HESI A2
HESI A2 Chemistry Questions
1. Which of the following is a colligative property of a solution?
- A. Freezing point depression
- B. Viscosity
- C. Surface tension
- D. Boiling point elevation
Correct answer: A
Rationale: A colligative property is a property that depends on the number of solute particles in a solution, not on the identity of the solute particles. Freezing point depression is one such property, where adding a solute to a solvent lowers the freezing point of the solution compared to the pure solvent. This phenomenon occurs because the presence of solute particles disrupts the formation of the regular crystal lattice structure, requiring a lower temperature for solidification to occur. Choices B, C, and D are not colligative properties. Viscosity and surface tension are not dependent on the number of solute particles but on intermolecular forces and molecular interactions. Boiling point elevation is another colligative property, but in this case, the question asked for a colligative property of a solution, making freezing point depression the correct answer.
2. If oxygen is in a compound, what would its oxidation number be?
- A. 2
- B. -2
- C. 0
- D. -1
Correct answer: B
Rationale: Oxygen typically has an oxidation number of -2 in compounds because it tends to gain electrons. This is due to its high electronegativity, which leads to oxygen attracting electrons towards itself in a chemical bond. Choice A (2) is incorrect because oxygen doesn't have a +2 oxidation number in compounds. Choice C (0) is incorrect as oxygen rarely has an oxidation number of 0 in compounds. Choice D (-1) is incorrect as oxygen's oxidation number in compounds is typically -2, not -1.
3. Which of the following best describes an endothermic reaction?
- A. A reaction that absorbs heat
- B. A reaction that releases heat
- C. A reaction that does not involve heat
- D. A reaction that remains at a constant temperature
Correct answer: A
Rationale: An endothermic reaction is a process that absorbs heat from its surroundings. When a reaction absorbs heat, it leads to a decrease in the temperature of the surroundings, making choice A the correct description. In an endothermic reaction, energy is taken in from the surroundings, resulting in a decrease in temperature around the reaction site. Choice B is incorrect because a reaction that releases heat is known as an exothermic reaction. Choice C is incorrect as all reactions involve heat to some extent. Choice D is incorrect as an endothermic reaction does not remain at a constant temperature but rather absorbs heat, leading to a temperature decrease in the surroundings.
4. What are mixtures of 2 or more metals called?
- A. Solutions
- B. Alloys
- C. Compounds
- D. Suspensions
Correct answer: B
Rationale: Alloys are mixtures of two or more metals, combining their properties to create materials with enhanced characteristics. Examples of alloys include bronze (copper and tin) and steel (iron and carbon). Alloys are commonly used in various industries due to their improved strength, durability, and other desirable qualities. Solutions (Choice A) refer to a homogeneous mixture of two or more substances, where one substance is dissolved in another. Compounds (Choice C) are substances composed of two or more elements chemically combined in fixed proportions. Suspensions (Choice D) are heterogeneous mixtures where particles are dispersed but can settle out over time.
5. What is 119 K in degrees Celsius?
- A. 32°C
- B. -154°C
- C. 154°C
- D. 0°C
Correct answer: B
Rationale: To convert Kelvin (K) to Celsius (°C), you subtract 273.15 from the Kelvin value. Therefore, 119 K - 273.15 = -154.15°C. The negative sign indicates that the temperature is below freezing. When rounded to the nearest whole number, -154.15°C is approximately -154°C. Choice A and Choice C are incorrect as they do not reflect the correct conversion from Kelvin to Celsius. Choice D is incorrect as it corresponds to the freezing point of water in Celsius, not the conversion of 119 K.
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