HESI A2
Chemistry HESI A2 Practice Test
1. What is the correct electron configuration for lithium?
- A. 1s²2s¹
- B. 1s²2s²
- C. 1s²2s¹2p¹
- D. 1s¹2s¹2p²
Correct answer: A
Rationale: The electron configuration for lithium is 1s²2s¹. Lithium has 3 electrons, and the configuration indicates that the first two electrons fill the 1s orbital, while the third electron fills the 2s orbital. Therefore, the correct electron configuration for lithium is 1s²2s¹. Choice B (1s²2s²) is incorrect as it represents the electron configuration for beryllium, not lithium. Choice C (1s²2s¹2p¹) includes the 2p orbital, which is not involved in lithium's electron configuration. Choice D (1s¹2s¹2p²) is incorrect as it does not accurately represent lithium's electron configuration.
2. Al(NO3)3 + H2SO4 → Al2(SO4)3 + HNO3 is an example of which kind of reaction?
- A. Decomposition reaction
- B. Synthesis reaction
- C. Single replacement reaction
- D. Double replacement reaction
Correct answer: C
Rationale: The given chemical equation represents a single replacement reaction. In this reaction, aluminum (Al) displaces hydrogen in sulfuric acid (H2SO4), forming aluminum sulfate (Al2(SO4)3) and releasing nitric acid (HNO3). Single replacement reactions involve an element replacing another element in a compound, which is evident in this reaction. Choice A, Decomposition reaction, is incorrect because decomposition reactions involve a single compound breaking down into two or more substances. Choice B, Synthesis reaction, is incorrect as it involves the combination of two or more substances to form a more complex compound. Choice D, Double replacement reaction, is also incorrect as it involves an exchange of ions between two compounds to form two new compounds.
3. Which ion would you expect to dominate in water solutions of bases?
- A. MgCl₂
- B. 2HCl
- C. H⁺
- D. OH⁻
Correct answer: D
Rationale: In water solutions of bases, the dominant ion would be OH⁻ (hydroxide ion). Bases release OH⁻ ions when dissolved in water, increasing the concentration of hydroxide ions and leading to a higher pH. This is in contrast to acids, which release H⁺ ions. Therefore, in water solutions of bases, the presence of OH⁻ ions signifies the basic nature of the solution. Choices A, B, and C are incorrect because MgCl₂ is a salt, 2HCl is a compound consisting of two hydrogen ions and one chloride ion, and H⁺ represents a hydrogen ion typically associated with acids, not bases.
4. Radioactive isotopes are frequently used in medicine. What kind of half-life would a medical isotope probably have?
- A. Seconds-long
- B. Days-long
- C. Years-long
- D. Many years long
Correct answer: B
Rationale: Medical isotopes used in diagnosis and treatment need to have a relatively short half-life to minimize radiation exposure to patients. If the half-life were too long (such as many years) or even years-long, the radiation would persist for too long and could be harmful to the patient. Seconds-long half-lives would not provide enough time for the isotope to be effective. Days-long half-lives strike a balance between providing enough time for the isotope to be used effectively and minimizing radiation exposure.
5. On what concept is Kelvin based?
- A. Freezing point
- B. Absolute zero
- C. Boiling point
- D. Evaporation point
Correct answer: B
Rationale: The correct answer is B: Absolute zero. Kelvin is based on the concept of absolute zero, which is the point where molecular movement ceases entirely. This temperature scale starts at absolute zero (0K), where theoretically no molecular movement occurs. Choices A, C, and D are incorrect because Kelvin is not based on the freezing point, boiling point, or evaporation point, but rather on the absolute absence of molecular motion.
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