HESI A2
Chemistry HESI A2 Practice Test
1. Which two functional groups would you expect an amino acid to contain?
- A. R-NH2 and R-COOH
- B. R-CHO and R-CO-NH
- C. R-OH and R-COOR
- D. R-O-R and R-COOH
Correct answer: A
Rationale: Amino acids are organic compounds that are characterized by the presence of an amino group (NH2) and a carboxylic acid group (COOH) in their chemical structure. These two functional groups, found in option A, are fundamental components of amino acids and play crucial roles in their classification and biological functions. Option B contains an aldehyde group (CHO) and an amide group (CO-NH), which are not characteristic functional groups of amino acids. Option C includes a hydroxyl group (OH) and an ester group (COOR), which are not typically present in amino acids. Option D presents ether (R-O-R) and carboxylic acid (COOH) functional groups, which do not represent the functional groups commonly found in amino acids.
2. Which ion would you expect to dominate in water solutions of bases?
- A. MgCl₂
- B. 2HCl
- C. H⁺
- D. OH⁻
Correct answer: D
Rationale: In water solutions of bases, the dominant ion would be OH⁻ (hydroxide ion). Bases release OH⁻ ions when dissolved in water, increasing the concentration of hydroxide ions and leading to a higher pH. This is in contrast to acids, which release H⁺ ions. Therefore, in water solutions of bases, the presence of OH⁻ ions signifies the basic nature of the solution. Choices A, B, and C are incorrect because MgCl₂ is a salt, 2HCl is a compound consisting of two hydrogen ions and one chloride ion, and H⁺ represents a hydrogen ion typically associated with acids, not bases.
3. What is the pH of acids?
- A. 7.5
- B. < 7
- C. > 7
- D. 7
Correct answer: B
Rationale: The correct answer is B: < 7. Acids have a pH lower than 7, indicating higher acidity. A pH below 7 signifies an acidic solution, with lower values indicating stronger acids. Choice A (7.5) is incorrect as it is greater than 7, which is alkaline. Choice C (> 7) is incorrect as values greater than 7 represent alkaline/basic solutions. Choice D (7) is incorrect because a pH of 7 is neutral, not acidic.
4. Which of these types of intermolecular force is the strongest?
- A. Dipole-dipole interaction
- B. London dispersion force
- C. Keesom interaction
- D. Hydrogen bonding
Correct answer: D
Rationale: Hydrogen bonding is the strongest type of intermolecular force among the options provided. It occurs when a hydrogen atom is covalently bonded to a highly electronegative atom (such as nitrogen, oxygen, or fluorine) and forms a strong electrostatic attraction with an unshared pair of electrons on another electronegative atom. This type of bond is stronger than dipole-dipole interactions, London dispersion forces, and Keesom interactions due to the significant electronegativity difference between the hydrogen and the electronegative atom involved in the bond. The presence of hydrogen bonding contributes to unique properties in substances, such as high boiling and melting points, making it a crucial force in various biological and chemical processes.
5. How many neutrons does carbon-14 have?
- A. 10
- B. 8
- C. 6
- D. 12
Correct answer: B
Rationale: The correct answer is B: 8. Carbon-14 is an isotope of carbon with 6 protons and 8 neutrons. To determine the number of neutrons in an atom, subtract the atomic number (number of protons) from the mass number. In this case, the mass number of carbon-14 is 14, and the atomic number of carbon is 6. Therefore, 14 (mass number) - 6 (atomic number) = 8 neutrons. Choices A, C, and D are incorrect because they do not reflect the correct number of neutrons in a carbon-14 atom.
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