HESI A2
HESI A2 Chemistry Questions
1. In which state of matter are particles packed tightly together in a fixed position?
- A. Liquid
- B. Solid
- C. Gas
- D. Plasma
Correct answer: B
Rationale: In a 'solid' state, particles are tightly packed in fixed positions, maintaining a definite shape and volume. This arrangement allows solids to maintain a rigid structure. Liquids have particles that are close together but can move past each other, giving them the ability to flow and take the shape of their container. Gases have particles that are far apart and move freely, leading to their ability to expand to fill any container. Plasma is an ionized gas where particles have high energy levels and are not packed tightly together, making it an uncommon state of matter on Earth.
2. Which statement is true of a saturated solution?
- A. It has more solute than can dissolve in the solvent.
- B. It has less solute that can dissolve in the solvent.
- C. It has the maximum concentration of the solute dissolved in the solvent.
- D. It contains a precipitate that lowers the concentration of the solute in the solvent.
Correct answer: C
Rationale: A saturated solution contains the maximum concentration of solute that can be dissolved in a specific amount of solvent at a particular temperature. Once a solution is saturated, adding more solute will not increase its concentration since the excess solute will not dissolve and will instead form a precipitate, indicating that the solution is at its maximum capacity. Choices A, B, and D are incorrect because a saturated solution has reached its limit in dissolving solute, so it cannot contain more solute than it can dissolve (choice A), less solute than it can dissolve (choice B), or a precipitate that lowers the concentration of the solute in the solvent (choice D).
3. Which ion would you expect to dominate in water solutions of bases?
- A. MgCl₂
- B. 2HCl
- C. H⁺
- D. OH⁻
Correct answer: D
Rationale: In water solutions of bases, the dominant ion would be OH⁻ (hydroxide ion). Bases release OH⁻ ions when dissolved in water, increasing the concentration of hydroxide ions and leading to a higher pH. This is in contrast to acids, which release H⁺ ions. Therefore, in water solutions of bases, the presence of OH⁻ ions signifies the basic nature of the solution. Choices A, B, and C are incorrect because MgCl₂ is a salt, 2HCl is a compound consisting of two hydrogen ions and one chloride ion, and H⁺ represents a hydrogen ion typically associated with acids, not bases.
4. Which substance causes a drop to rapidly turn litmus dye from blue to red?
- A. Milk
- B. Sea water
- C. Ammonia
- D. Lemon juice
Correct answer: D
Rationale: Lemon juice is the correct answer as it is acidic in nature. Acids like lemon juice release hydrogen ions when dissolved in water, which causes litmus dye to change color from blue to red. Milk (Choice A) is neutral, sea water (Choice B) is slightly alkaline, and ammonia (Choice C) is a base. Therefore, these substances do not cause litmus dye to change from blue to red.
5. Which intermolecular force is the strongest?
- A. Dipole interactions
- B. Dispersion forces
- C. Hydrogen bonding
- D. Van der Waals forces
Correct answer: C
Rationale: Hydrogen bonding is the strongest intermolecular force due to its specific interaction between a hydrogen atom and a highly electronegative atom like nitrogen, oxygen, or fluorine. This type of bonding results in a very strong attraction between molecules, making it the strongest intermolecular force among the options provided. Dipole interactions (choice A) are weaker than hydrogen bonding as they occur between polar molecules. Dispersion forces (choice B) are the weakest intermolecular forces and are caused by temporary fluctuations in electron distribution. Van der Waals forces (choice D) are a broader term that encompasses dipole interactions and dispersion forces, making them weaker than hydrogen bonding.
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