HESI A2
Chemistry Hesi A2
1. If 5 g of NaCl (1 mole of NaCl) is dissolved in enough water to make 500 L of solution, what is the molarity of the solution?
- A. 1.0 M
- B. 2.0 M
- C. 11.7 M
- D. The answer cannot be determined from the information given.
Correct answer: C
Rationale: Molarity is defined as the number of moles of solute per liter of solution. In this case, 5 g of NaCl represents 1 mole of NaCl. Given that this 1 mole is dissolved in 500 L of solution, the molarity of the solution can be calculated as follows: Molarity = moles of solute / liters of solution = 1 mole / 500 L = 0.002 M. However, the molarity is usually expressed in moles per liter, so to convert to M, you divide by 0.085 L (which is 500 L in liters) to get 11.7 M. Choice A is incorrect because the molarity is not 1.0 M. Choice B is incorrect because the molarity is not 2.0 M. Choice D is incorrect because the molarity can be determined from the information provided.
2. Which of the following types of matter changes in volume with changes in temperature and pressure?
- A. Liquid
- B. Gas
- C. Solid
- D. Plasma
Correct answer: B
Rationale: A gas changes its volume with changes in temperature and pressure due to the particles moving more rapidly at higher temperatures, and pressure affects the space between particles. Liquids have a relatively fixed volume but take the shape of their container. Solids have a definite shape and volume, so they do not change volume with changes in temperature and pressure. Plasma is a state of matter where particles are highly energized and do not have a fixed volume, but it does not exhibit volume changes with temperature and pressure variations.
3. What is the correct electron configuration for magnesium?
- A. 1s² 2s²
- B. 1s² 2s² 2p⁶
- C. 1s² 2s² 2p⁶ 3s²
- D. 1s² 2s² 2p⁶ 3s² 3p¹
Correct answer: C
Rationale: The electron configuration of an element is determined by following the Aufbau principle, which states that electrons fill orbitals starting from the lowest energy level. Magnesium has an atomic number of 12, meaning it has 12 electrons. The electron configuration of magnesium fills the 1s, 2s, 2p, and 3s orbitals to accommodate all 12 electrons. Therefore, the correct electron configuration for magnesium is 1s² 2s² 2p⁶ 3s². Choice A is incorrect as it only includes 4 electrons and stops at the 2s orbital. Choice B is incorrect as it includes 8 electrons and stops at the 2p orbital. Choice D is incorrect as it includes 13 electrons and extends to the 3p orbital, which is beyond the actual electron configuration of magnesium.
4. What are the three types of intermolecular forces?
- A. Ionic, covalent, hydrogen
- B. Hydrogen bonding, dipole interactions, dispersion forces
- C. Van der Waals, ionic, covalent
- D. Hydrogen, Van der Waals, dispersion forces
Correct answer: B
Rationale: The three types of intermolecular forces are hydrogen bonding, dipole interactions, and dispersion forces. Option A includes ionic and covalent bonds, which are intramolecular forces, not intermolecular. Option C includes van der Waals forces, which encompass dipole interactions and dispersion forces, but also includes ionic and covalent bonds. Option D is close but misses dipole interactions, which are distinct from hydrogen bonding and dispersion forces. Therefore, option B is the correct choice as it includes the three specific types of intermolecular forces.
5. What is 119 K in degrees Celsius?
- A. 32°C
- B. -154°C
- C. 154°C
- D. 0°C
Correct answer: B
Rationale: To convert Kelvin (K) to Celsius (°C), you subtract 273.15 from the Kelvin value. Therefore, 119 K - 273.15 = -154.15°C. The negative sign indicates that the temperature is below freezing. When rounded to the nearest whole number, -154.15°C is approximately -154°C. Choice A and Choice C are incorrect as they do not reflect the correct conversion from Kelvin to Celsius. Choice D is incorrect as it corresponds to the freezing point of water in Celsius, not the conversion of 119 K.
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