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1. Which branch of chemistry deals with the quantities and numeric relationships between compounds in a chemical reaction?

• A. Stoichiometry
• B. Molecular chemistry
• C. Atomic chemistry
• D. Thermodynamics

Correct answer: A

Rationale: Stoichiometry is the branch of chemistry that deals with the quantitative relationships between reactants and products in chemical reactions. It involves the calculation of quantities of substances consumed and produced in a chemical reaction based on the balanced chemical equation. Choice B, 'Molecular chemistry,' is incorrect as it focuses on the structure, properties, and reactions of molecules. Choice C, 'Atomic chemistry,' is incorrect as it primarily deals with the study of atoms and their interactions. Choice D, 'Thermodynamics,' is incorrect as it pertains to the study of energy and heat transfer in chemical and physical processes.

2. The molar mass of some gases is as follows: carbon monoxide—28.01 g/mol; helium—4.00 g/mol; nitrogen—28.01 g/mol; and oxygen—32.00 g/mol. Which would you expect to diffuse most rapidly?

• A. Carbon monoxide
• B. Helium
• C. Nitrogen
• D. Oxygen

Correct answer: B

Rationale: The rate of diffusion is inversely proportional to the molar mass of the gas. Helium has the lowest molar mass among the given gases, making it the lightest and fastest gas to diffuse. Therefore, helium would be expected to diffuse most rapidly compared to carbon monoxide, nitrogen, and oxygen. Carbon monoxide, nitrogen, and oxygen have higher molar masses than helium, so they would diffuse more slowly. Therefore, the correct answer is helium.

3. If gas A has four times the molar mass of gas B, you would expect it to diffuse through a plug ___________.

• A. at half the rate of gas B
• B. at twice the rate of gas B
• C. at a quarter the rate of gas B
• D. at four times the rate of gas B

Correct answer: A

Rationale: When comparing the diffusion rates of two gases, according to Graham's law of diffusion, the rate of diffusion is inversely proportional to the square root of the molar mass. If gas A has four times the molar mass of gas B, the square root of the molar masses ratio (4:1) is 2. This means that gas A would diffuse through a plug at half the rate of gas B. Therefore, the correct answer is A, at half the rate of gas B. Choices B, C, and D are incorrect because they do not reflect the correct relationship between the molar masses and the rates of diffusion according to Graham's law.

4. What distinguishes one allotrope from another?

• A. Arrangement of atoms
• B. Gram atomic mass
• C. Physical state
• D. Stability

Correct answer: A

Rationale: Allotropes are different forms of the same element that exist in the same physical state but have different structures. The arrangement of atoms is what distinguishes one allotrope from another, determining their unique properties and characteristics. Gram atomic mass (Choice B) is a constant value for a specific element and does not change between different allotropes. Physical state (Choice C) refers to whether a substance is a solid, liquid, or gas, which can be the same for different allotropes of an element. Stability (Choice D) can vary between different allotropes, but it is not what always differentiates one allotrope from another. Therefore, the correct answer is the arrangement of atoms, as it is the key factor that varies across different allotropes.

5. Which gas is produced when an acid reacts with a carbonate?

• A. Carbon dioxide
• B. Oxygen
• C. Hydrogen
• D. Nitrogen

Correct answer: A

Rationale: When an acid reacts with a carbonate, the chemical reaction typically yields carbon dioxide gas. Carbon dioxide is formed due to the chemical reaction between the acid and the carbonate, releasing this gas as a product. Therefore, the correct answer is 'Carbon dioxide.' Choices B, C, and D are incorrect as oxygen, hydrogen, and nitrogen are not the gases produced in this specific acid-carbonate reaction.

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