you would expect an amino acid to contain which two functional groups

HESI A2

Chemistry HESI A2 Practice Test

1. Which two functional groups would you expect an amino acid to contain?

A. R-NH2 and R-COOH
B. R-CHO and R-CO-NH
C. R-OH and R-COOR
D. R-O-R and R-COOH

Correct answer: A

Rationale: Amino acids are organic compounds that are characterized by the presence of an amino group (NH2) and a carboxylic acid group (COOH) in their chemical structure. These two functional groups, found in option A, are fundamental components of amino acids and play crucial roles in their classification and biological functions. Option B contains an aldehyde group (CHO) and an amide group (CO-NH), which are not characteristic functional groups of amino acids. Option C includes a hydroxyl group (OH) and an ester group (COOR), which are not typically present in amino acids. Option D presents ether (R-O-R) and carboxylic acid (COOH) functional groups, which do not represent the functional groups commonly found in amino acids.

2. If gas A has four times the molar mass of gas B, you would expect it to diffuse through a plug ___________.

A. at half the rate of gas B
B. at twice the rate of gas B
C. at a quarter the rate of gas B
D. at four times the rate of gas B

Correct answer: A

Rationale: When comparing the diffusion rates of two gases, according to Graham's law of diffusion, the rate of diffusion is inversely proportional to the square root of the molar mass. If gas A has four times the molar mass of gas B, the square root of the molar masses ratio (4:1) is 2. This means that gas A would diffuse through a plug at half the rate of gas B. Therefore, the correct answer is A, at half the rate of gas B. Choices B, C, and D are incorrect because they do not reflect the correct relationship between the molar masses and the rates of diffusion according to Graham's law.

3. Which intermolecular force is the strongest?

A. Dipole interactions
B. Dispersion forces
C. Hydrogen bonding
D. Van der Waals forces

Correct answer: C

Rationale: Hydrogen bonding is the strongest intermolecular force due to its specific interaction between a hydrogen atom and a highly electronegative atom like nitrogen, oxygen, or fluorine. This type of bonding results in a very strong attraction between molecules, making it the strongest intermolecular force among the options provided. Dipole interactions (choice A) are weaker than hydrogen bonding as they occur between polar molecules. Dispersion forces (choice B) are the weakest intermolecular forces and are caused by temporary fluctuations in electron distribution. Van der Waals forces (choice D) are a broader term that encompasses dipole interactions and dispersion forces, making them weaker than hydrogen bonding.

4. How many neutrons are in an atom of carbon-12?

A. 2
B. 4
C. 6
D. 24

Correct answer: C

Rationale: An atom of carbon-12 has 6 neutrons. The atomic number of carbon is 6, representing the number of protons. The atomic mass of carbon-12 is 12. To find the number of neutrons, subtract the atomic number from the atomic mass: 12 - 6 = 6 neutrons. Choice A, 2, is incorrect as it does not reflect the correct calculation for neutrons in carbon-12. Choice B, 4, is incorrect as it does not match the correct number of neutrons in carbon-12. Choice D, 24, is incorrect as it is significantly higher than the actual number of neutrons in carbon-12.

5. What is the correct electron configuration for magnesium?

A. 1s² 2s²
B. 1s² 2s² 2p⁶
C. 1s² 2s² 2p⁶ 3s²
D. 1s² 2s² 2p⁶ 3s² 3p¹

Correct answer: C

Rationale: The electron configuration of an element is determined by following the Aufbau principle, which states that electrons fill orbitals starting from the lowest energy level. Magnesium has an atomic number of 12, meaning it has 12 electrons. The electron configuration of magnesium fills the 1s, 2s, 2p, and 3s orbitals to accommodate all 12 electrons. Therefore, the correct electron configuration for magnesium is 1s² 2s² 2p⁶ 3s². Choice A is incorrect as it only includes 4 electrons and stops at the 2s orbital. Choice B is incorrect as it includes 8 electrons and stops at the 2p orbital. Choice D is incorrect as it includes 13 electrons and extends to the 3p orbital, which is beyond the actual electron configuration of magnesium.