which compound has a nonpolar bond in which the electrons are shared equally

HESI A2

Chemistry Hesi A2

1. Which compound has a nonpolar bond in which the electrons are shared equally?

A. H₂O
B. NH₃
C. Cl₂
D. CH₄

Correct answer: D

Rationale: The compound CH₄, methane, has a nonpolar bond where carbon and hydrogen share electrons equally. This occurs because carbon and hydrogen have similar electronegativities, meaning they have equal abilities to attract shared electrons. Consequently, a nonpolar covalent bond is formed due to the balanced sharing of electrons between these atoms. Choices A, B, and C do not have nonpolar bonds with electrons shared equally. In H₂O (water), there are polar covalent bonds due to the difference in electronegativity between hydrogen and oxygen. In NH₃ (ammonia), the nitrogen-hydrogen bonds are polar because of the electronegativity difference. In Cl₂ (chlorine gas), the Cl-Cl bond is nonpolar, but the question specifies a compound, not an element, and chlorine does not share its electrons equally with another element in a compound.

2. Which of these intermolecular forces might represent attraction between atoms of a noble gas?

A. Dipole-dipole interaction
B. London dispersion force
C. Keesom interaction
D. Hydrogen bonding

Correct answer: B

Rationale: Noble gases are non-polar molecules without a permanent dipole moment. The only intermolecular force applicable to noble gases is the London dispersion force, also known as Van der Waals forces. This force is a temporary attractive force resulting from the formation of temporary dipoles in non-polar molecules. Dipole-dipole interactions, Keesom interactions, and hydrogen bonding involve significant dipoles or hydrogen atoms bonded to electronegative atoms, which do not apply to noble gases.

3. Balance this equation: Fe + Cl2 → FeCl3

A. 2Fe + 2Cl2 → 2FeCl3
B. 2Fe + 3Cl2 → 2FeCl3
C. 3Fe + 2Cl2 → 3FeCl3
D. 3Fe + 3Cl2 → 6FeCl3

Correct answer: B

Rationale: In the given equation, Fe combines with Cl to form FeCl3. To balance the equation, we need to have the same number of each element on both sides. Since Cl is represented as Cl2 in the equation, we need 3 Cl2 molecules to balance Fe, resulting in 2Fe + 3Cl2 → 2FeCl3. Choice A is incorrect because it only balances Fe but not Cl2. Choice C is incorrect as it balances Fe but not Cl2. Choice D is incorrect as it balances Fe but overbalances Cl2.

4. Which element would you expect to be least reactive?

A. Li
B. Cr
C. Nd
D. Xe

Correct answer: D

Rationale: Xenon (Xe) is a noble gas located in Group 18 of the periodic table. Noble gases are known for their stable and unreactive nature due to having a full outer shell of electrons. Therefore, xenon would be expected to be the least reactive among the given elements. Choice A (Li) is a metal in Group 1 of the periodic table, which tends to be reactive, especially with water. Choice B (Cr) is a transition metal known for its reactivity in some forms. Choice C (Nd) is a rare earth element, which can exhibit varying reactivity depending on the compound or environment.

5. Which of the following substances is a base?

A. Water
B. Sodium chloride
C. Ammonia
D. Salt

Correct answer: C

Rationale: The correct answer is 'Ammonia' (Choice C) as it is a common example of a base. Bases are substances that release hydroxide ions (OH-) in aqueous solutions, helping to increase the pH level. Ammonia is a weak base that can accept a proton (H+) to form ammonium hydroxide. In contrast, water (Choice A), sodium chloride (Choice B), and salt (Choice D) are not bases; water is neutral, while sodium chloride and salt are neutral compounds composed of a cation and an anion.