which substance shows a decrease in solubility in water with an increase in temperature
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HESI A2

Chemistry Hesi A2

1. Which substance shows a decrease in solubility in water with an increase in temperature?

Correct answer: C

Rationale: Potassium iodide (KI) shows a decrease in solubility in water with an increase in temperature. This is due to the dissolution of KI in water being an endothermic process. When the temperature rises, the equilibrium shifts toward the solid state, leading to a decrease in solubility. Therefore, as the temperature increases, KI becomes less soluble in water. Choice A (NaCl) and Choice D (CaCl) do not exhibit a decrease in solubility with an increase in temperature. NaCl and CaCl are generally more soluble in water at higher temperatures. Choice B (Oxygen) is a gas and not typically considered in solubility discussions involving solids or liquids dissolving in water.

2. Which of the following is not an allotrope of carbon?

Correct answer: C

Rationale: The correct answer is C: Fluorine. Allotropes of carbon are different forms of the same element. Diamonds, graphite, and buckminsterfullerene are all allotropes of carbon. However, fluorine is a separate chemical element and not an allotrope of carbon. Therefore, fluorine does not belong to the group of carbon allotropes.

3. A radioactive isotope has a half-life of 20 years. How many grams of a 6-gram sample will remain after 40 years?

Correct answer: C

Rationale: The half-life of a radioactive isotope is the time it takes for half of the original sample to decay. After each half-life period, half of the initial sample remains. In this case, after the first 20 years, half of the 6-gram sample (3 grams) will remain. After another 20 years (total of 40 years), half of the remaining 3 grams will remain, which is 1.5 grams. Therefore, 3 grams will be left after 40 years. Choice A is incorrect as it doesn't consider the concept of half-life and incorrectly suggests an increase in the sample. Choice B is incorrect as it assumes no decay over time. Choice D is incorrect as it miscalculates the remaining amount after two half-life periods.

4. Which substance forms hydroxide ions when placed in water?

Correct answer: D

Rationale: The correct answer is D, lye. Lye, also known as sodium hydroxide (NaOH), is a strong base that forms hydroxide ions (OH-) when placed in water. When lye dissolves in water, it dissociates into sodium ions (Na+) and hydroxide ions, making it an alkaline substance. Lemon juice, battery acid, and vinegar do not form hydroxide ions when placed in water. Lemon juice contains citric acid, battery acid contains sulfuric acid, and vinegar contains acetic acid, none of which produce hydroxide ions when dissolved in water.

5. Which law states that matter can neither be created nor destroyed during a chemical reaction?

Correct answer: B

Rationale: The correct answer is B, the Law of Conservation of Mass. This law, formulated by Antoine Lavoisier, states that matter cannot be created or destroyed in a chemical reaction. It is a fundamental principle in chemistry that explains the preservation of mass during chemical reactions, indicating that the total mass of the reactants is equal to the total mass of the products. The other choices are incorrect because: A: The Law of Conservation of Energy states that energy cannot be created or destroyed, not matter. C: The Law of Constant Composition refers to compounds having the same composition by mass regardless of their source or how they were prepared, not about the conservation of matter in reactions. D: The Law of Multiple Proportions describes the ratios in which elements combine to form compounds, not the conservation of mass.

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