HESI A2
Chemistry Hesi A2
1. On the periodic table, where are atoms with the largest atomic radius located?
- A. At the top of their group
- B. In the middle of their group
- C. At the bottom of their group
- D. Along the right-hand side
Correct answer: C
Rationale: Atoms with the largest atomic radius are located at the bottom of their group on the periodic table. This is because atomic radius increases down a group due to the addition of more energy levels or shells of electrons. As you move down a group, the outermost electrons are further away from the nucleus, leading to an increase in atomic radius. Choice A 'At the top of their group' is incorrect because atomic radius decreases going up within a group. Choice B 'In the middle of their group' is incorrect as the atomic radius generally increases as you go down a group, not in the middle. Choice D 'Along the right-hand side' is incorrect because atomic radius tends to decrease from left to right across a period on the periodic table due to increased nuclear charge and effective nuclear charge.
2. Which intermolecular force is the strongest?
- A. Dipole interactions
- B. Dispersion forces
- C. Hydrogen bonding
- D. Van der Waals forces
Correct answer: C
Rationale: Hydrogen bonding is the strongest intermolecular force due to its specific interaction between a hydrogen atom and a highly electronegative atom like nitrogen, oxygen, or fluorine. This type of bonding results in a very strong attraction between molecules, making it the strongest intermolecular force among the options provided. Dipole interactions (choice A) are weaker than hydrogen bonding as they occur between polar molecules. Dispersion forces (choice B) are the weakest intermolecular forces and are caused by temporary fluctuations in electron distribution. Van der Waals forces (choice D) are a broader term that encompasses dipole interactions and dispersion forces, making them weaker than hydrogen bonding.
3. What is the correct name of AgNO₃?
- A. Argent nitrous
- B. Argent oxide
- C. Silver nitrite
- D. Silver nitrate
Correct answer: D
Rationale: The correct name for AgNO₃ is silver nitrate. In chemical nomenclature, the element symbol Ag represents silver, and the polyatomic ion NO₃ is known as nitrate. Therefore, when the silver ion (Ag⁺) combines with the nitrate ion (NO₃⁻), the resulting compound is named silver nitrate (AgNO₃). Choices A, B, and C are incorrect because they do not accurately represent the composition of AgNO₃. Argent nitrous (Choice A) and Argent oxide (Choice B) do not reflect the correct anion, and Silver nitrite (Choice C) uses a different anion altogether.
4. How many electron pairs are shared to form a double covalent bond?
- A. 1
- B. 2
- C. 3
- D. 4
Correct answer: B
Rationale: The correct answer is B. In a double covalent bond, two pairs of electrons are shared between two atoms. This sharing of two electron pairs results in a stronger bond compared to a single covalent bond where only one pair of electrons is shared. Choice A is incorrect because a single covalent bond involves the sharing of one pair of electrons. Choices C and D are incorrect as they do not represent the correct number of electron pairs shared in a double covalent bond.
5. What is stoichiometry?
- A. The study of energy changes in chemical reactions
- B. The study of the mass relationships in chemical reactions
- C. The study of atomic structure
- D. The study of molecular geometry
Correct answer: B
Rationale: Stoichiometry is the branch of chemistry that deals with the quantitative relationships between reactants and products in chemical reactions. It focuses on the calculation of the amounts of substances consumed and produced in a reaction based on the balanced chemical equation. Choice A is incorrect because the study of energy changes in chemical reactions falls under thermodynamics. Choice C is incorrect as atomic structure is related to the arrangement of atoms within molecules. Choice D is incorrect as molecular geometry deals with the spatial arrangement of atoms within molecules.
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