when the heat of a reaction is negative which statement is true

HESI A2

HESI A2 Physics

1. When the heat of a reaction is negative, which statement is true?

A. The products have less energy and are less stable.
B. The products have more energy and are more stable.
C. The products have less energy and are more stable.
D. The products have more energy and are less stable.

Correct answer: C

Rationale: When the heat of a reaction is negative, it indicates that the reaction releases energy in the form of heat. This means that the products have lower energy levels compared to the reactants. Lower energy levels are associated with greater stability in chemical systems. Therefore, when the heat of a reaction is negative, the products are more stable due to having less energy than the reactants. Choice A, stating that the products have less energy and are less stable, is incorrect as lower energy levels imply greater stability. Choice B, stating that the products have more energy and are more stable, is incorrect as lower energy levels lead to higher stability. Choice D, stating that the products have more energy and are less stable, is incorrect as lower energy levels are associated with higher stability.

2. Which of the following substances has the highest density?

A. Mist
B. Water
C. Steam
D. Ice

Correct answer: B

Rationale: Water has the highest density among the options provided. Density is a measure of mass per unit volume. In this case, water in its liquid form is denser than mist, steam, and ice. Ice has a lower density than water because its crystalline structure causes it to be less dense. Mist and steam are forms of water vapor, which are much less dense than liquid water. Therefore, the correct answer is water (choice B).

3. An object with a charge of 4 μC is placed 50 cm from another object with a charge twice as great. What is the magnitude of the resulting repulsive force?

A. 0.1152 N
B. 1.152 N
C. 10^−3 N
D. 2.5 × 10^−3 N

Correct answer: D

Rationale: The force between two charges is calculated using Coulomb's Law, which states that the force is proportional to the product of the two charges and inversely proportional to the square of the distance between them. Given that one charge is twice as great as the other and the distance between them is 50 cm, we can calculate the repulsive force. The magnitude of the resulting repulsive force is 2.5 × 10^−3 N. Choice A is incorrect as it does not match the calculated value. Choice B is incorrect as it is significantly higher than the correct answer. Choice C is incorrect as it represents 10^−3 N, which is lower than the calculated value.

4. Enthalpy (H) is a thermodynamic property defined as the sum of a system's internal energy (U) and the product of its pressure (P) and volume (V). The relationship between these is:

A. H = U + PV
B. H = U - PV
C. H = U / PV
D. H = PV / U

Correct answer: A

Rationale: Enthalpy (H) is defined as H = U + PV, where U represents internal energy, P is pressure, and V is volume. Enthalpy includes both the internal energy of a system and the energy required to create space for the system against an external pressure. Therefore, the correct relationship between enthalpy, internal energy, pressure, and volume is H = U + PV. Choice B is incorrect as subtracting PV would not account for the work done against pressure. Choice C is incorrect as dividing U by PV doesn't represent the definition of enthalpy. Choice D is incorrect as dividing PV by U is not the correct relationship based on the definition of enthalpy.

5. Psychrometrics is a branch of thermodynamics that deals with the properties of:

A. Ideal gases.
B. Magnetic materials.
C. Mixtures of moist air and water vapor.
D. Nuclear reactions.

Correct answer: C

Rationale: Psychrometrics is the study of the physical and thermodynamic properties of gas-vapor mixtures, especially mixtures of moist air and water vapor. This branch of thermodynamics focuses on the relationships between temperature, pressure, humidity, and other properties of these mixtures. Choice A, ideal gases, is incorrect because psychrometrics specifically deals with gas-vapor mixtures, not ideal gases. Choice B, magnetic materials, and Choice D, nuclear reactions, are unrelated to psychrometrics and thermodynamics, making them incorrect. Understanding psychrometrics is crucial in fields like heating, ventilation, air conditioning, and refrigeration (HVAC&R) to design systems that effectively control air quality, comfort, and temperature.