HESI A2
HESI A2 Chemistry Questions
1. Which of the following elements is the most electronegative?
- A. Oxygen
- B. Fluorine
- C. Nitrogen
- D. Sodium
Correct answer: B
Rationale: Fluorine is the most electronegative element on the periodic table. It has the highest electronegativity value, indicating its strong ability to attract electrons in a chemical bond. This property makes it highly reactive, explaining why it is the correct answer in this question. Oxygen and Nitrogen are also electronegative elements, but they are not as electronegative as Fluorine. Sodium, on the other hand, is not electronegative; it is an electropositive element.
2. Which compound has a nonpolar bond in which the electrons are shared equally?
- A. H₂O
- B. NH₃
- C. Cl₂
- D. CH₄
Correct answer: D
Rationale: The compound CH₄, methane, has a nonpolar bond where carbon and hydrogen share electrons equally. This occurs because carbon and hydrogen have similar electronegativities, meaning they have equal abilities to attract shared electrons. Consequently, a nonpolar covalent bond is formed due to the balanced sharing of electrons between these atoms. Choices A, B, and C do not have nonpolar bonds with electrons shared equally. In H₂O (water), there are polar covalent bonds due to the difference in electronegativity between hydrogen and oxygen. In NH₃ (ammonia), the nitrogen-hydrogen bonds are polar because of the electronegativity difference. In Cl₂ (chlorine gas), the Cl-Cl bond is nonpolar, but the question specifies a compound, not an element, and chlorine does not share its electrons equally with another element in a compound.
3. Which of the following pH values is most likely for lemon juice?
- A. 3
- B. 5
- C. 7
- D. 9
Correct answer: A
Rationale: Lemon juice is highly acidic with a pH around 2-3, making it more acidic than neutral substances. A pH of 5 is too high for lemon juice, indicating less acidity. Similarly, pH 7 is neutral, and pH 9 would be alkaline, which is not characteristic of lemon juice. Therefore, the correct answer is option A (pH 3).
4. If 5 g of NaCl (1 mole of NaCl) is dissolved in enough water to make 500 L of solution, what is the molarity of the solution?
- A. 1.0 M
- B. 2.0 M
- C. 11.7 M
- D. The answer cannot be determined from the information given.
Correct answer: C
Rationale: Molarity is defined as the number of moles of solute per liter of solution. In this case, 5 g of NaCl represents 1 mole of NaCl. Given that this 1 mole is dissolved in 500 L of solution, the molarity of the solution can be calculated as follows: Molarity = moles of solute / liters of solution = 1 mole / 500 L = 0.002 M. However, the molarity is usually expressed in moles per liter, so to convert to M, you divide by 0.085 L (which is 500 L in liters) to get 11.7 M. Choice A is incorrect because the molarity is not 1.0 M. Choice B is incorrect because the molarity is not 2.0 M. Choice D is incorrect because the molarity can be determined from the information provided.
5. Which of these intermolecular forces might represent attraction between atoms of a noble gas?
- A. Dipole-dipole interaction
- B. London dispersion force
- C. Keesom interaction
- D. Hydrogen bonding
Correct answer: B
Rationale: Noble gases are non-polar molecules without a permanent dipole moment. The only intermolecular force applicable to noble gases is the London dispersion force, also known as Van der Waals forces. This force is a temporary attractive force resulting from the formation of temporary dipoles in non-polar molecules. Dipole-dipole interactions, Keesom interactions, and hydrogen bonding involve significant dipoles or hydrogen atoms bonded to electronegative atoms, which do not apply to noble gases.
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