HESI A2
Chemistry HESI A2 Practice Test
1. Which two functional groups would you expect an amino acid to contain?
- A. R-NH2 and R-COOH
- B. R-CHO and R-CO-NH
- C. R-OH and R-COOR
- D. R-O-R and R-COOH
Correct answer: A
Rationale: Amino acids are organic compounds that are characterized by the presence of an amino group (NH2) and a carboxylic acid group (COOH) in their chemical structure. These two functional groups, found in option A, are fundamental components of amino acids and play crucial roles in their classification and biological functions. Option B contains an aldehyde group (CHO) and an amide group (CO-NH), which are not characteristic functional groups of amino acids. Option C includes a hydroxyl group (OH) and an ester group (COOR), which are not typically present in amino acids. Option D presents ether (R-O-R) and carboxylic acid (COOH) functional groups, which do not represent the functional groups commonly found in amino acids.
2. Which of the following best describes an endothermic reaction?
- A. A reaction that absorbs heat
- B. A reaction that releases heat
- C. A reaction that does not involve heat
- D. A reaction that remains at a constant temperature
Correct answer: A
Rationale: An endothermic reaction is a process that absorbs heat from its surroundings. When a reaction absorbs heat, it leads to a decrease in the temperature of the surroundings, making choice A the correct description. In an endothermic reaction, energy is taken in from the surroundings, resulting in a decrease in temperature around the reaction site. Choice B is incorrect because a reaction that releases heat is known as an exothermic reaction. Choice C is incorrect as all reactions involve heat to some extent. Choice D is incorrect as an endothermic reaction does not remain at a constant temperature but rather absorbs heat, leading to a temperature decrease in the surroundings.
3. Which element has the highest atomic number?
- A. Uranium
- B. Hydrogen
- C. Radon
- D. Bismuth
Correct answer: A
Rationale: The correct answer is Uranium. The atomic number represents the number of protons in an atom's nucleus. Among the options provided, Uranium has the highest atomic number, which is 92. Hydrogen has an atomic number of 1, Radon has an atomic number of 86, and Bismuth has an atomic number of 83. Therefore, Uranium is the element with the highest atomic number in the given choices.
4. Which of these types of intermolecular force is the strongest?
- A. Dipole-dipole interaction
- B. London dispersion force
- C. Keesom interaction
- D. Hydrogen bonding
Correct answer: D
Rationale: Hydrogen bonding is the strongest type of intermolecular force among the options provided. It occurs when a hydrogen atom is covalently bonded to a highly electronegative atom (such as nitrogen, oxygen, or fluorine) and forms a strong electrostatic attraction with an unshared pair of electrons on another electronegative atom. This type of bond is stronger than dipole-dipole interactions, London dispersion forces, and Keesom interactions due to the significant electronegativity difference between the hydrogen and the electronegative atom involved in the bond. The presence of hydrogen bonding contributes to unique properties in substances, such as high boiling and melting points, making it a crucial force in various biological and chemical processes.
5. To the nearest whole number, what is the mass of one mole of hydrogen iodide?
- A. 2 g/mol
- B. 58 g/mol
- C. 87 g/mol
- D. 128 g/mol
Correct answer: C
Rationale: The molar mass of hydrogen iodide (HI) is the sum of the atomic masses of its constituent elements. Hydrogen (H) has a molar mass of approximately 1 g/mol, and iodine (I) has a molar mass of about 127 g/mol. Thus, the molar mass of hydrogen iodide (HI) is approximately 1 + 127 = 128 g/mol. Rounding to the nearest whole number, the molar mass of hydrogen iodide is 128 g/mol, which is closest to choice C. Choice A (2 g/mol) is too low and does not reflect the correct molar mass of hydrogen iodide. Choice B (58 g/mol) is significantly lower than the actual molar mass. Choice D (128 g/mol) matches the calculated molar mass but is not the nearest whole number as requested.
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