which of these factors would not affect rates of reaction

HESI A2

Chemistry HESI A2 Practice Test

1. Which of the following factors would not affect rates of reaction?

A. Temperature
B. Surface area
C. Pressure
D. Time

Correct answer: D

Rationale: Time would not directly affect rates of reaction. The rate of a chemical reaction is determined by factors that affect the frequency of successful collisions between reactant molecules, leading to a reaction. Temperature, surface area, and pressure can influence reaction rates by impacting the kinetic energy of molecules, the exposed surface for collisions, and the concentration of reactants, respectively. However, time, in the context of this question, does not alter the rate of reaction but may affect the extent of the reaction or the amount of product formed over time.

2. Which elements are typically involved in hydrogen bonding?

A. Carbon, hydrogen, oxygen
B. Fluorine, chlorine, oxygen
C. Fluorine, chlorine, nitrogen
D. Fluorine, oxygen, nitrogen

Correct answer: D

Rationale: Hydrogen bonding occurs between hydrogen and highly electronegative atoms such as fluorine, oxygen, and nitrogen. These atoms have a strong pull on the shared electrons, leading to a partial negative charge on them, which allows them to form hydrogen bonds with hydrogen or other electronegative atoms. Choice A is incorrect because carbon is not typically involved in hydrogen bonding. Choice B is incorrect because chlorine is not as electronegative as nitrogen, and choice C is incorrect because nitrogen is more electronegative than chlorine.

3. Carbon-12 and carbon-14 are isotopes. What do they have in common?

A. Number of nuclear particles
B. Number of protons
C. Number of neutrons
D. Mass number

Correct answer: C

Rationale: Isotopes are atoms of the same element with the same number of protons (which determines the element) but different numbers of neutrons. Both carbon-12 and carbon-14 have 6 protons (hence they are both carbon atoms) but different numbers of neutrons: carbon-12 has 6 neutrons, while carbon-14 has 8 neutrons. Therefore, the correct answer is the number of neutrons. Choices A, B, and D are incorrect because isotopes may have different numbers of nuclear particles (protons + neutrons), protons, and mass numbers, respectively.

4. Which of the following is the weakest intermolecular force?

A. Dipole interactions
B. Hydrogen bonding
C. Van der Waals forces
D. Dispersion forces

Correct answer: D

Rationale: Dispersion forces, also known as London dispersion forces, are the weakest intermolecular forces. They are temporary attractive forces that occur due to momentary shifts in electron distribution within molecules. While dipole interactions, hydrogen bonding, and Van der Waals forces are stronger intermolecular forces, dispersion forces are the weakest because they arise from short-lived fluctuations in electron density. Dipole interactions involve permanent dipoles in molecules, making them stronger than dispersion forces. Hydrogen bonding is stronger than dipole interactions and involves hydrogen atoms bonded to highly electronegative atoms. Van der Waals forces encompass dipole-dipole interactions and dispersion forces, making them stronger than dispersion forces alone.

5. What is the oxidation state of the potassium ion in the compound KCl?

A. +1
B. -1
C. +2
D. -2

Correct answer: A

Rationale: In the compound KCl (potassium chloride), potassium is in Group 1 of the periodic table, which means it has a valence electron of 1. Chlorine is in Group 17 and gains one electron to achieve a stable electron configuration by forming an ionic bond with potassium. As a result, the potassium ion in KCl has a +1 oxidation state. Therefore, the correct answer is +1. Choices B, C, and D are incorrect as they do not reflect the oxidation state of the potassium ion in KCl.