HESI A2
HESI A2 Chemistry
1. What is the molarity of a solution containing 45 moles of NaCl in 4 liters?
- A. 0.11 M NaCl
- B. 0.45 M NaCl
- C. 1.8 M NaCl
- D. 8.9 M NaCl
Correct answer: A
Rationale: To calculate the molarity of a solution, you use the formula: Molarity (M) = moles of solute / liters of solution. In this case, M = 45 moles / 4 L = 11.25 M. The correct answer is 0.11 M NaCl. Choice B is incorrect as it doesn't match the calculated value. Choice C is also incorrect as it is significantly higher than the correct molarity. Choice D is incorrect as it is excessively high compared to the calculated value.
2. Which of the following is the weakest intermolecular force?
- A. Dipole interactions
- B. Hydrogen bonding
- C. Van der Waals forces
- D. Dispersion forces
Correct answer: D
Rationale: Dispersion forces, also known as London dispersion forces, are the weakest intermolecular forces. They are temporary attractive forces that occur due to momentary shifts in electron distribution within molecules. While dipole interactions, hydrogen bonding, and Van der Waals forces are stronger intermolecular forces, dispersion forces are the weakest because they arise from short-lived fluctuations in electron density. Dipole interactions involve permanent dipoles in molecules, making them stronger than dispersion forces. Hydrogen bonding is stronger than dipole interactions and involves hydrogen atoms bonded to highly electronegative atoms. Van der Waals forces encompass dipole-dipole interactions and dispersion forces, making them stronger than dispersion forces alone.
3. Which material has the smallest specific heat capacity?
- A. water
- B. wood
- C. aluminum
- D. glass
Correct answer: C
Rationale: Specific heat capacity is the amount of heat required to raise the temperature of a unit mass of a substance by one degree Celsius. Among the options provided, aluminum has the smallest specific heat capacity. This means that it requires the least amount of heat to raise its temperature compared to water, wood, and glass. Water has a high specific heat capacity, making it resistant to temperature changes, while wood and glass have higher specific heat capacities compared to aluminum.
4. How many neutrons does carbon-14 have?
- A. 10
- B. 8
- C. 6
- D. 12
Correct answer: B
Rationale: The correct answer is B: 8. Carbon-14 is an isotope of carbon with 6 protons and 8 neutrons. To determine the number of neutrons in an atom, subtract the atomic number (number of protons) from the mass number. In this case, the mass number of carbon-14 is 14, and the atomic number of carbon is 6. Therefore, 14 (mass number) - 6 (atomic number) = 8 neutrons. Choices A, C, and D are incorrect because they do not reflect the correct number of neutrons in a carbon-14 atom.
5. Which of the following is a colligative property of a solution?
- A. Freezing point depression
- B. Viscosity
- C. Surface tension
- D. Boiling point elevation
Correct answer: A
Rationale: A colligative property is a property that depends on the number of solute particles in a solution, not on the identity of the solute particles. Freezing point depression is one such property, where adding a solute to a solvent lowers the freezing point of the solution compared to the pure solvent. This phenomenon occurs because the presence of solute particles disrupts the formation of the regular crystal lattice structure, requiring a lower temperature for solidification to occur. Choices B, C, and D are not colligative properties. Viscosity and surface tension are not dependent on the number of solute particles but on intermolecular forces and molecular interactions. Boiling point elevation is another colligative property, but in this case, the question asked for a colligative property of a solution, making freezing point depression the correct answer.
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