HESI A2
HESI A2 Chemistry Practice Test
1. What is the oxidation state of the sulfur atom in sulfuric acid H2SO4?
- A. 4
- B. 6
- C. 8
- D. 10
Correct answer: B
Rationale: In sulfuric acid (H2SO4), sulfur has an oxidation state of +6. The oxidation state is determined by considering the overall charge of the compound and the known oxidation states of other elements. In this case, hydrogen is typically +1, and oxygen is -2. To balance the charges and match the compound's overall charge of 0, sulfur must have an oxidation state of +6. Choice A (4) is incorrect because it doesn't balance the charges in the compound. Choices C (8) and D (10) are also incorrect as they are not valid oxidation states for sulfur in this compound.
2. How many neutrons are in an atom of uranium-235?
- A. 92
- B. 125
- C. 143
- D. 235
Correct answer: A
Rationale: The correct answer is A: '92'. To determine the number of neutrons in an atom, you subtract the atomic number (number of protons) from the atomic mass number. For uranium-235, the atomic number is 92, and the atomic mass number is 235. Subtracting 92 from 235 gives us 143 neutrons in an atom of uranium-235. Therefore, options B, C, and D are incorrect as they do not represent the correct number of neutrons in an atom of uranium-235.
3. Which compound has a nonpolar bond in which the electrons are shared equally?
- A. H₂O
- B. NH₃
- C. Cl₂
- D. CH₄
Correct answer: D
Rationale: The compound CH₄, methane, has a nonpolar bond where carbon and hydrogen share electrons equally. This occurs because carbon and hydrogen have similar electronegativities, meaning they have equal abilities to attract shared electrons. Consequently, a nonpolar covalent bond is formed due to the balanced sharing of electrons between these atoms. Choices A, B, and C do not have nonpolar bonds with electrons shared equally. In H₂O (water), there are polar covalent bonds due to the difference in electronegativity between hydrogen and oxygen. In NH₃ (ammonia), the nitrogen-hydrogen bonds are polar because of the electronegativity difference. In Cl₂ (chlorine gas), the Cl-Cl bond is nonpolar, but the question specifies a compound, not an element, and chlorine does not share its electrons equally with another element in a compound.
4. Which two functional groups would you expect an amino acid to contain?
- A. R-NH2 and R-COOH
- B. R-CHO and R-CO-NH
- C. R-OH and R-COOR
- D. R-O-R and R-COOH
Correct answer: A
Rationale: Amino acids are organic compounds that are characterized by the presence of an amino group (NH2) and a carboxylic acid group (COOH) in their chemical structure. These two functional groups, found in option A, are fundamental components of amino acids and play crucial roles in their classification and biological functions. Option B contains an aldehyde group (CHO) and an amide group (CO-NH), which are not characteristic functional groups of amino acids. Option C includes a hydroxyl group (OH) and an ester group (COOR), which are not typically present in amino acids. Option D presents ether (R-O-R) and carboxylic acid (COOH) functional groups, which do not represent the functional groups commonly found in amino acids.
5. What is the correct electron configuration for magnesium?
- A. 1s² 2s²
- B. 1s² 2s² 2p⁶
- C. 1s² 2s² 2p⁶ 3s²
- D. 1s² 2s² 2p⁶ 3s² 3p¹
Correct answer: C
Rationale: The electron configuration of an element is determined by following the Aufbau principle, which states that electrons fill orbitals starting from the lowest energy level. Magnesium has an atomic number of 12, meaning it has 12 electrons. The electron configuration of magnesium fills the 1s, 2s, 2p, and 3s orbitals to accommodate all 12 electrons. Therefore, the correct electron configuration for magnesium is 1s² 2s² 2p⁶ 3s². Choice A is incorrect as it only includes 4 electrons and stops at the 2s orbital. Choice B is incorrect as it includes 8 electrons and stops at the 2p orbital. Choice D is incorrect as it includes 13 electrons and extends to the 3p orbital, which is beyond the actual electron configuration of magnesium.
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