HESI A2
Chemistry HESI A2 Practice Test
1. Which of these types of intermolecular force is the strongest?
- A. Dipole-dipole interaction
- B. London dispersion force
- C. Keesom interaction
- D. Hydrogen bonding
Correct answer: D
Rationale: Hydrogen bonding is the strongest type of intermolecular force among the options provided. It occurs when a hydrogen atom is covalently bonded to a highly electronegative atom (such as nitrogen, oxygen, or fluorine) and forms a strong electrostatic attraction with an unshared pair of electrons on another electronegative atom. This type of bond is stronger than dipole-dipole interactions, London dispersion forces, and Keesom interactions due to the significant electronegativity difference between the hydrogen and the electronegative atom involved in the bond. The presence of hydrogen bonding contributes to unique properties in substances, such as high boiling and melting points, making it a crucial force in various biological and chemical processes.
2. Which of the following factors would not affect rates of reaction?
- A. Temperature
- B. Surface area
- C. Pressure
- D. Time
Correct answer: D
Rationale: Time would not directly affect rates of reaction. The rate of a chemical reaction is determined by factors that affect the frequency of successful collisions between reactant molecules, leading to a reaction. Temperature, surface area, and pressure can influence reaction rates by impacting the kinetic energy of molecules, the exposed surface for collisions, and the concentration of reactants, respectively. However, time, in the context of this question, does not alter the rate of reaction but may affect the extent of the reaction or the amount of product formed over time.
3. What is the correct formula for silver hydroxide?
- A. AgO
- B. AgOH
- C. AgH
- D. AgH₂O
Correct answer: B
Rationale: The correct formula for silver hydroxide is AgOH. Silver hydroxide is formed by the combination of the silver ion (Ag⁺) with the hydroxide ion (OH⁻) to create AgOH. It is essential to note that the hydroxide ion consists of one oxygen and one hydrogen atom, thus the formula AgOH. Choices A, C, and D are incorrect as they do not accurately represent the composition of silver hydroxide.
4. How many times more acidic is a substance with a pH of 3 compared to a substance with a pH of 5?
- A. 8
- B. 2
- C. 100
- D. 1,000
Correct answer: D
Rationale: The pH scale is logarithmic, indicating that each pH unit change reflects a 10-fold difference in acidity level. Going from pH 5 to pH 3 involves a difference of 2 units, which translates to a 100-fold increase in acidity level (10^2 = 100 for each unit). Therefore, a substance with a pH of 3 is 1,000 times more acidic than a substance with a pH of 5 (100 * 10 = 1,000). Choice A (8) is incorrect as it does not consider the logarithmic nature of the pH scale. Choice B (2) is incorrect because it represents the difference in pH units, not the increase in acidity level. Choice C (100) is incorrect as it miscalculates the increase in acidity level, which is 1,000 times and not 100 times.
5. What is the oxidation state of the chlorine atom in the compound HCl?
- A. +1
- B. -1
- C. +2
- D. -2
Correct answer: B
Rationale: In the compound HCl (hydrochloric acid), the hydrogen atom has an oxidation state of +1 based on the rules of assigning oxidation states. Since the overall compound is neutral, the oxidation state of chlorine must be -1 to balance the charge. Chlorine typically has an oxidation state of -1 in binary compounds with nonmetals, such as HCl. Therefore, the correct answer is -1. Choices A, C, and D are incorrect as the oxidation state of chlorine in HCl is -1, not +1, +2, or -2.
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