HESI A2
Chemistry Hesi A2
1. Identify the type of reaction shown: 8Fe + S → 8FeS
- A. Single displacement
- B. Double displacement
- C. Synthesis
- D. Acid-base
Correct answer: C
Rationale: The reaction shown (8Fe + S → 8FeS) is a synthesis reaction. In a synthesis reaction, two or more substances combine to form a single compound. In this case, iron (Fe) and sulfur (S) combine to form iron sulfide (FeS). The key characteristic of a synthesis reaction is the formation of a single product from multiple reactants, which aligns with the given chemical equation. Choice A, single displacement, involves an element displacing another in a compound, which is not the case here. Choice B, double displacement, involves the exchange of ions between two compounds, which is also not happening in this reaction. Choice D, acid-base, refers to reactions between an acid and a base to form salt and water, which is not the case in the given equation.
2. What is the molarity of a solution containing 45 moles of NaCl in 4 liters?
- A. 0.11 M NaCl
- B. 0.45 M NaCl
- C. 1.8 M NaCl
- D. 8.9 M NaCl
Correct answer: A
Rationale: To calculate the molarity of a solution, you use the formula: Molarity (M) = moles of solute / liters of solution. In this case, M = 45 moles / 4 L = 11.25 M. The correct answer is 0.11 M NaCl. Choice B is incorrect as it doesn't match the calculated value. Choice C is also incorrect as it is significantly higher than the correct molarity. Choice D is incorrect as it is excessively high compared to the calculated value.
3. Here are the solubilities of four substances at 0°C, in grams of solute per 100 mL of water. If the temperature increases to 20°C, what would you expect to happen to the solubility figures?
- A. Citric acid and potassium phosphate will decrease; nitrogen and oxygen will increase.
- B. Citric acid and potassium phosphate will increase; nitrogen and oxygen will decrease.
- C. All four figures will increase.
- D. All four figures will decrease.
Correct answer: C
Rationale: Solubility generally tends to increase with temperature for most solid solutes in liquid solvents due to higher kinetic energy leading to better solute-solvent interactions. As the temperature increases from 0°C to 20°C, all four solubility figures are expected to increase. Choice A is incorrect because solubility tends to increase with temperature. Choice B is incorrect as well for the same reason. Choice D is incorrect because the solubility of solid solutes typically increases with temperature.
4. Which statement is true of a saturated solution?
- A. It has more solute than can dissolve in the solvent.
- B. It has less solute that can dissolve in the solvent.
- C. It has the maximum concentration of the solute dissolved in the solvent.
- D. It contains a precipitate that lowers the concentration of the solute in the solvent.
Correct answer: C
Rationale: A saturated solution contains the maximum concentration of solute that can be dissolved in a specific amount of solvent at a particular temperature. Once a solution is saturated, adding more solute will not increase its concentration since the excess solute will not dissolve and will instead form a precipitate, indicating that the solution is at its maximum capacity. Choices A, B, and D are incorrect because a saturated solution has reached its limit in dissolving solute, so it cannot contain more solute than it can dissolve (choice A), less solute than it can dissolve (choice B), or a precipitate that lowers the concentration of the solute in the solvent (choice D).
5. If electrons are not shared equally in a covalent bond, the bond is what?
- A. Polar
- B. Non-polar
- C. Ionic
- D. Hydrogen
Correct answer: A
Rationale: A polar covalent bond occurs when electrons are shared unequally between atoms. In this type of bond, one atom has a stronger pull on the shared electrons, leading to a partial positive and partial negative charge distribution within the molecule. Choice B, non-polar, is incorrect because in non-polar covalent bonds, electrons are shared equally between atoms. Choice C, ionic, is incorrect as ionic bonds involve a transfer of electrons rather than sharing. Choice D, hydrogen, is incorrect as it does not describe the nature of a covalent bond.
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