HESI A2
HESI A2 Chemistry
1. Which compound contains a polar covalent bond?
- A. O
- B. F
- C. Br
- D. H₂O
Correct answer: D
Rationale: The compound 'H₂O' (water) contains a polar covalent bond. In a water molecule, the oxygen atom is more electronegative than the hydrogen atoms. As a result, the electrons in the O-H bonds are unevenly shared, leading to a partial negative charge on the oxygen atom and partial positive charges on the hydrogen atoms. This unequal sharing of electrons creates a polar covalent bond in water. Choices A, B, and C are incorrect because they represent individual elements, not compounds, and do not involve the concept of polar covalent bonds.
2. What are the horizontal rows of the periodic table called?
- A. Periods
- B. Families
- C. Groups
- D. Columns
Correct answer: A
Rationale: The correct answer is A: Periods. Rows in the periodic table are called periods. They are arranged horizontally from left to right and represent the energy levels of the elements. Each period starts a new energy level or shell, indicating the number of electron shells an element has. Choices B, C, and D are incorrect. Families and groups refer to vertical columns in the periodic table that share similar chemical properties, while columns are vertical arrangements of elements known as groups or families.
3. How many neutrons are in an atom of uranium-235?
- A. 92
- B. 125
- C. 143
- D. 235
Correct answer: A
Rationale: The correct answer is A: '92'. To determine the number of neutrons in an atom, you subtract the atomic number (number of protons) from the atomic mass number. For uranium-235, the atomic number is 92, and the atomic mass number is 235. Subtracting 92 from 235 gives us 143 neutrons in an atom of uranium-235. Therefore, options B, C, and D are incorrect as they do not represent the correct number of neutrons in an atom of uranium-235.
4. What is stoichiometry?
- A. The study of energy changes in chemical reactions
- B. The study of the mass relationships in chemical reactions
- C. The study of atomic structure
- D. The study of molecular geometry
Correct answer: B
Rationale: Stoichiometry is the branch of chemistry that deals with the quantitative relationships between reactants and products in chemical reactions. It focuses on the calculation of the amounts of substances consumed and produced in a reaction based on the balanced chemical equation. Choice A is incorrect because the study of energy changes in chemical reactions falls under thermodynamics. Choice C is incorrect as atomic structure is related to the arrangement of atoms within molecules. Choice D is incorrect as molecular geometry deals with the spatial arrangement of atoms within molecules.
5. Which of these types of intermolecular force is the strongest?
- A. Dipole-dipole interaction
- B. London dispersion force
- C. Keesom interaction
- D. Hydrogen bonding
Correct answer: D
Rationale: Hydrogen bonding is the strongest type of intermolecular force among the options provided. It occurs when a hydrogen atom is covalently bonded to a highly electronegative atom (such as nitrogen, oxygen, or fluorine) and forms a strong electrostatic attraction with an unshared pair of electrons on another electronegative atom. This type of bond is stronger than dipole-dipole interactions, London dispersion forces, and Keesom interactions due to the significant electronegativity difference between the hydrogen and the electronegative atom involved in the bond. The presence of hydrogen bonding contributes to unique properties in substances, such as high boiling and melting points, making it a crucial force in various biological and chemical processes.
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