in which state of matter are particles packed tightly together in a fixed position

HESI A2

HESI A2 Chemistry Questions

1. In which state of matter are particles packed tightly together in a fixed position?

A. Liquid
B. Solid
C. Gas
D. Plasma

Correct answer: B

Rationale: In a 'solid' state, particles are tightly packed in fixed positions, maintaining a definite shape and volume. This arrangement allows solids to maintain a rigid structure. Liquids have particles that are close together but can move past each other, giving them the ability to flow and take the shape of their container. Gases have particles that are far apart and move freely, leading to their ability to expand to fill any container. Plasma is an ionized gas where particles have high energy levels and are not packed tightly together, making it an uncommon state of matter on Earth.

2. Here are the solubilities of four substances at 0Â°C, in grams of solute per 100 mL of water. If the temperature increases to 20Â°C, what would you expect to happen to the solubility figures?

A. Citric acid and potassium phosphate will decrease; nitrogen and oxygen will increase.
B. Citric acid and potassium phosphate will increase; nitrogen and oxygen will decrease.
C. All four figures will increase.
D. All four figures will decrease.

Correct answer: C

Rationale: Solubility generally tends to increase with temperature for most solid solutes in liquid solvents due to higher kinetic energy leading to better solute-solvent interactions. As the temperature increases from 0Â°C to 20Â°C, all four solubility figures are expected to increase. Choice A is incorrect because solubility tends to increase with temperature. Choice B is incorrect as well for the same reason. Choice D is incorrect because the solubility of solid solutes typically increases with temperature.

3. Which intermolecular force is the strongest?

A. Dipole interactions
B. Dispersion forces
C. Hydrogen bonding
D. Van der Waals forces

Correct answer: C

Rationale: Hydrogen bonding is the strongest intermolecular force due to its specific interaction between a hydrogen atom and a highly electronegative atom like nitrogen, oxygen, or fluorine. This type of bonding results in a very strong attraction between molecules, making it the strongest intermolecular force among the options provided. Dipole interactions (choice A) are weaker than hydrogen bonding as they occur between polar molecules. Dispersion forces (choice B) are the weakest intermolecular forces and are caused by temporary fluctuations in electron distribution. Van der Waals forces (choice D) are a broader term that encompasses dipole interactions and dispersion forces, making them weaker than hydrogen bonding.

4. What is the oxidation state of the oxygen atom in the compound NaOH?

A. -2
B. -1
C. 0
D. +2

Correct answer: B

Rationale: In the compound NaOH (sodium hydroxide), the oxidation state of the sodium ion (Na) is +1 as it commonly has a +1 charge in ionic compounds. Oxygen (O) typically has an oxidation state of -2 in most compounds. Since the compound is electrically neutral and the overall charge is zero, the sum of the oxidation states of all atoms in the compound must be zero. Therefore, considering that sodium has an oxidation state of +1, the oxygen atom in NaOH must have an oxidation state of -1 to balance the charges and overall neutrality of the compound. Choice A (-2) is incorrect as this is not the oxidation state of oxygen in this compound. Choice C (0) is incorrect as oxygen in NaOH does not have an oxidation state of 0. Choice D (+2) is incorrect as oxygen typically has a negative oxidation state in compounds, not a positive one.

5. A radioactive isotope has a half-life of 20 years. How many grams of a 6-gram sample will remain after 40 years?

A. 8
B. 6
C. 3
D. 1.5

Correct answer: C

Rationale: The half-life of a radioactive isotope is the time it takes for half of the original sample to decay. After each half-life period, half of the initial sample remains. In this case, after the first 20 years, half of the 6-gram sample (3 grams) will remain. After another 20 years (total of 40 years), half of the remaining 3 grams will remain, which is 1.5 grams. Therefore, 3 grams will be left after 40 years. Choice A is incorrect as it doesn't consider the concept of half-life and incorrectly suggests an increase in the sample. Choice B is incorrect as it assumes no decay over time. Choice D is incorrect as it miscalculates the remaining amount after two half-life periods.