HESI A2
HESI A2 Chemistry Questions
1. Which of the following best describes an endothermic reaction?
- A. A reaction that absorbs heat
- B. A reaction that releases heat
- C. A reaction that does not involve heat
- D. A reaction that remains at a constant temperature
Correct answer: A
Rationale: An endothermic reaction is a process that absorbs heat from its surroundings. When a reaction absorbs heat, it leads to a decrease in the temperature of the surroundings, making choice A the correct description. In an endothermic reaction, energy is taken in from the surroundings, resulting in a decrease in temperature around the reaction site. Choice B is incorrect because a reaction that releases heat is known as an exothermic reaction. Choice C is incorrect as all reactions involve heat to some extent. Choice D is incorrect as an endothermic reaction does not remain at a constant temperature but rather absorbs heat, leading to a temperature decrease in the surroundings.
2. What is the correct electron configuration for magnesium?
- A. 1s² 2s²
- B. 1s² 2s² 2p⁶
- C. 1s² 2s² 2p⁶ 3s²
- D. 1s² 2s² 2p⁶ 3s² 3p¹
Correct answer: C
Rationale: The electron configuration of an element is determined by following the Aufbau principle, which states that electrons fill orbitals starting from the lowest energy level. Magnesium has an atomic number of 12, meaning it has 12 electrons. The electron configuration of magnesium fills the 1s, 2s, 2p, and 3s orbitals to accommodate all 12 electrons. Therefore, the correct electron configuration for magnesium is 1s² 2s² 2p⁶ 3s². Choice A is incorrect as it only includes 4 electrons and stops at the 2s orbital. Choice B is incorrect as it includes 8 electrons and stops at the 2p orbital. Choice D is incorrect as it includes 13 electrons and extends to the 3p orbital, which is beyond the actual electron configuration of magnesium.
3. Which two elements are most alike in reactivity?
- A. He and H
- B. K and Ar
- C. Cl and P
- D. Ba and Mg
Correct answer: C
Rationale: Chlorine (Cl) and Phosphorus (P) are most alike in reactivity among the given pairs. Both elements are nonmetals and belong to Group 7 (halogens) and Group 15 (nitrogen group), respectively. They have similar electronic configurations and can form compounds by gaining or sharing electrons. Chlorine is highly reactive and can easily form ionic compounds, while phosphorus also shows a range of reactivity in its compounds. Choice A (He and H) is incorrect because helium (He) is a noble gas and hydrogen (H) is a nonmetal, so they are not similar in reactivity. Choice B (K and Ar) is incorrect as potassium (K) is a metal and argon (Ar) is a noble gas, having different reactivities. Choice D (Ba and Mg) is incorrect because barium (Ba) and magnesium (Mg) are both metals, but their reactivities differ due to their positions in the periodic table.
4. What type of chemical reaction involves the reaction of a compound with oxygen?
- A. Decomposition
- B. Synthesis
- C. Combustion
- D. Single replacement
Correct answer: C
Rationale: The correct answer is C: Combustion. A combustion reaction is characterized by a compound reacting with oxygen. During this process, heat and light are often produced as energy is released in the form of heat. Combustion is a common type of reaction involving organic compounds, like hydrocarbons, reacting with oxygen to produce carbon dioxide and water. Choices A, B, and D are incorrect because decomposition involves a compound breaking down into simpler substances, synthesis involves the combination of two or more substances to form a more complex one, and single replacement involves an element replacing another element in a compound.
5. What is the chemical reaction that involves breaking down a compound into component parts?
- A. Decomposition
- B. Synthesis
- C. Combustion
- D. Single replacement
Correct answer: A
Rationale: Decomposition is the correct answer because in a decomposition reaction, a compound is broken down into simpler substances. This type of reaction involves the splitting of a compound into its component parts, often through the use of heat, light, or electricity. Synthesis (choice B) is the opposite process where simpler substances are combined to form a more complex compound. Combustion (choice C) is a reaction involving rapid oxidation often accompanied by heat and light. Single replacement (choice D) is a reaction where one element replaces another in a compound.
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