HESI A2
Chemistry Hesi A2
1. Which of these intermolecular forces might represent attraction between atoms of a noble gas?
- A. Dipole-dipole interaction
- B. London dispersion force
- C. Keesom interaction
- D. Hydrogen bonding
Correct answer: B
Rationale: Noble gases are non-polar molecules without a permanent dipole moment. The only intermolecular force applicable to noble gases is the London dispersion force, also known as Van der Waals forces. This force is a temporary attractive force resulting from the formation of temporary dipoles in non-polar molecules. Dipole-dipole interactions, Keesom interactions, and hydrogen bonding involve significant dipoles or hydrogen atoms bonded to electronegative atoms, which do not apply to noble gases.
2. Which of the following elements is a halogen?
- A. Oxygen
- B. Fluorine
- C. Sodium
- D. Carbon
Correct answer: B
Rationale: The correct answer is 'Fluorine' (Choice B) as it is a halogen. Halogens are a group of elements that include fluorine, chlorine, bromine, iodine, and astatine. They are highly reactive nonmetals located in Group 17 of the periodic table. Oxygen (Choice A) is a nonmetal but not a halogen. Sodium (Choice C) is a metal, and Carbon (Choice D) is a nonmetal, neither of which belong to the halogen group.
3. Which element is considered a noble gas?
- A. Oxygen
- B. Neon
- C. Hydrogen
- D. Argon
Correct answer: B
Rationale: The correct answer is 'Neon.' Noble gases are a group of elements with very low reactivity. Neon is one of these elements, known for its stable and unreactive nature. Oxygen, hydrogen, and argon do not belong to the noble gas group. Oxygen is a reactive non-metal, hydrogen is a non-metal and the first element in the periodic table, and argon is a noble gas like neon but not the correct answer in this case.
4. Which of the following elements does not exist as a diatomic molecule?
- A. boron
- B. fluorine
- C. oxygen
- D. nitrogen
Correct answer: A
Rationale: The correct answer is 'boron.' Diatomic molecules consist of two atoms of the same element bonded together. Boron is an exception and does not exist naturally as a diatomic molecule. On the other hand, fluorine, oxygen, and nitrogen commonly exist as diatomic molecules in their natural states. Fluorine, for example, exists as F2, oxygen exists as O2, and nitrogen exists as N2.
5. Why does fluorine have a higher ionization energy than oxygen?
- A. Fluorine has a smaller number of neutrons.
- B. Fluorine has a larger number of neutrons.
- C. Fluorine has a smaller nuclear charge.
- D. Fluorine has a larger nuclear charge.
Correct answer: D
Rationale: Fluorine has a higher ionization energy than oxygen because fluorine has a larger nuclear charge. The greater number of protons in the nucleus of fluorine attracts its electrons more strongly, making it harder to remove an electron from a fluorine atom compared to an oxygen atom. Choice A is incorrect as the number of neutrons does not directly affect ionization energy. Choice B is also incorrect for the same reason. Choice C is incorrect because a smaller nuclear charge would result in lower ionization energy, not higher.
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