HESI A2
HESI A2 Chemistry
1. Which compound contains a polar covalent bond?
- A. O
- B. F
- C. Br
- D. H₂O
Correct answer: D
Rationale: The compound 'H₂O' (water) contains a polar covalent bond. In a water molecule, the oxygen atom is more electronegative than the hydrogen atoms. As a result, the electrons in the O-H bonds are unevenly shared, leading to a partial negative charge on the oxygen atom and partial positive charges on the hydrogen atoms. This unequal sharing of electrons creates a polar covalent bond in water. Choices A, B, and C are incorrect because they represent individual elements, not compounds, and do not involve the concept of polar covalent bonds.
2. On the periodic table, families of elements with similar properties appear in the same _________.
- A. row
- B. principal energy level
- C. period
- D. column
Correct answer: D
Rationale: Families of elements with similar properties appear in the same column on the periodic table. Columns are also known as groups, and elements within the same group have similar chemical and physical properties due to their identical number of valence electrons. Therefore, the correct answer is 'column.' Choice A, 'row,' is incorrect because rows on the periodic table are called periods, not families or groups of elements. Choice B, 'principal energy level,' is incorrect as it refers to the energy levels of electrons around the nucleus of an atom, not the arrangement of elements with similar properties on the periodic table. Choice C, 'period,' is incorrect as periods represent horizontal rows on the periodic table, where elements do not necessarily have similar properties compared to elements in the same column.
3. On the periodic table, where are atoms with the largest atomic radius located?
- A. At the top of their group
- B. In the middle of their group
- C. At the bottom of their group
- D. Along the right-hand side
Correct answer: C
Rationale: Atoms with the largest atomic radius are located at the bottom of their group on the periodic table. This is because atomic radius increases down a group due to the addition of more energy levels or shells of electrons. As you move down a group, the outermost electrons are further away from the nucleus, leading to an increase in atomic radius. Choice A 'At the top of their group' is incorrect because atomic radius decreases going up within a group. Choice B 'In the middle of their group' is incorrect as the atomic radius generally increases as you go down a group, not in the middle. Choice D 'Along the right-hand side' is incorrect because atomic radius tends to decrease from left to right across a period on the periodic table due to increased nuclear charge and effective nuclear charge.
4. Which type of radiation emits helium ions and can be stopped by a piece of paper?
- A. Beta radiation
- B. Alpha radiation
- C. Gamma radiation
- D. X-ray radiation
Correct answer: B
Rationale: Alpha radiation emits helium ions, which are helium nuclei without electrons, making them positively charged. These ions are relatively large and heavy compared to beta and gamma radiation. Due to their size and charge, alpha particles interact strongly with matter and are easily stopped. A piece of paper or even human skin can effectively block alpha radiation. Therefore, alpha radiation is the type of radiation that can be stopped by a piece of paper. Beta radiation consists of fast-moving electrons and can penetrate further into materials than alpha radiation, thus not stopped by a piece of paper. Gamma radiation is highly penetrating and requires dense materials like lead or concrete to block it effectively. X-ray radiation, similar to gamma radiation, is also highly penetrating and cannot be stopped by a piece of paper.
5. What type of reaction occurs when an acid and a base react to form water and salt?
- A. Neutralization reaction
- B. Decomposition reaction
- C. Combustion reaction
- D. Redox reaction
Correct answer: A
Rationale: A neutralization reaction is the correct answer. In this type of reaction, an acid and a base combine to form water and salt. The acid donates a proton (H+) to the base, forming water, while the remaining ions combine to form a salt. This reaction results in the neutralization of both the acid and the base, hence the name 'neutralization reaction.' Choice B, decomposition reaction, is incorrect because it refers to a reaction where a compound breaks down into simpler substances. Choice C, combustion reaction, is incorrect as it involves a substance reacting with oxygen to produce heat and light. Choice D, redox reaction, is incorrect because it involves the transfer of electrons between reactants.
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