on the periodic table where are atoms with the largest atomic radius located

HESI A2

Chemistry Hesi A2

1. On the periodic table, where are atoms with the largest atomic radius located?

A. At the top of their group
B. In the middle of their group
C. At the bottom of their group
D. Along the right-hand side

Correct answer: C

Rationale: Atoms with the largest atomic radius are located at the bottom of their group on the periodic table. This is because atomic radius increases down a group due to the addition of more energy levels or shells of electrons. As you move down a group, the outermost electrons are further away from the nucleus, leading to an increase in atomic radius. Choice A 'At the top of their group' is incorrect because atomic radius decreases going up within a group. Choice B 'In the middle of their group' is incorrect as the atomic radius generally increases as you go down a group, not in the middle. Choice D 'Along the right-hand side' is incorrect because atomic radius tends to decrease from left to right across a period on the periodic table due to increased nuclear charge and effective nuclear charge.

2. On the periodic table, families of elements with similar properties appear in the same _________.

A. row
B. principal energy level
C. period
D. column

Correct answer: D

Rationale: Families of elements with similar properties appear in the same column on the periodic table. Columns are also known as groups, and elements within the same group have similar chemical and physical properties due to their identical number of valence electrons. Therefore, the correct answer is 'column.' Choice A, 'row,' is incorrect because rows on the periodic table are called periods, not families or groups of elements. Choice B, 'principal energy level,' is incorrect as it refers to the energy levels of electrons around the nucleus of an atom, not the arrangement of elements with similar properties on the periodic table. Choice C, 'period,' is incorrect as periods represent horizontal rows on the periodic table, where elements do not necessarily have similar properties compared to elements in the same column.

3. You contain two odorous gases in vials with porous plugs. Gas A has twice the mass of Gas B. Which observation is most likely?

A. You will smell Gas A before you smell Gas B.
B. You will smell Gas B before you smell Gas A.
C. You will smell Gas A but not Gas B.
D. You will smell Gas B but not Gas A.

Correct answer: A

Rationale: The rate of effusion of a gas is inversely proportional to the square root of its molar mass. Since Gas A has twice the mass of Gas B, Gas A will effuse more slowly than Gas B. Therefore, you will likely smell Gas A before you smell Gas B as Gas A will escape and diffuse through the porous plug at a slower rate compared to Gas B. Choice A is correct because Gas A, with its higher molar mass, will take longer to effuse through the porous plug, causing you to smell it first. Choices B, C, and D are incorrect as they do not consider the relationship between molar mass and effusion rate.

4. Which of the following substances is a base?

A. Water
B. Sodium chloride
C. Ammonia
D. Salt

Correct answer: C

Rationale: The correct answer is 'Ammonia' (Choice C) as it is a common example of a base. Bases are substances that release hydroxide ions (OH-) in aqueous solutions, helping to increase the pH level. Ammonia is a weak base that can accept a proton (H+) to form ammonium hydroxide. In contrast, water (Choice A), sodium chloride (Choice B), and salt (Choice D) are not bases; water is neutral, while sodium chloride and salt are neutral compounds composed of a cation and an anion.

5. What is the correct electron configuration for carbon?

A. 1sÂ²2sÂ²2pÂ¹
B. 1sÂ²2sÂ²2pÂ²
C. 1sÂ²2sÂ²2pÂ³
D. 1sÂ²2sÂ²2pâ¶3sÂ¹

Correct answer: B

Rationale: The correct electron configuration for carbon is 1sÂ²2sÂ²2pÂ². This configuration indicates that there are 2 electrons in the first energy level (1sÂ²), 2 electrons in the second energy level (2sÂ²), and 2 electrons in the second energy level (2pÂ²). It adheres to the aufbau principle, which states that electrons fill orbitals starting from the lowest energy level, and the Pauli exclusion principle, which states that each electron in an atom must have a unique set of quantum numbers. Choice A is incorrect because it does not fill the 2p orbital correctly. Choice C is incorrect as it exceeds the number of possible electrons in the 2p orbital. Choice D is incorrect as it includes an electron in the 3s orbital, which is not part of the electron configuration for carbon.