HESI A2
HESI A2 Chemistry Practice Questions
1. On the periodic table, families of elements with similar properties appear in the same _________.
- A. row
- B. principal energy level
- C. period
- D. column
Correct answer: D
Rationale: Families of elements with similar properties appear in the same column on the periodic table. Columns are also known as groups, and elements within the same group have similar chemical and physical properties due to their identical number of valence electrons. Therefore, the correct answer is 'column.' Choice A, 'row,' is incorrect because rows on the periodic table are called periods, not families or groups of elements. Choice B, 'principal energy level,' is incorrect as it refers to the energy levels of electrons around the nucleus of an atom, not the arrangement of elements with similar properties on the periodic table. Choice C, 'period,' is incorrect as periods represent horizontal rows on the periodic table, where elements do not necessarily have similar properties compared to elements in the same column.
2. What does the mass of one mole of a substance represent?
- A. Atomic mass
- B. Mass number
- C. Molecular weight
- D. Molar mass
Correct answer: D
Rationale: The mass of one mole of a substance is represented by its molar mass. Molar mass is the mass of one mole of a substance and is expressed in grams per mole. It is calculated by summing the atomic masses of all atoms in a molecule. Therefore, the correct answer is D - 'Molar mass'. Choice A, 'Atomic mass', refers to the average mass of an atom of an element. Choice B, 'Mass number', is the total number of protons and neutrons in an atom's nucleus. Choice C, 'Molecular weight', is the average mass of a molecule relative to 1/12 of the mass of an atom of carbon-12.
3. If oxygen is in a compound, what would its oxidation number be?
- A. 2
- B. -2
- C. 0
- D. -1
Correct answer: B
Rationale: Oxygen typically has an oxidation number of -2 in compounds because it tends to gain electrons. This is due to its high electronegativity, which leads to oxygen attracting electrons towards itself in a chemical bond. Choice A (2) is incorrect because oxygen doesn't have a +2 oxidation number in compounds. Choice C (0) is incorrect as oxygen rarely has an oxidation number of 0 in compounds. Choice D (-1) is incorrect as oxygen's oxidation number in compounds is typically -2, not -1.
4. Which of these intermolecular forces would result in the lowest boiling point?
- A. Dipole-dipole interaction
- B. London dispersion force
- C. Keesom interaction
- D. Hydrogen bonding
Correct answer: B
Rationale: The London dispersion force is the weakest intermolecular force among the options provided. These forces are present in all molecules and are caused by temporary fluctuations in electron density, resulting in temporary dipoles. Since London dispersion forces are generally weaker than dipole-dipole interactions, Keesom interactions, and hydrogen bonding, a substance with London dispersion forces as the primary intermolecular force would have the lowest boiling point due to the weaker intermolecular forces holding the molecules together. Dipole-dipole interactions, Keesom interactions, and hydrogen bonding are stronger intermolecular forces compared to London dispersion forces, resulting in higher boiling points for substances that exhibit these interactions.
5. Which of the following factors would not affect rates of reaction?
- A. Temperature
- B. Surface area
- C. Pressure
- D. Time
Correct answer: D
Rationale: Time would not directly affect rates of reaction. The rate of a chemical reaction is determined by factors that affect the frequency of successful collisions between reactant molecules, leading to a reaction. Temperature, surface area, and pressure can influence reaction rates by impacting the kinetic energy of molecules, the exposed surface for collisions, and the concentration of reactants, respectively. However, time, in the context of this question, does not alter the rate of reaction but may affect the extent of the reaction or the amount of product formed over time.
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