which substance shows a decrease in solubility in water with an increase in temperature
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HESI A2

Chemistry Hesi A2

1. Which substance shows a decrease in solubility in water with an increase in temperature?

Correct answer: C

Rationale: Potassium iodide (KI) shows a decrease in solubility in water with an increase in temperature. This is due to the dissolution of KI in water being an endothermic process. When the temperature rises, the equilibrium shifts toward the solid state, leading to a decrease in solubility. Therefore, as the temperature increases, KI becomes less soluble in water. Choice A (NaCl) and Choice D (CaCl) do not exhibit a decrease in solubility with an increase in temperature. NaCl and CaCl are generally more soluble in water at higher temperatures. Choice B (Oxygen) is a gas and not typically considered in solubility discussions involving solids or liquids dissolving in water.

2. What is the oxidation state of the nitrogen atom in the compound NH3?

Correct answer: B

Rationale: In the compound NH3, nitrogen is bonded to three hydrogen atoms. Hydrogen is always assigned an oxidation state of +1. Since the overall charge of NH3 is zero, the oxidation state of nitrogen must be -1 to balance out the hydrogen's +1 oxidation state. Therefore, the correct oxidation state of the nitrogen atom in NH3 is -1. Choice A (-3) is incorrect because it does not account for the electronegativity of hydrogen. Choice C (+1) and Choice D (+3) are incorrect as the nitrogen atom in NH3 needs to balance the +1 oxidation state of each hydrogen atom, resulting in a total of -3 to maintain the compound's charge neutrality.

3. Identify the type of reaction shown: 8Fe + S → 8FeS

Correct answer: C

Rationale: The reaction shown (8Fe + S → 8FeS) is a synthesis reaction. In a synthesis reaction, two or more substances combine to form a single compound. In this case, iron (Fe) and sulfur (S) combine to form iron sulfide (FeS). The key characteristic of a synthesis reaction is the formation of a single product from multiple reactants, which aligns with the given chemical equation. Choice A, single displacement, involves an element displacing another in a compound, which is not the case here. Choice B, double displacement, involves the exchange of ions between two compounds, which is also not happening in this reaction. Choice D, acid-base, refers to reactions between an acid and a base to form salt and water, which is not the case in the given equation.

4. What is the main component of air?

Correct answer: B

Rationale: Nitrogen is the main component of air, constituting approximately 78% of the Earth's atmosphere. Oxygen, carbon dioxide, and argon are also present in smaller amounts, but nitrogen is the most abundant gas in the air. Therefore, the correct answer is B. Choice A, oxygen, is essential for respiration but makes up only about 21% of the atmosphere. Choice C, carbon dioxide, is vital for photosynthesis but exists in trace amounts in the air. Choice D, argon, is a noble gas found in relatively small quantities in the atmosphere.

5. In what type of covalent compounds are dispersion forces typically found?

Correct answer: B

Rationale: Dispersion forces, also known as London dispersion forces, are the weakest intermolecular forces that occur in non-polar covalent compounds. These forces result from temporary shifts in electron density within molecules, creating temporary dipoles. As a result, non-polar molecules, which lack a permanent dipole moment, can experience these dispersion forces. Polar compounds exhibit stronger intermolecular forces such as dipole-dipole interactions or hydrogen bonding, while ionic compounds involve electrostatic interactions between ions. Therefore, the correct answer is non-polar (choice B). Choices A, C, and D are incorrect because dispersion forces are typically found in non-polar covalent compounds, not polar, ionic, or hydrogen-bonded compounds.

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