HESI A2
HESI A2 Chemistry
1. You contain two odorous gases in vials with porous plugs. Gas A has twice the mass of Gas B. Which observation is most likely?
- A. You will smell Gas A before you smell Gas B.
- B. You will smell Gas B before you smell Gas A.
- C. You will smell Gas A but not Gas B.
- D. You will smell Gas B but not Gas A.
Correct answer: A
Rationale: The rate of effusion of a gas is inversely proportional to the square root of its molar mass. Since Gas A has twice the mass of Gas B, Gas A will effuse more slowly than Gas B. Therefore, you will likely smell Gas A before you smell Gas B as Gas A will escape and diffuse through the porous plug at a slower rate compared to Gas B. Choice A is correct because Gas A, with its higher molar mass, will take longer to effuse through the porous plug, causing you to smell it first. Choices B, C, and D are incorrect as they do not consider the relationship between molar mass and effusion rate.
2. What form of radiation is composed of electrons traveling at around 16,000 km/sec?
- A. Alpha radiation
- B. Beta radiation
- C. Gamma radiation
- D. Delta radiation
Correct answer: B
Rationale: Beta radiation is composed of high-energy electrons (β- particles) or positrons (β+ particles) traveling at considerable speeds. In this case, the electrons traveling at around 16,000 km/sec align with the characteristics of beta radiation, making it the correct choice. Alpha radiation consists of helium nuclei, gamma radiation is electromagnetic radiation of high frequency, and delta radiation is not a recognized form of radiation, making them all incorrect choices.
3. Which of these intermolecular forces would result in the lowest boiling point?
- A. Dipole-dipole interaction
- B. London dispersion force
- C. Keesom interaction
- D. Hydrogen bonding
Correct answer: B
Rationale: The London dispersion force is the weakest intermolecular force among the options provided. These forces are present in all molecules and are caused by temporary fluctuations in electron density, resulting in temporary dipoles. Since London dispersion forces are generally weaker than dipole-dipole interactions, Keesom interactions, and hydrogen bonding, a substance with London dispersion forces as the primary intermolecular force would have the lowest boiling point due to the weaker intermolecular forces holding the molecules together. Dipole-dipole interactions, Keesom interactions, and hydrogen bonding are stronger intermolecular forces compared to London dispersion forces, resulting in higher boiling points for substances that exhibit these interactions.
4. What is the correct electron configuration for magnesium?
- A. 1s² 2s²
- B. 1s² 2s² 2p⁶
- C. 1s² 2s² 2p⁶ 3s²
- D. 1s² 2s² 2p⁶ 3s² 3p¹
Correct answer: C
Rationale: The electron configuration of an element is determined by following the Aufbau principle, which states that electrons fill orbitals starting from the lowest energy level. Magnesium has an atomic number of 12, meaning it has 12 electrons. The electron configuration of magnesium fills the 1s, 2s, 2p, and 3s orbitals to accommodate all 12 electrons. Therefore, the correct electron configuration for magnesium is 1s² 2s² 2p⁶ 3s². Choice A is incorrect as it only includes 4 electrons and stops at the 2s orbital. Choice B is incorrect as it includes 8 electrons and stops at the 2p orbital. Choice D is incorrect as it includes 13 electrons and extends to the 3p orbital, which is beyond the actual electron configuration of magnesium.
5. What are the 3 types of radiation in nuclear chemistry?
- A. Alpha, Beta, Delta
- B. Alpha, Beta, Gamma
- C. Gamma, Beta, Delta
- D. Delta, Beta, Gamma
Correct answer: B
Rationale: The correct answer is B: Alpha, Beta, Gamma. In nuclear chemistry, the 3 types of radiation are alpha, beta, and gamma radiation. Alpha radiation consists of helium nuclei, beta radiation involves electrons or positrons, and gamma radiation is electromagnetic radiation of high frequency. Choice A is incorrect because 'Delta' is not a type of radiation in nuclear chemistry. Choice C is incorrect as it does not list alpha radiation. Choice D is incorrect as it lists the types in the wrong order and includes 'Delta' instead of alpha radiation.
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