HESI A2
HESI A2 Chemistry Questions
1. What is the pH of a neutral solution?
- A. 7
- B. 0
- C. 14
- D. 4
Correct answer: A
Rationale: The correct answer is A: 7. A neutral solution has a pH of 7. In the pH scale, values below 7 are acidic, 7 is neutral, and values above 7 are basic. Therefore, a solution with a pH of 7 is considered neutral as it is neither acidic nor basic. Choices B, C, and D are incorrect because a pH of 0 indicates a strong acid, a pH of 14 indicates a strong base, and a pH of 4 indicates an acidic solution. None of these values represent a neutral solution.
2. Which of the following is the weakest intermolecular force?
- A. Dipole interactions
- B. Hydrogen bonding
- C. Van der Waals forces
- D. Dispersion forces
Correct answer: D
Rationale: Dispersion forces, also known as London dispersion forces, are the weakest intermolecular forces. They are temporary attractive forces that occur due to momentary shifts in electron distribution within molecules. While dipole interactions, hydrogen bonding, and Van der Waals forces are stronger intermolecular forces, dispersion forces are the weakest because they arise from short-lived fluctuations in electron density. Dipole interactions involve permanent dipoles in molecules, making them stronger than dispersion forces. Hydrogen bonding is stronger than dipole interactions and involves hydrogen atoms bonded to highly electronegative atoms. Van der Waals forces encompass dipole-dipole interactions and dispersion forces, making them stronger than dispersion forces alone.
3. When an acid is added to a base, water and a salt form. What kinds of bonds form in these two compounds?
- A. Liquid and metallic
- B. Polar and nonpolar covalent
- C. Polar covalent and ionic
- D. Ionic only
Correct answer: C
Rationale: In water, the bond formed between the oxygen atom and the hydrogen atoms is a polar covalent bond. The oxygen atom attracts the shared electrons more strongly, creating a partial negative charge on the oxygen and a partial positive charge on the hydrogen atoms. In the salt formed, the bond between the metal cation and the nonmetal anion is predominantly an ionic bond. The metal cation donates electrons to the nonmetal anion, resulting in the formation of oppositely charged ions that are held together by electrostatic attractions. Choices A and B are incorrect because water and salts do not form bonds that are liquid and metallic, or polar and nonpolar covalent. Choice D is incorrect as it oversimplifies the types of bonds present in water and salts, failing to differentiate between the covalent bond in water and the ionic bond in the salt.
4. Which substance forms hydroxide ions when placed in water?
- A. Lemon juice
- B. Battery acid
- C. Vinegar
- D. Lye
Correct answer: D
Rationale: The correct answer is D, lye. Lye, also known as sodium hydroxide (NaOH), is a strong base that forms hydroxide ions (OH-) when placed in water. When lye dissolves in water, it dissociates into sodium ions (Na+) and hydroxide ions, making it an alkaline substance. Lemon juice, battery acid, and vinegar do not form hydroxide ions when placed in water. Lemon juice contains citric acid, battery acid contains sulfuric acid, and vinegar contains acetic acid, none of which produce hydroxide ions when dissolved in water.
5. To the nearest whole number, what is the mass of one mole of water?
- A. 16 g/mol
- B. 18 g/mol
- C. 20 g/mol
- D. 22 g/mol
Correct answer: B
Rationale: The molar mass of water (H₂O) is calculated by adding the atomic masses of two hydrogen atoms (each with a molar mass of approximately 1 g/mol) and one oxygen atom (with a molar mass of approximately 16 g/mol). Therefore, the molar mass of water is approximately 18 g/mol, making choice B the correct answer. Choice A (16 g/mol) is incorrect because it represents the molar mass of oxygen, not water. Choices C (20 g/mol) and D (22 g/mol) are incorrect as they do not correspond to the molar mass of water.
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