HESI A2
HESI A2 Chemistry Questions
1. Which of the following is a colligative property of a solution?
- A. Freezing point depression
- B. Viscosity
- C. Surface tension
- D. Boiling point elevation
Correct answer: A
Rationale: A colligative property is a property that depends on the number of solute particles in a solution, not on the identity of the solute particles. Freezing point depression is one such property, where adding a solute to a solvent lowers the freezing point of the solution compared to the pure solvent. This phenomenon occurs because the presence of solute particles disrupts the formation of the regular crystal lattice structure, requiring a lower temperature for solidification to occur. Choices B, C, and D are not colligative properties. Viscosity and surface tension are not dependent on the number of solute particles but on intermolecular forces and molecular interactions. Boiling point elevation is another colligative property, but in this case, the question asked for a colligative property of a solution, making freezing point depression the correct answer.
2. Which material has the smallest specific heat capacity?
- A. water
- B. wood
- C. aluminum
- D. glass
Correct answer: C
Rationale: Specific heat capacity is the amount of heat required to raise the temperature of a unit mass of a substance by one degree Celsius. Among the options provided, aluminum has the smallest specific heat capacity. This means that it requires the least amount of heat to raise its temperature compared to water, wood, and glass. Water has a high specific heat capacity, making it resistant to temperature changes, while wood and glass have higher specific heat capacities compared to aluminum.
3. Here are the solubilities of four substances at 0°C, in grams of solute per 100 mL of water. If the temperature increases to 20°C, what would you expect to happen to the solubility figures?
- A. Citric acid and potassium phosphate will decrease; nitrogen and oxygen will increase.
- B. Citric acid and potassium phosphate will increase; nitrogen and oxygen will decrease.
- C. All four figures will increase.
- D. All four figures will decrease.
Correct answer: C
Rationale: Solubility generally tends to increase with temperature for most solid solutes in liquid solvents due to higher kinetic energy leading to better solute-solvent interactions. As the temperature increases from 0°C to 20°C, all four solubility figures are expected to increase. Choice A is incorrect because solubility tends to increase with temperature. Choice B is incorrect as well for the same reason. Choice D is incorrect because the solubility of solid solutes typically increases with temperature.
4. Which type of radiation involves the emission of helium ions?
- A. Beta
- B. Alpha
- C. Gamma
- D. Delta
Correct answer: B
Rationale: Alpha radiation involves the emission of helium ions. Helium ions are composed of two protons and two neutrons, which is the same as the nucleus of a helium atom. This type of radiation has low penetration power and can be stopped by a piece of paper or human skin, making it less harmful compared to other forms of radiation like beta or gamma radiation. Beta radiation involves the emission of high-speed electrons, while gamma radiation involves electromagnetic waves with high energy. Delta radiation is not a recognized form of radiation in this context, making it an incorrect choice.
5. What is the simplest form of a substance that is represented by a letter or letters?
- A. Compound
- B. Mixture
- C. Element
- D. Molecule
Correct answer: C
Rationale: The correct answer is C, 'Element.' An element is the most basic form of a substance that cannot be broken down further by chemical reactions. Each element is represented by a unique symbol, typically consisting of one or two letters. Choice A, 'Compound,' is incorrect as compounds are formed by the combination of two or more elements. Choice B, 'Mixture,' is also incorrect as mixtures are composed of two or more substances physically combined. Choice D, 'Molecule,' refers to the smallest unit of a compound that retains the chemical properties of that compound, not the simplest form of a substance represented by a symbol.
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