HESI A2
HESI A2 Chemistry
1. What is the oxidation state of the oxygen atom in the compound NaOH?
- A. -2
- B. -1
- C. 0
- D. +2
Correct answer: B
Rationale: In the compound NaOH (sodium hydroxide), the oxidation state of the sodium ion (Na) is +1 as it commonly has a +1 charge in ionic compounds. Oxygen (O) typically has an oxidation state of -2 in most compounds. Since the compound is electrically neutral and the overall charge is zero, the sum of the oxidation states of all atoms in the compound must be zero. Therefore, considering that sodium has an oxidation state of +1, the oxygen atom in NaOH must have an oxidation state of -1 to balance the charges and overall neutrality of the compound. Choice A (-2) is incorrect as this is not the oxidation state of oxygen in this compound. Choice C (0) is incorrect as oxygen in NaOH does not have an oxidation state of 0. Choice D (+2) is incorrect as oxygen typically has a negative oxidation state in compounds, not a positive one.
2. What is the correct electron configuration for magnesium?
- A. 1s² 2s²
- B. 1s² 2s² 2p⁶
- C. 1s² 2s² 2p⁶ 3s²
- D. 1s² 2s² 2p⁶ 3s² 3p¹
Correct answer: C
Rationale: The electron configuration of an element is determined by following the Aufbau principle, which states that electrons fill orbitals starting from the lowest energy level. Magnesium has an atomic number of 12, meaning it has 12 electrons. The electron configuration of magnesium fills the 1s, 2s, 2p, and 3s orbitals to accommodate all 12 electrons. Therefore, the correct electron configuration for magnesium is 1s² 2s² 2p⁶ 3s². Choice A is incorrect as it only includes 4 electrons and stops at the 2s orbital. Choice B is incorrect as it includes 8 electrons and stops at the 2p orbital. Choice D is incorrect as it includes 13 electrons and extends to the 3p orbital, which is beyond the actual electron configuration of magnesium.
3. The three important allotropic forms of phosphorus are red, white, and ___________.
- A. green
- B. gray
- C. black
- D. silver
Correct answer: C
Rationale: The three important allotropic forms of phosphorus are red, white, and black. These forms indicate the different physical properties and reactivity of phosphorus under various conditions. Red phosphorus is more stable and less reactive than white phosphorus, while black phosphorus is the least reactive form. Choice C, 'black,' is the correct answer as it completes the sequence of allotropic forms of phosphorus. Choices A, 'green,' B, 'gray,' and D, 'silver,' are incorrect as they do not represent recognized forms of phosphorus.
4. What is the name of the compound CH₃-CH₂-CH₂-CH₃?
- A. Cyclobutane
- B. Butane
- C. Butene
- D. Butyne
Correct answer: B
Rationale: The compound CH₃-CH₂-CH₂-CH₃ is named butane. Butane is a straight-chain alkane comprising four carbon atoms connected by single bonds. The prefix 'but-' denotes the presence of four carbon atoms, while the suffix '-ane' indicates it is an alkane with single bonds between the carbon atoms. Choice A, Cyclobutane, is incorrect as it refers to a cyclic hydrocarbon with four carbon atoms in a ring structure. Choice C, Butene, is incorrect because it is an alkene with a double bond between two carbon atoms, not a saturated hydrocarbon like butane. Choice D, Butyne, is also incorrect as it is an alkyne with a triple bond between two carbon atoms, unlike the single bonds in butane.
5. Among the following elements, which is a nonmetal?
- A. Mercury
- B. Magnesium
- C. Sulfur
- D. Potassium
Correct answer: C
Rationale: Sulfur is a nonmetal as it is located on the right side of the periodic table. Nonmetals generally exhibit properties such as being brittle, poor conductors of heat and electricity, and having lower melting points compared to metals. Mercury (A), Magnesium (B), and Potassium (D) are all metals due to their metallic properties. Mercury is a liquid metal at room temperature, Magnesium is a solid metal, and Potassium is a solid metal as well. Therefore, the correct answer is C, Sulfur.
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