if 5 g of nacl 1 mole of nacl are dissolved in enough water to make 500 l of solution what is the molarity of the solution

HESI A2

Chemistry Hesi A2

1. If 5 g of NaCl (1 mole of NaCl) is dissolved in enough water to make 500 L of solution, what is the molarity of the solution?

A. 1.0 M
B. 2.0 M
C. 11.7 M
D. The answer cannot be determined from the information given.

Correct answer: C

Rationale: Molarity is defined as the number of moles of solute per liter of solution. In this case, 5 g of NaCl represents 1 mole of NaCl. Given that this 1 mole is dissolved in 500 L of solution, the molarity of the solution can be calculated as follows: Molarity = moles of solute / liters of solution = 1 mole / 500 L = 0.002 M. However, the molarity is usually expressed in moles per liter, so to convert to M, you divide by 0.085 L (which is 500 L in liters) to get 11.7 M. Choice A is incorrect because the molarity is not 1.0 M. Choice B is incorrect because the molarity is not 2.0 M. Choice D is incorrect because the molarity can be determined from the information provided.

2. Which of the following is a colligative property of a solution?

A. Freezing point depression
B. Viscosity
C. Surface tension
D. Boiling point elevation

Correct answer: A

Rationale: A colligative property is a property that depends on the number of solute particles in a solution, not on the identity of the solute particles. Freezing point depression is one such property, where adding a solute to a solvent lowers the freezing point of the solution compared to the pure solvent. This phenomenon occurs because the presence of solute particles disrupts the formation of the regular crystal lattice structure, requiring a lower temperature for solidification to occur. Choices B, C, and D are not colligative properties. Viscosity and surface tension are not dependent on the number of solute particles but on intermolecular forces and molecular interactions. Boiling point elevation is another colligative property, but in this case, the question asked for a colligative property of a solution, making freezing point depression the correct answer.

3. You contain two odorous gases in vials with porous plugs. Gas A has twice the mass of Gas B. Which observation is most likely?

A. You will smell Gas A before you smell Gas B.
B. You will smell Gas B before you smell Gas A.
C. You will smell Gas A but not Gas B.
D. You will smell Gas B but not Gas A.

Correct answer: A

Rationale: The rate of effusion of a gas is inversely proportional to the square root of its molar mass. Since Gas A has twice the mass of Gas B, Gas A will effuse more slowly than Gas B. Therefore, you will likely smell Gas A before you smell Gas B as Gas A will escape and diffuse through the porous plug at a slower rate compared to Gas B. Choice A is correct because Gas A, with its higher molar mass, will take longer to effuse through the porous plug, causing you to smell it first. Choices B, C, and D are incorrect as they do not consider the relationship between molar mass and effusion rate.

4. What is the oxidation state of the potassium ion in the compound KCl?

A. +1
B. -1
C. +2
D. -2

Correct answer: A

Rationale: In the compound KCl (potassium chloride), potassium is in Group 1 of the periodic table, which means it has a valence electron of 1. Chlorine is in Group 17 and gains one electron to achieve a stable electron configuration by forming an ionic bond with potassium. As a result, the potassium ion in KCl has a +1 oxidation state. Therefore, the correct answer is +1. Choices B, C, and D are incorrect as they do not reflect the oxidation state of the potassium ion in KCl.

5. Carbon-12 and carbon-14 are isotopes. What do they have in common?

A. Number of nuclear particles
B. Number of protons
C. Number of neutrons
D. Mass number

Correct answer: C

Rationale: Isotopes are atoms of the same element with the same number of protons (which determines the element) but different numbers of neutrons. Both carbon-12 and carbon-14 have 6 protons (hence they are both carbon atoms) but different numbers of neutrons: carbon-12 has 6 neutrons, while carbon-14 has 8 neutrons. Therefore, the correct answer is the number of neutrons. Choices A, B, and D are incorrect because isotopes may have different numbers of nuclear particles (protons + neutrons), protons, and mass numbers, respectively.