what is a colligative property of a solution

HESI A2

HESI A2 Chemistry Questions

1. Which of the following is a colligative property of a solution?

A. Freezing point depression
B. Viscosity
C. Surface tension
D. Boiling point elevation

Correct answer: A

Rationale: A colligative property is a property that depends on the number of solute particles in a solution, not on the identity of the solute particles. Freezing point depression is one such property, where adding a solute to a solvent lowers the freezing point of the solution compared to the pure solvent. This phenomenon occurs because the presence of solute particles disrupts the formation of the regular crystal lattice structure, requiring a lower temperature for solidification to occur. Choices B, C, and D are not colligative properties. Viscosity and surface tension are not dependent on the number of solute particles but on intermolecular forces and molecular interactions. Boiling point elevation is another colligative property, but in this case, the question asked for a colligative property of a solution, making freezing point depression the correct answer.

2. Why does the diffusion rate increase as a substance is heated?

A. The kinetic energy of particles increases.
B. The space between particles increases.
C. The density of particles decreases.
D. The size of particles increases.

Correct answer: A

Rationale: The correct answer is A. When a substance is heated, the kinetic energy of particles increases, causing them to move faster. This increased movement allows the particles to spread out more rapidly, leading to a higher diffusion rate. Choice B is incorrect because heating does not directly affect the space between particles. Choice C is incorrect because heating does not necessarily lead to a decrease in the density of particles. Choice D is incorrect because the size of particles does not necessarily increase when a substance is heated. Therefore, the correct explanation for the increase in diffusion rate is the rise in kinetic energy of particles.

3. A chemist takes 100 mL of a 40 g NaCl solution and dilutes it to 1L. What is the concentration (molarity) of the new solution?

A. 0.04 M NaCl
B. 0.25 M NaCl
C. 0.40 M NaCl
D. 2.5 M NaCl

Correct answer: C

Rationale: Initially, the chemist has 40 g of NaCl in 100 mL of solution. To find the initial molarity, we need to calculate the number of moles of NaCl using the molar mass of NaCl (58.44 g/mol). After dilution to 1 L, the molarity of the new solution can be calculated by dividing the moles of NaCl by the total volume in liters. Therefore, the concentration (molarity) of the new solution is 0.40 M NaCl. Choice A (0.04 M NaCl) is incorrect because it doesn't consider the correct molar concentration after dilution. Choice B (0.25 M NaCl) is incorrect as it also doesn't account for the correct molar concentration post-dilution. Choice D (2.5 M NaCl) is incorrect as it is too concentrated given the initial amount of NaCl and the dilution factor.

4. What are the products of the combustion of a hydrocarbon?

A. Water and carbon dioxide
B. Water and oxygen
C. Hydrogen and carbon monoxide
D. Carbon dioxide and oxygen

Correct answer: A

Rationale: When a hydrocarbon undergoes combustion, it reacts with oxygen to produce water and carbon dioxide as the main products. The general chemical equation for the combustion of a hydrocarbon is hydrocarbon + oxygen → carbon dioxide + water. Therefore, the correct answer is 'Water and carbon dioxide.' Choices B, C, and D are incorrect because water and carbon dioxide are the primary products of hydrocarbon combustion, not water and oxygen, hydrogen and carbon monoxide, or carbon dioxide and oxygen.

5. What is the simplest form of a substance that is represented by a letter or letters?

A. Compound
B. Mixture
C. Element
D. Molecule

Correct answer: C

Rationale: The correct answer is C, 'Element.' An element is the most basic form of a substance that cannot be broken down further by chemical reactions. Each element is represented by a unique symbol, typically consisting of one or two letters. Choice A, 'Compound,' is incorrect as compounds are formed by the combination of two or more elements. Choice B, 'Mixture,' is also incorrect as mixtures are composed of two or more substances physically combined. Choice D, 'Molecule,' refers to the smallest unit of a compound that retains the chemical properties of that compound, not the simplest form of a substance represented by a symbol.