HESI A2
Chemistry Hesi A2
1. Which compound has a nonpolar bond in which the electrons are shared equally?
- A. H₂O
- B. NH₃
- C. Cl₂
- D. CH₄
Correct answer: D
Rationale: The compound CH₄, methane, has a nonpolar bond where carbon and hydrogen share electrons equally. This occurs because carbon and hydrogen have similar electronegativities, meaning they have equal abilities to attract shared electrons. Consequently, a nonpolar covalent bond is formed due to the balanced sharing of electrons between these atoms. Choices A, B, and C do not have nonpolar bonds with electrons shared equally. In H₂O (water), there are polar covalent bonds due to the difference in electronegativity between hydrogen and oxygen. In NH₃ (ammonia), the nitrogen-hydrogen bonds are polar because of the electronegativity difference. In Cl₂ (chlorine gas), the Cl-Cl bond is nonpolar, but the question specifies a compound, not an element, and chlorine does not share its electrons equally with another element in a compound.
2. What does the sum of protons and neutrons in an element represent?
- A. Atomic number
- B. Mass number
- C. Atomic mass
- D. Neutron number
Correct answer: B
Rationale: The sum of protons and neutrons in an element is known as the mass number. The mass number is an important concept in chemistry as it represents the total number of nucleons (protons and neutrons) in an atom's nucleus. It is different from the atomic number, which represents the number of protons in an atom. The atomic mass is the average mass of an element's isotopes, taking into account the abundance of each isotope. Neutron number, on the other hand, specifically refers to the number of neutrons in an atom's nucleus. Therefore, the correct answer is B, mass number.
3. Which element has the highest electronegativity?
- A. Fluorine
- B. Chlorine
- C. Nitrogen
- D. Oxygen
Correct answer: A
Rationale: Fluorine has the highest electronegativity among the elements listed. Electronegativity is a measure of an atom's ability to attract and hold onto electrons in a chemical bond. Fluorine, being the most electronegative element on the periodic table, has the strongest ability to attract electrons towards itself compared to chlorine, nitrogen, and oxygen. Therefore, fluorine is the correct answer. Chlorine, nitrogen, and oxygen have lower electronegativities compared to fluorine, making them incorrect choices for the element with the highest electronegativity.
4. What is the term used when an atom gains one or more electrons?
- A. Cation
- B. Anion
- C. Isotope
- D. Electron
Correct answer: B
Rationale: When an atom gains electrons, it becomes negatively charged and is called an anion. An anion is formed when an atom gains one or more electrons, leading to an excess of negative charge. Choice A, 'Cation,' is incorrect because a cation is formed when an atom loses electrons, resulting in a positively charged ion. Choice C, 'Isotope,' refers to atoms of the same element with different numbers of neutrons and is not related to gaining electrons. Choice D, 'Electron,' is the particle that an atom gains to become an anion, not the term for the atom itself after gaining electrons.
5. What is the coefficient of O after the following equation is balanced?
- A. 1
- B. 2
- C. 3
- D. 4
Correct answer: A
Rationale: In a balanced chemical equation, the coefficient of oxygen (O) in O2 is already 2, so there is no need to adjust its coefficient further. Therefore, the coefficient of O remains as 1. Since the coefficient of O2 is 2, each O atom is represented by the coefficient of 1, and it does not change during the balancing process. Choices B, C, and D are incorrect as they suggest changing the coefficient of oxygen, which is not necessary for O2 in a balanced equation.
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