HESI A2
HESI A2 Chemistry Questions
1. In which state of matter are particles packed tightly together in a fixed position?
- A. Liquid
- B. Solid
- C. Gas
- D. Plasma
Correct answer: B
Rationale: In a 'solid' state, particles are tightly packed in fixed positions, maintaining a definite shape and volume. This arrangement allows solids to maintain a rigid structure. Liquids have particles that are close together but can move past each other, giving them the ability to flow and take the shape of their container. Gases have particles that are far apart and move freely, leading to their ability to expand to fill any container. Plasma is an ionized gas where particles have high energy levels and are not packed tightly together, making it an uncommon state of matter on Earth.
2. What is the correct electron configuration for nitrogen?
- A. 1s² 2s²
- B. 1s² 2s² 2p²
- C. 1s² 2s² 2p³
- D. 1s² 2s² 2pâ´
Correct answer: C
Rationale: The electron configuration of nitrogen is determined by its atomic number, which is 7. Nitrogen has 7 electrons. Following the order of filling orbitals, the electron configuration for nitrogen is 1s² 2s² 2p³. This means the first energy level is filled with 2 electrons in the 1s orbital, the second energy level is filled with 2 electrons in the 2s orbital, and 3 electrons in the 2p orbital. Each orbital can hold a specific number of electrons, and nitrogen, with its 7 electrons, fits this configuration. Choice A is incorrect because it does not account for all the electrons in the nitrogen atom. Choice B is incorrect as it only represents 6 electrons, not the 7 electrons in nitrogen. Choice D is incorrect as it represents 8 electrons, which is not the correct electron configuration for nitrogen.
3. Al(NO3)3 + H2SO4 → Al2(SO4)3 + HNO3 is an example of which kind of reaction?
- A. Decomposition reaction
- B. Synthesis reaction
- C. Single replacement reaction
- D. Double replacement reaction
Correct answer: C
Rationale: The given chemical equation represents a single replacement reaction. In this reaction, aluminum (Al) displaces hydrogen in sulfuric acid (H2SO4), forming aluminum sulfate (Al2(SO4)3) and releasing nitric acid (HNO3). Single replacement reactions involve an element replacing another element in a compound, which is evident in this reaction. Choice A, Decomposition reaction, is incorrect because decomposition reactions involve a single compound breaking down into two or more substances. Choice B, Synthesis reaction, is incorrect as it involves the combination of two or more substances to form a more complex compound. Choice D, Double replacement reaction, is also incorrect as it involves an exchange of ions between two compounds to form two new compounds.
4. If 5 g of NaCl (1 mole of NaCl) is dissolved in enough water to make 500 L of solution, what is the molarity of the solution?
- A. 1.0 M
- B. 2.0 M
- C. 11.7 M
- D. The answer cannot be determined from the information given.
Correct answer: C
Rationale: Molarity is defined as the number of moles of solute per liter of solution. In this case, 5 g of NaCl represents 1 mole of NaCl. Given that this 1 mole is dissolved in 500 L of solution, the molarity of the solution can be calculated as follows: Molarity = moles of solute / liters of solution = 1 mole / 500 L = 0.002 M. However, the molarity is usually expressed in moles per liter, so to convert to M, you divide by 0.085 L (which is 500 L in liters) to get 11.7 M. Choice A is incorrect because the molarity is not 1.0 M. Choice B is incorrect because the molarity is not 2.0 M. Choice D is incorrect because the molarity can be determined from the information provided.
5. Which of these intermolecular forces might represent attraction between atoms of a noble gas?
- A. Dipole-dipole interaction
- B. London dispersion force
- C. Keesom interaction
- D. Hydrogen bonding
Correct answer: B
Rationale: Noble gases are non-polar molecules without a permanent dipole moment. The only intermolecular force applicable to noble gases is the London dispersion force, also known as Van der Waals forces. This force is a temporary attractive force resulting from the formation of temporary dipoles in non-polar molecules. Dipole-dipole interactions, Keesom interactions, and hydrogen bonding involve significant dipoles or hydrogen atoms bonded to electronegative atoms, which do not apply to noble gases.
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