HESI A2
Chemistry Hesi A2
1. Which of these intermolecular forces might represent attraction between atoms of a noble gas?
- A. Dipole-dipole interaction
- B. London dispersion force
- C. Keesom interaction
- D. Hydrogen bonding
Correct answer: B
Rationale: Noble gases are non-polar molecules without a permanent dipole moment. The only intermolecular force applicable to noble gases is the London dispersion force, also known as Van der Waals forces. This force is a temporary attractive force resulting from the formation of temporary dipoles in non-polar molecules. Dipole-dipole interactions, Keesom interactions, and hydrogen bonding involve significant dipoles or hydrogen atoms bonded to electronegative atoms, which do not apply to noble gases.
2. In what type of covalent compounds are dispersion forces typically found?
- A. Polar
- B. Non-polar
- C. Ionic
- D. Hydrogen
Correct answer: B
Rationale: Dispersion forces, also known as London dispersion forces, are the weakest intermolecular forces that occur in non-polar covalent compounds. These forces result from temporary shifts in electron density within molecules, creating temporary dipoles. As a result, non-polar molecules, which lack a permanent dipole moment, can experience these dispersion forces. Polar compounds exhibit stronger intermolecular forces such as dipole-dipole interactions or hydrogen bonding, while ionic compounds involve electrostatic interactions between ions. Therefore, the correct answer is non-polar (choice B). Choices A, C, and D are incorrect because dispersion forces are typically found in non-polar covalent compounds, not polar, ionic, or hydrogen-bonded compounds.
3. Which type of chemical bond is the strongest?
- A. Ionic
- B. Hydrogen
- C. Covalent
- D. Metallic
Correct answer: C
Rationale: Covalent bonds, especially those formed between non-metals, are the strongest type of chemical bond. In covalent bonds, atoms share electrons, creating a strong bond that requires a significant amount of energy to break. Choice A, ionic bonds, are strong but generally weaker than covalent bonds as they involve the transfer of electrons rather than sharing. Choice B, hydrogen bonds, are relatively weak intermolecular forces, not true chemical bonds. Choice D, metallic bonds, are strong but typically not as strong as covalent bonds. Metallic bonds involve a 'sea of electrons' shared between metal atoms, providing strength but with less directional bonding compared to covalent bonds.
4. Which of these represents a strong acid?
- A. CH₃COOH
- B. Hâ‚‚SOâ‚„
- C. NH₃
- D. KOH
Correct answer: B
Rationale: Among the options provided, H₂SO₄ (sulfuric acid) represents a strong acid. Strong acids completely ionize in water to produce a high concentration of H+ ions. Sulfuric acid is a strong acid known for its ability to dissociate almost completely in water, making it a strong acid. Choice A, CH₃COOH (acetic acid), is a weak acid that only partially dissociates in water. Choices C and D, NH₃ (ammonia) and KOH (potassium hydroxide), are bases and not acids.
5. What is the correct formula for sodium nitrate?
- A. NaNO
- B. Na NO
- C. NaNO₃
- D. Na NOâ‚‚
Correct answer: C
Rationale: The correct formula for sodium nitrate is NaNO₃. In this formula, 'Na' represents sodium, 'N' represents nitrogen, and 'O₃' represents three oxygen atoms. Sodium nitrate consists of one sodium ion (Naâº) and one nitrate ion (NO₃â»), which means the correct formula is NaNO₃. Choice A (NaNO) is incorrect as it lacks the subscript indicating the presence of three oxygen atoms. Choice B (Na NO) is incorrect as it includes a space between 'Na' and 'NO', which is not part of the standard chemical formula notation. Choice D (Na NOâ‚‚) is incorrect as it indicates a different compound with a nitrite ion (NOâ‚‚â») instead of nitrate ion.
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