?
- A. Alpha, Beta, Delta
- B. Alpha, Beta, Gamma
- C. Gamma, Beta, Delta
- D. Delta, Beta, Gamma
Correct answer: B
Rationale: The correct answer is B: Alpha, Beta, Gamma. In nuclear chemistry, the 3 types of radiation are alpha, beta, and gamma radiation. Alpha radiation consists of helium nuclei, beta radiation involves electrons or positrons, and gamma radiation is electromagnetic radiation of high frequency. Choice A is incorrect because 'Delta' is not a type of radiation in nuclear chemistry. Choice C is incorrect as it does not list alpha radiation. Choice D is incorrect as it lists the types in the wrong order and includes 'Delta' instead of alpha radiation.
5. Among the following elements, which is a nonmetal?
- A. Mercury
- B. Magnesium
- C. Sulfur
- D. Potassium
Correct answer: C
Rationale: Sulfur is a nonmetal as it is located on the right side of the periodic table. Nonmetals generally exhibit properties such as being brittle, poor conductors of heat and electricity, and having lower melting points compared to metals. Mercury (A), Magnesium (B), and Potassium (D) are all metals due to their metallic properties. Mercury is a liquid metal at room temperature, Magnesium is a solid metal, and Potassium is a solid metal as well. Therefore, the correct answer is C, Sulfur.
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