HESI A2
Chemistry Hesi A2
1. On the periodic table, where are atoms with the largest atomic radius located?
- A. At the top of their group
- B. In the middle of their group
- C. At the bottom of their group
- D. Along the right-hand side
Correct answer: C
Rationale: Atoms with the largest atomic radius are located at the bottom of their group on the periodic table. This is because atomic radius increases down a group due to the addition of more energy levels or shells of electrons. As you move down a group, the outermost electrons are further away from the nucleus, leading to an increase in atomic radius. Choice A 'At the top of their group' is incorrect because atomic radius decreases going up within a group. Choice B 'In the middle of their group' is incorrect as the atomic radius generally increases as you go down a group, not in the middle. Choice D 'Along the right-hand side' is incorrect because atomic radius tends to decrease from left to right across a period on the periodic table due to increased nuclear charge and effective nuclear charge.
2. What charge do Group IA elements have?
- A. +1
- B. +2
- C. +3
- D. 0
Correct answer: A
Rationale: Group IA elements, also known as alkali metals, have a +1 charge. They readily lose one electron to achieve a stable electron configuration, forming ions with a single positive charge. This makes +1 the correct choice. Choices B, C, and D are incorrect because alkali metals in Group IA typically lose one electron, so they do not have a +2, +3, or 0 charge.
3. Which of these intermolecular forces might represent attraction between atoms of a noble gas?
- A. Dipole-dipole interaction
- B. London dispersion force
- C. Keesom interaction
- D. Hydrogen bonding
Correct answer: B
Rationale: Noble gases are non-polar molecules without a permanent dipole moment. The only intermolecular force applicable to noble gases is the London dispersion force, also known as Van der Waals forces. This force is a temporary attractive force resulting from the formation of temporary dipoles in non-polar molecules. Dipole-dipole interactions, Keesom interactions, and hydrogen bonding involve significant dipoles or hydrogen atoms bonded to electronegative atoms, which do not apply to noble gases.
4. How does increasing the concentration of reactants affect a chemical reaction?
- A. Decreases the reaction rate
- B. Increases the reaction rate
- C. Stops the reaction
- D. Has no effect
Correct answer: B
Rationale: Increasing the concentration of reactants leads to more reactant particles being available, which, in turn, increases the likelihood of successful collisions between particles. This higher frequency of collisions results in a higher reaction rate. Therefore, option B, 'Increases the reaction rate,' is the correct answer. Choice A, 'Decreases the reaction rate,' is incorrect because higher reactant concentration usually speeds up the reaction. Choice C, 'Stops the reaction,' is incorrect as increasing concentration promotes more collisions, enhancing the reaction. Choice D, 'Has no effect,' is incorrect because changing reactant concentration directly impacts the reaction rate in most cases.
5. What number represents the number of protons an element has?
- A. Atomic mass
- B. Mass number
- C. Atomic number
- D. Neutron number
Correct answer: C
Rationale: The correct answer is C, atomic number. The atomic number corresponds to the number of protons in an element. This number is unique to each element and determines its placement on the periodic table. It is equal to the number of protons found in the nucleus of an atom of that element. Choice A, atomic mass, represents the average mass of an element's isotopes. Choice B, mass number, is the sum of protons and neutrons in an atom. Choice D, neutron number, specifically refers to the count of neutrons in an atom and not protons.
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