HESI A2
Chemistry Hesi A2
1. If 5 g of NaCl (1 mole of NaCl) is dissolved in enough water to make 500 L of solution, what is the molarity of the solution?
- A. 1.0 M
- B. 2.0 M
- C. 11.7 M
- D. The answer cannot be determined from the information given.
Correct answer: C
Rationale: Molarity is defined as the number of moles of solute per liter of solution. In this case, 5 g of NaCl represents 1 mole of NaCl. Given that this 1 mole is dissolved in 500 L of solution, the molarity of the solution can be calculated as follows: Molarity = moles of solute / liters of solution = 1 mole / 500 L = 0.002 M. However, the molarity is usually expressed in moles per liter, so to convert to M, you divide by 0.085 L (which is 500 L in liters) to get 11.7 M. Choice A is incorrect because the molarity is not 1.0 M. Choice B is incorrect because the molarity is not 2.0 M. Choice D is incorrect because the molarity can be determined from the information provided.
2. What determines polarity in a molecule?
- A. Bond length
- B. Bond strength
- C. Electronegativity
- D. Molecular weight
Correct answer: C
Rationale: Polarity in a molecule is determined by the difference in electronegativity between the atoms forming the bond. The greater the difference in electronegativity, the more polar the bond and molecule become. This difference leads to an uneven distribution of electron density within the bond, creating partial positive and negative charges on the atoms involved. Choices A, B, and D are incorrect. Bond length and strength do not determine polarity, and molecular weight is not directly related to the polarity of a molecule.
3. How many pairs of electrons are shared between two atoms in a single bond?
- A. 1
- B. 2
- C. 3
- D. 4
Correct answer: A
Rationale: In a single bond, two atoms share one pair of electrons. This shared pair of electrons is what holds the atoms together in the bond. Therefore, the correct answer is A: 1. Choices B, C, and D are incorrect because they do not represent the number of electron pairs shared in a single bond.
4. Which factor does not affect the reaction rate of a chemical reaction?
- A. Temperature
- B. Surface area
- C. Concentration of reactants
- D. Color of the reactants
Correct answer: D
Rationale: The color of reactants is not a factor that affects the rate of a chemical reaction. Temperature, surface area, and concentration of reactants are known factors that influence the reaction rate. Temperature plays a significant role in altering the reaction rate by affecting the kinetic energy of molecules. Surface area impacts the rate by providing more area for collisions to occur. Concentration affects the frequency of effective collisions. On the other hand, the color of reactants is a physical property that does not directly affect the speed of a chemical reaction.
5. What type of bond is present in sodium chloride?
- A. Covalent
- B. Ionic
- C. Metallic
- D. Hydrogen
Correct answer: B
Rationale: Ionic bonds are found in sodium chloride. In an ionic bond, one atom donates an electron to another atom, resulting in the formation of positively and negatively charged ions that are held together by electrostatic forces of attraction. Sodium chloride is a classic example of an ionic compound, where sodium (Na) donates an electron to chlorine (Cl), forming Na+ and Cl- ions that are attracted to each other, creating a crystal lattice structure. Covalent bonds involve the sharing of electron pairs between atoms, which is not the case in sodium chloride. Metallic bonds occur in metals where electrons are delocalized and shared across a lattice, unlike the specific transfer seen in ionic bonds. Hydrogen bonds are a type of intermolecular force, not the primary bond type present in sodium chloride.
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