HESI A2
Chemistry HESI A2 Practice Test
1. Which of the following factors would not affect rates of reaction?
- A. Temperature
- B. Surface area
- C. Pressure
- D. Time
Correct answer: D
Rationale: Time would not directly affect rates of reaction. The rate of a chemical reaction is determined by factors that affect the frequency of successful collisions between reactant molecules, leading to a reaction. Temperature, surface area, and pressure can influence reaction rates by impacting the kinetic energy of molecules, the exposed surface for collisions, and the concentration of reactants, respectively. However, time, in the context of this question, does not alter the rate of reaction but may affect the extent of the reaction or the amount of product formed over time.
2. What is the correct electron configuration for magnesium?
- A. 1s² 2s²
- B. 1s² 2s² 2pâ¶
- C. 1s² 2s² 2pⶠ3s²
- D. 1s² 2s² 2pⶠ3s² 3p¹
Correct answer: C
Rationale: The electron configuration of an element is determined by following the Aufbau principle, which states that electrons fill orbitals starting from the lowest energy level. Magnesium has an atomic number of 12, meaning it has 12 electrons. The electron configuration of magnesium fills the 1s, 2s, 2p, and 3s orbitals to accommodate all 12 electrons. Therefore, the correct electron configuration for magnesium is 1s² 2s² 2pⶠ3s². Choice A is incorrect as it only includes 4 electrons and stops at the 2s orbital. Choice B is incorrect as it includes 8 electrons and stops at the 2p orbital. Choice D is incorrect as it includes 13 electrons and extends to the 3p orbital, which is beyond the actual electron configuration of magnesium.
3. Which of the following is a characteristic of an exothermic reaction?
- A. It absorbs heat
- B. It releases heat
- C. It remains neutral
- D. It requires energy input
Correct answer: B
Rationale: An exothermic reaction is characterized by the release of heat. During an exothermic reaction, energy is released in the form of heat to the surroundings, resulting in a temperature increase. This distinguishes it from endothermic reactions, which absorb heat from the surroundings. Choice A is incorrect because exothermic reactions do not absorb heat; instead, they release heat. Choice C is incorrect as exothermic reactions do not remain neutral; they involve a net release of energy. Choice D is incorrect as exothermic reactions do not require energy input; instead, they release energy.
4. What type of intermolecular force is a dipole attraction?
- A. Strong
- B. Weak
- C. Medium
- D. Very strong
Correct answer: B
Rationale: A dipole attraction is considered a weak intermolecular force. It occurs between molecules with permanent dipoles, where the positive end of one molecule is attracted to the negative end of another molecule. While dipole-dipole interactions are stronger than dispersion forces, they are weaker than hydrogen bonding or ion-dipole interactions. Therefore, the correct answer is 'Weak.' Choices A, C, and D are incorrect because dipole attractions are not classified as strong, medium, or very strong intermolecular forces, but rather fall into the category of weak intermolecular forces.
5. Which of the following types of matter changes in volume with changes in temperature and pressure?
- A. Liquid
- B. Gas
- C. Solid
- D. Plasma
Correct answer: B
Rationale: A gas changes its volume with changes in temperature and pressure due to the particles moving more rapidly at higher temperatures, and pressure affects the space between particles. Liquids have a relatively fixed volume but take the shape of their container. Solids have a definite shape and volume, so they do not change volume with changes in temperature and pressure. Plasma is a state of matter where particles are highly energized and do not have a fixed volume, but it does not exhibit volume changes with temperature and pressure variations.
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