HESI A2
HESI A2 Chemistry Questions
1. Which of the following is a colligative property of a solution?
- A. Freezing point depression
- B. Viscosity
- C. Surface tension
- D. Boiling point elevation
Correct answer: A
Rationale: A colligative property is a property that depends on the number of solute particles in a solution, not on the identity of the solute particles. Freezing point depression is one such property, where adding a solute to a solvent lowers the freezing point of the solution compared to the pure solvent. This phenomenon occurs because the presence of solute particles disrupts the formation of the regular crystal lattice structure, requiring a lower temperature for solidification to occur. Choices B, C, and D are not colligative properties. Viscosity and surface tension are not dependent on the number of solute particles but on intermolecular forces and molecular interactions. Boiling point elevation is another colligative property, but in this case, the question asked for a colligative property of a solution, making freezing point depression the correct answer.
2. Which statement is true of a saturated solution?
- A. It has more solute than can dissolve in the solvent.
- B. It has less solute that can dissolve in the solvent.
- C. It has the maximum concentration of the solute dissolved in the solvent.
- D. It contains a precipitate that lowers the concentration of the solute in the solvent.
Correct answer: C
Rationale: A saturated solution contains the maximum concentration of solute that can be dissolved in a specific amount of solvent at a particular temperature. Once a solution is saturated, adding more solute will not increase its concentration since the excess solute will not dissolve and will instead form a precipitate, indicating that the solution is at its maximum capacity. Choices A, B, and D are incorrect because a saturated solution has reached its limit in dissolving solute, so it cannot contain more solute than it can dissolve (choice A), less solute than it can dissolve (choice B), or a precipitate that lowers the concentration of the solute in the solvent (choice D).
3. What effect does increasing the surface area of a reactant have?
- A. Decreases the reaction rate
- B. Has no effect
- C. Increases the reaction rate
- D. Stops the reaction
Correct answer: C
Rationale: Increasing the surface area of a reactant leads to more particles being exposed to the reaction, which in turn increases the reaction rate. This is because a larger surface area provides more sites for collisions between reacting particles, resulting in a higher frequency of successful collisions and thus accelerating the reaction. Choice A, 'Decreases the reaction rate,' is incorrect because increasing surface area actually accelerates the reaction. Choice B, 'Has no effect,' is incorrect as increasing surface area does have a significant effect on the reaction rate. Choice D, 'Stops the reaction,' is incorrect as increasing surface area does not stop the reaction but rather enhances it.
4. Which substance causes a drop to rapidly turn litmus dye from blue to red?
- A. Milk
- B. Sea water
- C. Ammonia
- D. Lemon juice
Correct answer: D
Rationale: Lemon juice is the correct answer as it is acidic in nature. Acids like lemon juice release hydrogen ions when dissolved in water, which causes litmus dye to change color from blue to red. Milk (Choice A) is neutral, sea water (Choice B) is slightly alkaline, and ammonia (Choice C) is a base. Therefore, these substances do not cause litmus dye to change from blue to red.
5. If gas A has four times the molar mass of gas B, you would expect it to diffuse through a plug ___________.
- A. at half the rate of gas B
- B. at twice the rate of gas B
- C. at a quarter the rate of gas B
- D. at four times the rate of gas B
Correct answer: A
Rationale: When comparing the diffusion rates of two gases, according to Graham's law of diffusion, the rate of diffusion is inversely proportional to the square root of the molar mass. If gas A has four times the molar mass of gas B, the square root of the molar masses ratio (4:1) is 2. This means that gas A would diffuse through a plug at half the rate of gas B. Therefore, the correct answer is A, at half the rate of gas B. Choices B, C, and D are incorrect because they do not reflect the correct relationship between the molar masses and the rates of diffusion according to Graham's law.
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