HESI A2
Chemistry Hesi A2
1. Which of these intermolecular forces might represent attraction between atoms of a noble gas?
- A. Dipole-dipole interaction
- B. London dispersion force
- C. Keesom interaction
- D. Hydrogen bonding
Correct answer: B
Rationale: Noble gases are non-polar molecules without a permanent dipole moment. The only intermolecular force applicable to noble gases is the London dispersion force, also known as Van der Waals forces. This force is a temporary attractive force resulting from the formation of temporary dipoles in non-polar molecules. Dipole-dipole interactions, Keesom interactions, and hydrogen bonding involve significant dipoles or hydrogen atoms bonded to electronegative atoms, which do not apply to noble gases.
2. What number represents the number of protons an element has?
- A. Atomic mass
- B. Mass number
- C. Atomic number
- D. Neutron number
Correct answer: C
Rationale: The correct answer is C, atomic number. The atomic number corresponds to the number of protons in an element. This number is unique to each element and determines its placement on the periodic table. It is equal to the number of protons found in the nucleus of an atom of that element. Choice A, atomic mass, represents the average mass of an element's isotopes. Choice B, mass number, is the sum of protons and neutrons in an atom. Choice D, neutron number, specifically refers to the count of neutrons in an atom and not protons.
3. Which ion would you expect to dominate in water solutions of bases?
- A. MgCl₂
- B. 2HCl
- C. H⁺
- D. OH⁻
Correct answer: D
Rationale: In water solutions of bases, the dominant ion would be OH⁻ (hydroxide ion). Bases release OH⁻ ions when dissolved in water, increasing the concentration of hydroxide ions and leading to a higher pH. This is in contrast to acids, which release H⁺ ions. Therefore, in water solutions of bases, the presence of OH⁻ ions signifies the basic nature of the solution. Choices A, B, and C are incorrect because MgCl₂ is a salt, 2HCl is a compound consisting of two hydrogen ions and one chloride ion, and H⁺ represents a hydrogen ion typically associated with acids, not bases.
4. Which elements are typically involved in hydrogen bonding?
- A. Carbon, hydrogen, oxygen
- B. Fluorine, chlorine, oxygen
- C. Fluorine, chlorine, nitrogen
- D. Fluorine, oxygen, nitrogen
Correct answer: D
Rationale: Hydrogen bonding occurs between hydrogen and highly electronegative atoms such as fluorine, oxygen, and nitrogen. These atoms have a strong pull on the shared electrons, leading to a partial negative charge on them, which allows them to form hydrogen bonds with hydrogen or other electronegative atoms. Choice A is incorrect because carbon is not typically involved in hydrogen bonding. Choice B is incorrect because chlorine is not as electronegative as nitrogen, and choice C is incorrect because nitrogen is more electronegative than chlorine.
5. What is the charge of an alpha particle?
- A. -1
- B. +1
- C. +2
- D. No charge
Correct answer: C
Rationale: An alpha particle consists of two protons and two neutrons, resulting in a total charge of +2 due to the presence of two positively charged protons. Therefore, the correct answer is C, indicating a charge of +2. Choices A, B, and D are incorrect because an alpha particle is positively charged due to the two protons it contains, resulting in a charge of +2.
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