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1. Which branch of chemistry deals with the quantities and numeric relationships between compounds in a chemical reaction?

• A. Stoichiometry
• B. Molecular chemistry
• C. Atomic chemistry
• D. Thermodynamics

Correct answer: A

Rationale: Stoichiometry is the branch of chemistry that deals with the quantitative relationships between reactants and products in chemical reactions. It involves the calculation of quantities of substances consumed and produced in a chemical reaction based on the balanced chemical equation. Choice B, 'Molecular chemistry,' is incorrect as it focuses on the structure, properties, and reactions of molecules. Choice C, 'Atomic chemistry,' is incorrect as it primarily deals with the study of atoms and their interactions. Choice D, 'Thermodynamics,' is incorrect as it pertains to the study of energy and heat transfer in chemical and physical processes.

2. How much concentrated HCl should be used to prepare 500 mL of a 0.100 M HCl solution?

• A. 75 mL
• B. 100 mL
• C. 125 mL
• D. 150 mL

Correct answer: B

Rationale: To prepare a 0.100 M HCl solution with a volume of 500 mL, you can use the formula C1V1 = C2V2, where C1 is the concentration of the concentrated HCl solution, V1 is the volume of concentrated HCl solution used, C2 is the desired concentration (0.100 M), and V2 is the final volume (500 mL). Rearranging the formula to solve for V1, you get V1 = (C2V2) / C1. Plugging in the values (0.100 M)(500 mL) / C1 = 100 mL, which means 100 mL of concentrated HCl should be used to prepare 500 mL of a 0.100 M HCl solution. Therefore, the correct answer is 100 mL. Choice A (75 mL), Choice C (125 mL), and Choice D (150 mL) are incorrect as they do not match the calculated volume needed to prepare the desired concentration of HCl solution.

3. If gas A has four times the molar mass of gas B, you would expect it to diffuse through a plug ___________.

• A. at half the rate of gas B
• B. at twice the rate of gas B
• C. at a quarter the rate of gas B
• D. at four times the rate of gas B

Correct answer: A

Rationale: When comparing the diffusion rates of two gases, according to Graham's law of diffusion, the rate of diffusion is inversely proportional to the square root of the molar mass. If gas A has four times the molar mass of gas B, the square root of the molar masses ratio (4:1) is 2. This means that gas A would diffuse through a plug at half the rate of gas B. Therefore, the correct answer is A, at half the rate of gas B. Choices B, C, and D are incorrect because they do not reflect the correct relationship between the molar masses and the rates of diffusion according to Graham's law.

4. Aluminum (Al) has 13 protons in its nucleus. What is the number of electrons in an Al3+ ion?

• A. 16
• B. 13
• C. 10
• D. 3

Correct answer: C

Rationale: Aluminum (Al) has an atomic number of 13, which indicates it normally has 13 electrons to balance the 13 protons in its nucleus. When Al forms an Al3+ ion, it loses 3 electrons to achieve a stable electron configuration. Therefore, the Al3+ ion will have 13 - 3 = 10 electrons. Choice A (16) is incorrect as it doesn't take into account the charge of the Al3+ ion. Choice B (13) is incorrect because the Al3+ ion has lost electrons. Choice D (3) is incorrect as it doesn't reflect the total number of electrons lost by the Al atom to form the Al3+ ion.

5. What is the simplest form of a substance that is represented by a letter or letters?

• A. Compound
• B. Mixture
• C. Element
• D. Molecule

Correct answer: C

Rationale: The correct answer is C, 'Element.' An element is the most basic form of a substance that cannot be broken down further by chemical reactions. Each element is represented by a unique symbol, typically consisting of one or two letters. Choice A, 'Compound,' is incorrect as compounds are formed by the combination of two or more elements. Choice B, 'Mixture,' is also incorrect as mixtures are composed of two or more substances physically combined. Choice D, 'Molecule,' refers to the smallest unit of a compound that retains the chemical properties of that compound, not the simplest form of a substance represented by a symbol.

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