which compound has a nonpolar bond in which the electrons are shared equally
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HESI A2

Chemistry Hesi A2

1. Which compound has a nonpolar bond in which the electrons are shared equally?

Correct answer: D

Rationale: The compound CH₄, methane, has a nonpolar bond where carbon and hydrogen share electrons equally. This occurs because carbon and hydrogen have similar electronegativities, meaning they have equal abilities to attract shared electrons. Consequently, a nonpolar covalent bond is formed due to the balanced sharing of electrons between these atoms. Choices A, B, and C do not have nonpolar bonds with electrons shared equally. In H₂O (water), there are polar covalent bonds due to the difference in electronegativity between hydrogen and oxygen. In NH₃ (ammonia), the nitrogen-hydrogen bonds are polar because of the electronegativity difference. In Cl₂ (chlorine gas), the Cl-Cl bond is nonpolar, but the question specifies a compound, not an element, and chlorine does not share its electrons equally with another element in a compound.

2. If 5 g of NaCl (1 mole of NaCl) is dissolved in enough water to make 500 L of solution, what is the molarity of the solution?

Correct answer: C

Rationale: Molarity is defined as the number of moles of solute per liter of solution. In this case, 5 g of NaCl represents 1 mole of NaCl. Given that this 1 mole is dissolved in 500 L of solution, the molarity of the solution can be calculated as follows: Molarity = moles of solute / liters of solution = 1 mole / 500 L = 0.002 M. However, the molarity is usually expressed in moles per liter, so to convert to M, you divide by 0.085 L (which is 500 L in liters) to get 11.7 M. Choice A is incorrect because the molarity is not 1.0 M. Choice B is incorrect because the molarity is not 2.0 M. Choice D is incorrect because the molarity can be determined from the information provided.

3. Which elements are typically involved in hydrogen bonding?

Correct answer: D

Rationale: Hydrogen bonding occurs between hydrogen and highly electronegative atoms such as fluorine, oxygen, and nitrogen. These atoms have a strong pull on the shared electrons, leading to a partial negative charge on them, which allows them to form hydrogen bonds with hydrogen or other electronegative atoms. Choice A is incorrect because carbon is not typically involved in hydrogen bonding. Choice B is incorrect because chlorine is not as electronegative as nitrogen, and choice C is incorrect because nitrogen is more electronegative than chlorine.

4. What is the term used when an atom gains one or more electrons?

Correct answer: B

Rationale: When an atom gains electrons, it becomes negatively charged and is called an anion. An anion is formed when an atom gains one or more electrons, leading to an excess of negative charge. Choice A, 'Cation,' is incorrect because a cation is formed when an atom loses electrons, resulting in a positively charged ion. Choice C, 'Isotope,' refers to atoms of the same element with different numbers of neutrons and is not related to gaining electrons. Choice D, 'Electron,' is the particle that an atom gains to become an anion, not the term for the atom itself after gaining electrons.

5. Which best defines the molarity of an aqueous sugar solution?

Correct answer: D

Rationale: The molarity of a solution is defined as the number of moles of solute per liter of solvent. In the case of an aqueous sugar solution, the molarity would be expressed as moles of sugar per liter of solution. This is because molarity is a measurement of the concentration of a solute in a solution based on the number of moles present in a given volume of the solution. Therefore, the correct answer is D. Choices A, B, and C are incorrect because the molarity is specifically defined in terms of moles of solute per liter of solution, not in grams per milliliter or grams per liter. Molarity is a unit of concentration that relates the amount of solute to the volume of the solution, not the mass of the solute.

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