HESI A2
Chemistry Hesi A2
1. Which substance shows a decrease in solubility in water with an increase in temperature?
- A. NaCl
- B. O
- C. KI
- D. CaCl
Correct answer: C
Rationale: Potassium iodide (KI) shows a decrease in solubility in water with an increase in temperature. This is due to the dissolution of KI in water being an endothermic process. When the temperature rises, the equilibrium shifts toward the solid state, leading to a decrease in solubility. Therefore, as the temperature increases, KI becomes less soluble in water. Choice A (NaCl) and Choice D (CaCl) do not exhibit a decrease in solubility with an increase in temperature. NaCl and CaCl are generally more soluble in water at higher temperatures. Choice B (Oxygen) is a gas and not typically considered in solubility discussions involving solids or liquids dissolving in water.
2. In the solid state, you would expect a nonmetal to be _________.
- A. brittle
- B. lustrous
- C. malleable
- D. conductive
Correct answer: A
Rationale: In the solid state, you would expect a nonmetal to be brittle. Nonmetals generally lack the malleability and ductility of metals, which makes them prone to being brittle and easily fractured under stress. This property is due to the lack of metallic bonding in nonmetals, which results in a more rigid and less flexible structure. Choice B, 'lustrous,' is incorrect because nonmetals typically do not exhibit a shiny or reflective surface like metals do. Choice C, 'malleable,' is also incorrect as nonmetals lack the ability to be hammered or rolled into thin sheets like metals. Choice D, 'conductive,' is incorrect since nonmetals are generally poor conductors of electricity compared to metals.
3. What is the product of the decomposition of water?
- A. Hydrogen and oxygen
- B. Carbon dioxide
- C. Nitrogen and hydrogen
- D. Methane
Correct answer: A
Rationale: The correct answer is A: Hydrogen and oxygen. When water undergoes decomposition, it breaks down into hydrogen and oxygen gases through a process known as electrolysis. This reaction is represented by 2H₂O → 2H₂ + O₂. Choice B, carbon dioxide, is incorrect as it is not a product of water decomposition. Choice C, nitrogen and hydrogen, is incorrect as water decomposes into hydrogen and oxygen, not nitrogen. Choice D, methane, is incorrect as methane is not a product of water decomposition.
4. Which classification best describes B, Si, As, Te, At, Ge, and Sb that form a staircase pattern on the right side of the periodic table?
- A. Metals
- B. Semimetals
- C. Nonmetals
- D. Ultrametals
Correct answer: B
Rationale: B, Si, As, Te, At, Ge, and Sb are located in a staircase pattern on the periodic table's right side. Elements in this region are known as metalloids or semimetals because they exhibit properties of both metals and nonmetals. They possess characteristics of both metallic and non-metallic elements, making them valuable semiconductors with diverse applications in electronics. Choice A is incorrect because these elements are not considered true metals. Choice C is incorrect as these elements do not display typical nonmetal properties exclusively. Choice D, 'Ultrametals,' is not a recognized classification in chemistry and is therefore incorrect.
5. In the periodic table, which group contains the alkali metals?
- A. Group 7
- B. Group 1
- C. Group 2
- D. Group 3
Correct answer: B
Rationale: The correct answer is Group 1. Alkali metals are found in Group 1 of the periodic table, which includes elements such as lithium, sodium, and potassium. These elements are known for their high reactivity and tendency to form alkaline solutions when they react with water. Therefore, Group 1 is specifically designated as the group containing alkali metals. Choice A (Group 7) is incorrect as Group 7 contains the halogens. Choice C (Group 2) is incorrect as Group 2 contains the alkaline earth metals. Choice D (Group 3) is incorrect as Group 3 contains the scandium group of elements.
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