HESI A2
HESI A2 Chemistry Questions
1. Which of the following elements does not exist as a diatomic molecule?
- A. boron
- B. fluorine
- C. oxygen
- D. nitrogen
Correct answer: A
Rationale: The correct answer is 'boron.' Diatomic molecules consist of two atoms of the same element bonded together. Boron is an exception and does not exist naturally as a diatomic molecule. On the other hand, fluorine, oxygen, and nitrogen commonly exist as diatomic molecules in their natural states. Fluorine, for example, exists as F2, oxygen exists as O2, and nitrogen exists as N2.
2. Why does fluorine have a higher ionization energy than oxygen?
- A. Fluorine has a smaller number of neutrons.
- B. Fluorine has a larger number of neutrons.
- C. Fluorine has a smaller nuclear charge.
- D. Fluorine has a larger nuclear charge.
Correct answer: D
Rationale: Fluorine has a higher ionization energy than oxygen because fluorine has a larger nuclear charge. The greater number of protons in the nucleus of fluorine attracts its electrons more strongly, making it harder to remove an electron from a fluorine atom compared to an oxygen atom. Choice A is incorrect as the number of neutrons does not directly affect ionization energy. Choice B is also incorrect for the same reason. Choice C is incorrect because a smaller nuclear charge would result in lower ionization energy, not higher.
3. Which intermolecular force is the strongest?
- A. Dipole interactions
- B. Dispersion forces
- C. Hydrogen bonding
- D. Van der Waals forces
Correct answer: C
Rationale: Hydrogen bonding is the strongest intermolecular force due to its specific interaction between a hydrogen atom and a highly electronegative atom like nitrogen, oxygen, or fluorine. This type of bonding results in a very strong attraction between molecules, making it the strongest intermolecular force among the options provided. Dipole interactions (choice A) are weaker than hydrogen bonding as they occur between polar molecules. Dispersion forces (choice B) are the weakest intermolecular forces and are caused by temporary fluctuations in electron distribution. Van der Waals forces (choice D) are a broader term that encompasses dipole interactions and dispersion forces, making them weaker than hydrogen bonding.
4. What charge do Group IIIA elements have?
- A. +1
- B. +2
- C. +3
- D. 0
Correct answer: C
Rationale: Group IIIA elements, also known as Group 13 elements, have a common oxidation state of +3. This is because they have three valence electrons and tend to lose these electrons to achieve a stable electron configuration, resulting in a +3 charge. Choice A (+1) and Choice B (+2) are incorrect because Group IIIA elements typically lose all three valence electrons to attain a stable configuration, leading to a +3 charge. Choice D (0) is incorrect as these elements do not gain electrons but rather lose them, resulting in a positive charge.
5. If electrons are shared equally in a covalent bond, the bond is classified as what?
- A. Polar
- B. Non-polar
- C. Ionic
- D. Hydrogen
Correct answer: B
Rationale: The correct answer is B: Non-polar. In a non-polar covalent bond, electrons are shared equally between the atoms involved, leading to a balanced distribution of charge and no significant difference in electronegativity between the atoms. This equal sharing results in a non-polar bond. Choices A, C, and D are incorrect because a polar bond involves an unequal sharing of electrons, an ionic bond is formed by the transfer of electrons, and a hydrogen bond is a specific type of non-covalent bond.
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