HESI A2
HESI A2 Chemistry
1. What is 0 K equal to in °C?
- A. -300°C
- B. -273°C
- C. -250°C
- D. -200°C
Correct answer: B
Rationale: 0 Kelvin, also known as absolute zero, is equal to -273°C. This is the point at which all molecular motion stops, making it the lowest possible temperature on the Kelvin scale. Choice A (-300°C) is incorrect as it is not the correct conversion of 0 K to °C. Choice C (-250°C) and Choice D (-200°C) are also incorrect as they do not correspond to the accurate conversion of 0 K to °C.
2. Which of these types of intermolecular force is the strongest?
- A. Dipole-dipole interaction
- B. London dispersion force
- C. Keesom interaction
- D. Hydrogen bonding
Correct answer: D
Rationale: Hydrogen bonding is the strongest type of intermolecular force among the options provided. It occurs when a hydrogen atom is covalently bonded to a highly electronegative atom (such as nitrogen, oxygen, or fluorine) and forms a strong electrostatic attraction with an unshared pair of electrons on another electronegative atom. This type of bond is stronger than dipole-dipole interactions, London dispersion forces, and Keesom interactions due to the significant electronegativity difference between the hydrogen and the electronegative atom involved in the bond. The presence of hydrogen bonding contributes to unique properties in substances, such as high boiling and melting points, making it a crucial force in various biological and chemical processes.
3. What is the name of the compound CH₃-CH₂-CH₂-CH₃?
- A. Cyclobutane
- B. Butane
- C. Butene
- D. Butyne
Correct answer: B
Rationale: The compound CH₃-CH₂-CH₂-CH₃ is named butane. Butane is a straight-chain alkane comprising four carbon atoms connected by single bonds. The prefix 'but-' denotes the presence of four carbon atoms, while the suffix '-ane' indicates it is an alkane with single bonds between the carbon atoms. Choice A, Cyclobutane, is incorrect as it refers to a cyclic hydrocarbon with four carbon atoms in a ring structure. Choice C, Butene, is incorrect because it is an alkene with a double bond between two carbon atoms, not a saturated hydrocarbon like butane. Choice D, Butyne, is also incorrect as it is an alkyne with a triple bond between two carbon atoms, unlike the single bonds in butane.
4. Which element has the highest electronegativity?
- A. Fluorine
- B. Chlorine
- C. Nitrogen
- D. Oxygen
Correct answer: A
Rationale: Fluorine has the highest electronegativity among the elements listed. Electronegativity is a measure of an atom's ability to attract and hold onto electrons in a chemical bond. Fluorine, being the most electronegative element on the periodic table, has the strongest ability to attract electrons towards itself compared to chlorine, nitrogen, and oxygen. Therefore, fluorine is the correct answer. Chlorine, nitrogen, and oxygen have lower electronegativities compared to fluorine, making them incorrect choices for the element with the highest electronegativity.
5. What is the correct formula for iron III oxide?
- A. IO
- B. FeS
- C. Fe₂O₃
- D. OFe₂₃
Correct answer: C
Rationale: The correct formula for iron III oxide is Fe2O3. In this formula, Fe represents iron and O represents oxygen. Iron III oxide consists of two iron (Fe) ions combined with three oxygen (O) ions. Thus, the correct formula is Fe2O3. Choice A (IO) is incorrect as it does not represent the correct combination of iron and oxygen ions. Choice B (FeS) is incorrect as it represents iron sulfide, not iron III oxide. Choice D (OFe₂₃) is incorrect as it does not follow the correct chemical nomenclature for iron III oxide.
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