HESI A2
Chemistry Hesi A2
1. Which compound has a nonpolar bond in which the electrons are shared equally?
- A. H₂O
- B. NH₃
- C. Cl₂
- D. CH₄
Correct answer: D
Rationale: The compound CH₄, methane, has a nonpolar bond where carbon and hydrogen share electrons equally. This occurs because carbon and hydrogen have similar electronegativities, meaning they have equal abilities to attract shared electrons. Consequently, a nonpolar covalent bond is formed due to the balanced sharing of electrons between these atoms. Choices A, B, and C do not have nonpolar bonds with electrons shared equally. In H₂O (water), there are polar covalent bonds due to the difference in electronegativity between hydrogen and oxygen. In NH₃ (ammonia), the nitrogen-hydrogen bonds are polar because of the electronegativity difference. In Cl₂ (chlorine gas), the Cl-Cl bond is nonpolar, but the question specifies a compound, not an element, and chlorine does not share its electrons equally with another element in a compound.
2. Which one does not name a polar molecule?
- A. NH₃
- B. H₂S
- C. SO₂
- D. CO₂
Correct answer: A
Rationale: The correct answer is NH₃. The molecule NH₃ does not represent a polar molecule because nitrogen and hydrogen in this molecule have a small difference in electronegativity that does not result in a significant polar covalent bond. In contrast, molecules H₂S, SO₂, and CO₂ have polar covalent bonds due to larger electronegativity differences, making them polar molecules. Therefore, options B, C, and D are polar molecules, unlike option A.
3. Here are the solubilities of four substances at 0°C, in grams of solute per 100 mL of water. If the temperature increases to 20°C, what would you expect to happen to the solubility figures?
- A. Citric acid and potassium phosphate will decrease; nitrogen and oxygen will increase.
- B. Citric acid and potassium phosphate will increase; nitrogen and oxygen will decrease.
- C. All four figures will increase.
- D. All four figures will decrease.
Correct answer: C
Rationale: Solubility generally tends to increase with temperature for most solid solutes in liquid solvents due to higher kinetic energy leading to better solute-solvent interactions. As the temperature increases from 0°C to 20°C, all four solubility figures are expected to increase. Choice A is incorrect because solubility tends to increase with temperature. Choice B is incorrect as well for the same reason. Choice D is incorrect because the solubility of solid solutes typically increases with temperature.
4. Which branch of chemistry deals with the quantities and numeric relationships between compounds in a chemical reaction?
- A. Stoichiometry
- B. Molecular chemistry
- C. Atomic chemistry
- D. Thermodynamics
Correct answer: A
Rationale: Stoichiometry is the branch of chemistry that deals with the quantitative relationships between reactants and products in chemical reactions. It involves the calculation of quantities of substances consumed and produced in a chemical reaction based on the balanced chemical equation. Choice B, 'Molecular chemistry,' is incorrect as it focuses on the structure, properties, and reactions of molecules. Choice C, 'Atomic chemistry,' is incorrect as it primarily deals with the study of atoms and their interactions. Choice D, 'Thermodynamics,' is incorrect as it pertains to the study of energy and heat transfer in chemical and physical processes.
5. What is the correct name of MgO?
- A. Manganese oxide
- B. Magnesium oxide
- C. Magnesium oxate
- D. Magnesium hydroxide
Correct answer: B
Rationale: The correct name of MgO is Magnesium oxide. Mg represents the chemical symbol for magnesium, and O represents the chemical symbol for oxygen. When these elements combine, they form magnesium oxide. Option A, Manganese oxide, is incorrect as it refers to a compound of manganese and oxygen, not magnesium. Option C, Magnesium oxate, is not a valid chemical compound name. Option D, Magnesium hydroxide, refers to a different compound consisting of magnesium, oxygen, and hydrogen.
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