HESI A2
Chemistry Hesi A2
1. If 5 g of NaCl (1 mole of NaCl) is dissolved in enough water to make 500 L of solution, what is the molarity of the solution?
- A. 1.0 M
- B. 2.0 M
- C. 11.7 M
- D. The answer cannot be determined from the information given.
Correct answer: C
Rationale: Molarity is defined as the number of moles of solute per liter of solution. In this case, 5 g of NaCl represents 1 mole of NaCl. Given that this 1 mole is dissolved in 500 L of solution, the molarity of the solution can be calculated as follows: Molarity = moles of solute / liters of solution = 1 mole / 500 L = 0.002 M. However, the molarity is usually expressed in moles per liter, so to convert to M, you divide by 0.085 L (which is 500 L in liters) to get 11.7 M. Choice A is incorrect because the molarity is not 1.0 M. Choice B is incorrect because the molarity is not 2.0 M. Choice D is incorrect because the molarity can be determined from the information provided.
2. What charge do Group VA elements typically have?
- A. -1
- B. -2
- C. -3
- D. 0
Correct answer: C
Rationale: Group VA elements, also known as Group 15 elements, typically have a charge of -3. This is because they have five valence electrons and tend to gain three electrons to achieve a stable octet configuration, resulting in a -3 charge. Choice A (-1) and Choice B (-2) are incorrect because Group VA elements need to gain three electrons to reach a stable electron configuration, not just one or two. Choice D (0) is also incorrect because Group VA elements do not lose electrons to form a charge of 0.
3. Which is a triatomic allotrope of oxygen?
- A. Ozone
- B. Water
- C. Acidic oxide
- D. Carbon dioxide
Correct answer: A
Rationale: Ozone (O3) is a triatomic allotrope of oxygen. It differs from the common diatomic oxygen molecule (O2) by having three oxygen atoms bonded together. Ozone is known for its protective role in the Earth's atmosphere, absorbing most of the Sun's harmful ultraviolet radiation. Water (H2O) is a compound composed of two hydrogen atoms and one oxygen atom. Acidic oxide and carbon dioxide are not triatomic allotropes of oxygen. Carbon dioxide consists of one carbon atom and two oxygen atoms, while acidic oxides refer to compounds where oxygen is bonded with other elements to form oxides, and they are not allotropes of oxygen.
4. What is stoichiometry?
- A. The study of energy changes in chemical reactions
- B. The study of the mass relationships in chemical reactions
- C. The study of atomic structure
- D. The study of molecular geometry
Correct answer: B
Rationale: Stoichiometry is the branch of chemistry that deals with the quantitative relationships between reactants and products in chemical reactions. It focuses on the calculation of the amounts of substances consumed and produced in a reaction based on the balanced chemical equation. Choice A is incorrect because the study of energy changes in chemical reactions falls under thermodynamics. Choice C is incorrect as atomic structure is related to the arrangement of atoms within molecules. Choice D is incorrect as molecular geometry deals with the spatial arrangement of atoms within molecules.
5. What is the oxidation state of the oxygen atom in the compound NaOH?
- A. -2
- B. -1
- C. 0
- D. +2
Correct answer: B
Rationale: In the compound NaOH (sodium hydroxide), the oxidation state of the sodium ion (Na) is +1 as it commonly has a +1 charge in ionic compounds. Oxygen (O) typically has an oxidation state of -2 in most compounds. Since the compound is electrically neutral and the overall charge is zero, the sum of the oxidation states of all atoms in the compound must be zero. Therefore, considering that sodium has an oxidation state of +1, the oxygen atom in NaOH must have an oxidation state of -1 to balance the charges and overall neutrality of the compound. Choice A (-2) is incorrect as this is not the oxidation state of oxygen in this compound. Choice C (0) is incorrect as oxygen in NaOH does not have an oxidation state of 0. Choice D (+2) is incorrect as oxygen typically has a negative oxidation state in compounds, not a positive one.
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