HESI A2
HESI A2 Chemistry
1. Which compound contains a polar covalent bond?
- A. O
- B. F
- C. Br
- D. H₂O
Correct answer: D
Rationale: The compound 'H₂O' (water) contains a polar covalent bond. In a water molecule, the oxygen atom is more electronegative than the hydrogen atoms. As a result, the electrons in the O-H bonds are unevenly shared, leading to a partial negative charge on the oxygen atom and partial positive charges on the hydrogen atoms. This unequal sharing of electrons creates a polar covalent bond in water. Choices A, B, and C are incorrect because they represent individual elements, not compounds, and do not involve the concept of polar covalent bonds.
2. What is atomic mass?
- A. Number of protons in an atom
- B. Sum of protons and neutrons
- C. Number of neutrons in an atom
- D. Average weight of an element
Correct answer: B
Rationale: Atomic mass, also known as atomic weight, is the sum of the number of protons and neutrons in an atom. It represents the average mass of an atom of an element, taking into account the different isotopes and their relative abundance. Neutrons contribute to the atomic mass alongside protons, while the number of neutrons alone is not the definition of atomic mass. Choice A is incorrect because it refers only to the number of protons, not the complete atomic mass. Choice C is incorrect as it focuses solely on the number of neutrons, excluding the contribution of protons. Choice D is incorrect as it mentions the 'average weight of an element,' which is related to atomic mass but does not encapsulate the specific definition of atomic mass as the sum of protons and neutrons.
3. What is the charge of a gamma ray?
- A. -1
- B. +1
- C. +2
- D. No charge
Correct answer: D
Rationale: Gamma rays are a form of electromagnetic radiation with no charge. They are neutral particles that do not possess any electric charge. This characteristic allows them to be unaffected by electric or magnetic fields. Additionally, gamma rays travel at the speed of light in a vacuum. Choices A, B, and C are incorrect as gamma rays do not carry a charge of -1, +1, or +2; they are neutral entities.
4. How many moles of potassium bromide are in 25 mL of a 4 M KBr solution?
- A. 0.035 mol
- B. 0.1 mol
- C. 0.18 mol
- D. 1.6 mol
Correct answer: B
Rationale: To find the moles of potassium bromide in 25 mL of a 4 M KBr solution, we first need to convert the volume from milliliters to liters. 25 mL is equal to 0.025 L. Then, we use the formula moles = molarity x volume in liters. Substituting the values, moles = 4 M x 0.025 L = 0.1 mol. Therefore, there are 0.1 moles of KBr in 25 mL of a 4 M solution. Choice A, 0.035 mol, is incorrect as it does not properly calculate the moles. Choice C, 0.18 mol, and choice D, 1.6 mol, are also incorrect as they are not the result of the correct calculation based on the given molarity and volume.
5. What is a benefit of water's ability to make hydrogen bonds?
- A. Lack of cohesiveness
- B. Low surface tension
- C. Use as a nonpolar solvent
- D. High specific heat
Correct answer: D
Rationale: The correct answer is D, high specific heat. Water's ability to form hydrogen bonds results in a high specific heat capacity, allowing it to absorb and release a large amount of heat energy with minimal temperature change. This property is essential for moderating temperature changes in organisms and maintaining stable environmental conditions for life processes. Choices A, lack of cohesiveness, and C, use as a nonpolar solvent, are incorrect. Water actually has high cohesiveness due to its ability to form hydrogen bonds, and it is a polar solvent, not nonpolar. Choice B, low surface tension, is also incorrect as water's hydrogen bonding contributes to its relatively high surface tension.
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