HESI A2
Chemistry Hesi A2
1. Which compound has a nonpolar bond in which the electrons are shared equally?
- A. Hâ‚‚O
- B. NH₃
- C. Clâ‚‚
- D. CHâ‚„
Correct answer: D
Rationale: The compound CH₄, methane, has a nonpolar bond where carbon and hydrogen share electrons equally. This occurs because carbon and hydrogen have similar electronegativities, meaning they have equal abilities to attract shared electrons. Consequently, a nonpolar covalent bond is formed due to the balanced sharing of electrons between these atoms. Choices A, B, and C do not have nonpolar bonds with electrons shared equally. In H₂O (water), there are polar covalent bonds due to the difference in electronegativity between hydrogen and oxygen. In NH₃ (ammonia), the nitrogen-hydrogen bonds are polar because of the electronegativity difference. In Cl₂ (chlorine gas), the Cl-Cl bond is nonpolar, but the question specifies a compound, not an element, and chlorine does not share its electrons equally with another element in a compound.
2. To the nearest whole number, what is the mass of one mole of hydrogen iodide?
- A. 2 g/mol
- B. 58 g/mol
- C. 87 g/mol
- D. 128 g/mol
Correct answer: C
Rationale: The molar mass of hydrogen iodide (HI) is the sum of the atomic masses of its constituent elements. Hydrogen (H) has a molar mass of approximately 1 g/mol, and iodine (I) has a molar mass of about 127 g/mol. Thus, the molar mass of hydrogen iodide (HI) is approximately 1 + 127 = 128 g/mol. Rounding to the nearest whole number, the molar mass of hydrogen iodide is 128 g/mol, which is closest to choice C. Choice A (2 g/mol) is too low and does not reflect the correct molar mass of hydrogen iodide. Choice B (58 g/mol) is significantly lower than the actual molar mass. Choice D (128 g/mol) matches the calculated molar mass but is not the nearest whole number as requested.
3. What are negatively charged ions called?
- A. Neutrons
- B. Protons
- C. Anions
- D. Cations
Correct answer: C
Rationale: Negatively charged ions are called anions. Anions gain electrons and carry a negative charge, which distinguishes them from cations that are positively charged and neutrons and protons that are subatomic particles found in the nucleus of an atom. Choice A, Neutrons, are neutral subatomic particles found in the nucleus of an atom, not negatively charged ions. Choice B, Protons, are positively charged subatomic particles found in the nucleus of an atom, not negatively charged ions. Choice D, Cations, are positively charged ions that lose electrons, which is opposite to the behavior of negatively charged ions.
4. What does the mass number minus the atomic number equal?
- A. Number of electrons
- B. Number of neutrons
- C. Number of protons
- D. Number of isotopes
Correct answer: B
Rationale: The mass number of an atom represents the total number of protons and neutrons in its nucleus. The atomic number indicates the number of protons in the nucleus. The difference between the mass number and the atomic number provides the number of neutrons present in the nucleus of an atom. Therefore, mass number minus atomic number equals the number of neutrons. Choice A is incorrect because the number of electrons is not determined by the mass number and atomic number. Choice C is incorrect as it represents the number of protons, not the difference between the mass number and atomic number. Choice D is incorrect as isotopes refer to atoms of the same element with different numbers of neutrons, not the difference between mass number and atomic number.
5. If fifty-six kilograms of a radioactive substance has a half-life of 12 days, how many days will it take the substance to decay naturally to only 7 kilograms?
- A. 8
- B. 12
- C. 36
- D. 48
Correct answer: C
Rationale: To decay from 56 kg to 7 kg, the substance needs to go through 3 half-lives (56 kg ÷ 2 ÷ 2 ÷ 2 = 7 kg). Since each half-life is 12 days, the total time required is 12 days per half-life x 3 half-lives = 36 days. Choice A is incorrect because it does not consider the concept of half-lives. Choice B is incorrect because it represents the duration of a single half-life, not the total time required for the decay. Choice D is incorrect as it does not account for the multiple half-lives needed for the substance to decay from 56 kg to 7 kg.
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