HESI A2
HESI A2 Chemistry
1. What type of chemical reaction is represented by AB → A + B?
- A. Synthesis
- B. Decomposition
- C. Single replacement
- D. Double replacement
Correct answer: B
Rationale: The chemical equation AB → A + B represents a decomposition reaction. In a decomposition reaction, a single compound breaks down into two or more simpler substances. In this specific reaction, compound AB is decomposed into its elements, A and B, making it a decomposition reaction. Choice A, Synthesis, involves the combination of two or more substances to form a more complex product, which is not the case here. Choices C and D, Single replacement and Double replacement, involve the exchange of ions between compounds or elements, which is not happening in the given reaction.
2. Which element has the highest electronegativity?
- A. Fluorine
- B. Chlorine
- C. Nitrogen
- D. Oxygen
Correct answer: A
Rationale: Fluorine has the highest electronegativity among the elements listed. Electronegativity is a measure of an atom's ability to attract and hold onto electrons in a chemical bond. Fluorine, being the most electronegative element on the periodic table, has the strongest ability to attract electrons towards itself compared to chlorine, nitrogen, and oxygen. Therefore, fluorine is the correct answer. Chlorine, nitrogen, and oxygen have lower electronegativities compared to fluorine, making them incorrect choices for the element with the highest electronegativity.
3. Which one is not a hydrocarbon?
- A. Methane (CH4)
- B. Pyridine (C5H5N)
- C. Ethane (C2H6)
- D. Propane (C3H8)
Correct answer: B
Rationale: The correct answer is B, Pyridine (C5H5N). Pyridine is not a hydrocarbon because it contains nitrogen (N) in its molecular structure, in addition to carbon (C) and hydrogen (H) atoms. Hydrocarbons consist solely of carbon and hydrogen atoms. Methane (CH4), ethane (C2H6), and propane (C3H8) are all examples of hydrocarbons as they only contain carbon and hydrogen atoms, making them organic compounds known for their combustion properties.
4. What term refers to the average of the masses of each of its isotopes as they occur in nature?
- A. Atomic number
- B. Mass number
- C. Atomic mass
- D. Neutron number
Correct answer: C
Rationale: The correct answer is atomic mass. Atomic mass is the weighted average of the masses of an element's isotopes. It takes into account the abundance of each isotope in nature to provide a more accurate representation of the element's overall mass. Choice A, atomic number, represents the number of protons in an atom. Choice B, mass number, refers to the total number of protons and neutrons in an atom's nucleus. Choice D, neutron number, specifically focuses on the count of neutrons in an atom's nucleus. These choices do not directly relate to the average mass of isotopes as asked in the question.
5. If gas A has four times the molar mass of gas B, you would expect it to diffuse through a plug ___________.
- A. at half the rate of gas B
- B. at twice the rate of gas B
- C. at a quarter the rate of gas B
- D. at four times the rate of gas B
Correct answer: A
Rationale: When comparing the diffusion rates of two gases, according to Graham's law of diffusion, the rate of diffusion is inversely proportional to the square root of the molar mass. If gas A has four times the molar mass of gas B, the square root of the molar masses ratio (4:1) is 2. This means that gas A would diffuse through a plug at half the rate of gas B. Therefore, the correct answer is A, at half the rate of gas B. Choices B, C, and D are incorrect because they do not reflect the correct relationship between the molar masses and the rates of diffusion according to Graham's law.
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