HESI A2
HESI A2 Chemistry Questions
1. Which of the following elements is the most electronegative?
- A. Oxygen
- B. Fluorine
- C. Nitrogen
- D. Sodium
Correct answer: B
Rationale: Fluorine is the most electronegative element on the periodic table. It has the highest electronegativity value, indicating its strong ability to attract electrons in a chemical bond. This property makes it highly reactive, explaining why it is the correct answer in this question. Oxygen and Nitrogen are also electronegative elements, but they are not as electronegative as Fluorine. Sodium, on the other hand, is not electronegative; it is an electropositive element.
2. On the periodic table, families of elements with similar properties appear in the same _________.
- A. row
- B. principal energy level
- C. period
- D. column
Correct answer: D
Rationale: Families of elements with similar properties appear in the same column on the periodic table. Columns are also known as groups, and elements within the same group have similar chemical and physical properties due to their identical number of valence electrons. Therefore, the correct answer is 'column.' Choice A, 'row,' is incorrect because rows on the periodic table are called periods, not families or groups of elements. Choice B, 'principal energy level,' is incorrect as it refers to the energy levels of electrons around the nucleus of an atom, not the arrangement of elements with similar properties on the periodic table. Choice C, 'period,' is incorrect as periods represent horizontal rows on the periodic table, where elements do not necessarily have similar properties compared to elements in the same column.
3. If fifty-six kilograms of a radioactive substance has a half-life of 12 days, how many days will it take the substance to decay naturally to only 7 kilograms?
- A. 8
- B. 12
- C. 36
- D. 48
Correct answer: C
Rationale: To decay from 56 kg to 7 kg, the substance needs to go through 3 half-lives (56 kg ÷ 2 ÷ 2 ÷ 2 = 7 kg). Since each half-life is 12 days, the total time required is 12 days per half-life x 3 half-lives = 36 days. Choice A is incorrect because it does not consider the concept of half-lives. Choice B is incorrect because it represents the duration of a single half-life, not the total time required for the decay. Choice D is incorrect as it does not account for the multiple half-lives needed for the substance to decay from 56 kg to 7 kg.
4. Which of these intermolecular forces would result in the lowest boiling point?
- A. Dipole-dipole interaction
- B. London dispersion force
- C. Keesom interaction
- D. Hydrogen bonding
Correct answer: B
Rationale: The London dispersion force is the weakest intermolecular force among the options provided. These forces are present in all molecules and are caused by temporary fluctuations in electron density, resulting in temporary dipoles. Since London dispersion forces are generally weaker than dipole-dipole interactions, Keesom interactions, and hydrogen bonding, a substance with London dispersion forces as the primary intermolecular force would have the lowest boiling point due to the weaker intermolecular forces holding the molecules together. Dipole-dipole interactions, Keesom interactions, and hydrogen bonding are stronger intermolecular forces compared to London dispersion forces, resulting in higher boiling points for substances that exhibit these interactions.
5. What are the two types of chemical bonding?
- A. Covalent & hydrogen
- B. Ionic & covalent
- C. Ionic & hydrogen
- D. Covalent & metallic
Correct answer: B
Rationale: The correct answer is B: Ionic & covalent. Ionic bonding involves the transfer of electrons between atoms, resulting in the formation of positive and negative ions attracted to each other. Covalent bonding involves the sharing of electrons between atoms to achieve a stable electron configuration. Choice A is incorrect as hydrogen bonding is a type of intermolecular force, not a primary type of chemical bonding. Choice C is incorrect as hydrogen bonding is not a primary type of chemical bonding. Choice D is incorrect as metallic bonding involves the sharing of electrons in a 'sea of electrons' within a metal lattice, not covalent bonding.
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