why does fluorine have a higher ionization energy than oxygen

HESI A2

Chemistry Hesi A2

1. Why does fluorine have a higher ionization energy than oxygen?

A. Fluorine has a smaller number of neutrons.
B. Fluorine has a larger number of neutrons.
C. Fluorine has a smaller nuclear charge.
D. Fluorine has a larger nuclear charge.

Correct answer: D

Rationale: Fluorine has a higher ionization energy than oxygen because fluorine has a larger nuclear charge. The greater number of protons in the nucleus of fluorine attracts its electrons more strongly, making it harder to remove an electron from a fluorine atom compared to an oxygen atom. Choice A is incorrect as the number of neutrons does not directly affect ionization energy. Choice B is also incorrect for the same reason. Choice C is incorrect because a smaller nuclear charge would result in lower ionization energy, not higher.

2. What term refers to the average of the masses of each of its isotopes as they occur in nature?

A. Atomic number
B. Mass number
C. Atomic mass
D. Neutron number

Correct answer: C

Rationale: The correct answer is atomic mass. Atomic mass is the weighted average of the masses of an element's isotopes. It takes into account the abundance of each isotope in nature to provide a more accurate representation of the element's overall mass. Choice A, atomic number, represents the number of protons in an atom. Choice B, mass number, refers to the total number of protons and neutrons in an atom's nucleus. Choice D, neutron number, specifically focuses on the count of neutrons in an atom's nucleus. These choices do not directly relate to the average mass of isotopes as asked in the question.

3. What are the three types of intermolecular forces?

A. Ionic, covalent, hydrogen
B. Hydrogen bonding, dipole interactions, dispersion forces
C. Van der Waals, ionic, covalent
D. Hydrogen, Van der Waals, dispersion forces

Correct answer: B

Rationale: The three types of intermolecular forces are hydrogen bonding, dipole interactions, and dispersion forces. Option A includes ionic and covalent bonds, which are intramolecular forces, not intermolecular. Option C includes van der Waals forces, which encompass dipole interactions and dispersion forces, but also includes ionic and covalent bonds. Option D is close but misses dipole interactions, which are distinct from hydrogen bonding and dispersion forces. Therefore, option B is the correct choice as it includes the three specific types of intermolecular forces.

4. Which of the following substances is a base?

A. Water
B. Sodium chloride
C. Ammonia
D. Salt

Correct answer: C

Rationale: The correct answer is 'Ammonia' (Choice C) as it is a common example of a base. Bases are substances that release hydroxide ions (OH-) in aqueous solutions, helping to increase the pH level. Ammonia is a weak base that can accept a proton (H+) to form ammonium hydroxide. In contrast, water (Choice A), sodium chloride (Choice B), and salt (Choice D) are not bases; water is neutral, while sodium chloride and salt are neutral compounds composed of a cation and an anion.

5. How many neutrons does carbon-14 have?

A. 10
B. 8
C. 6
D. 12

Correct answer: B

Rationale: The correct answer is B: 8. Carbon-14 is an isotope of carbon with 6 protons and 8 neutrons. To determine the number of neutrons in an atom, subtract the atomic number (number of protons) from the mass number. In this case, the mass number of carbon-14 is 14, and the atomic number of carbon is 6. Therefore, 14 (mass number) - 6 (atomic number) = 8 neutrons. Choices A, C, and D are incorrect because they do not reflect the correct number of neutrons in a carbon-14 atom.