HESI A2
HESI A2 Chemistry Questions
1. In which state of matter are particles packed tightly together in a fixed position?
- A. Liquid
- B. Solid
- C. Gas
- D. Plasma
Correct answer: B
Rationale: In a 'solid' state, particles are tightly packed in fixed positions, maintaining a definite shape and volume. This arrangement allows solids to maintain a rigid structure. Liquids have particles that are close together but can move past each other, giving them the ability to flow and take the shape of their container. Gases have particles that are far apart and move freely, leading to their ability to expand to fill any container. Plasma is an ionized gas where particles have high energy levels and are not packed tightly together, making it an uncommon state of matter on Earth.
2. Here are the solubilities of four substances at 0°C, in grams of solute per 100 mL of water. If the temperature increases to 20°C, what would you expect to happen to the solubility figures?
- A. Citric acid and potassium phosphate will decrease; nitrogen and oxygen will increase.
- B. Citric acid and potassium phosphate will increase; nitrogen and oxygen will decrease.
- C. All four figures will increase.
- D. All four figures will decrease.
Correct answer: C
Rationale: Solubility generally tends to increase with temperature for most solid solutes in liquid solvents due to higher kinetic energy leading to better solute-solvent interactions. As the temperature increases from 0°C to 20°C, all four solubility figures are expected to increase. Choice A is incorrect because solubility tends to increase with temperature. Choice B is incorrect as well for the same reason. Choice D is incorrect because the solubility of solid solutes typically increases with temperature.
3. What type of bond is present in sodium chloride?
- A. Covalent
- B. Ionic
- C. Metallic
- D. Hydrogen
Correct answer: B
Rationale: Ionic bonds are found in sodium chloride. In an ionic bond, one atom donates an electron to another atom, resulting in the formation of positively and negatively charged ions that are held together by electrostatic forces of attraction. Sodium chloride is a classic example of an ionic compound, where sodium (Na) donates an electron to chlorine (Cl), forming Na+ and Cl- ions that are attracted to each other, creating a crystal lattice structure. Covalent bonds involve the sharing of electron pairs between atoms, which is not the case in sodium chloride. Metallic bonds occur in metals where electrons are delocalized and shared across a lattice, unlike the specific transfer seen in ionic bonds. Hydrogen bonds are a type of intermolecular force, not the primary bond type present in sodium chloride.
4. What are the horizontal rows of the periodic table called?
- A. Periods
- B. Families
- C. Groups
- D. Columns
Correct answer: A
Rationale: The correct answer is A: Periods. Rows in the periodic table are called periods. They are arranged horizontally from left to right and represent the energy levels of the elements. Each period starts a new energy level or shell, indicating the number of electron shells an element has. Choices B, C, and D are incorrect. Families and groups refer to vertical columns in the periodic table that share similar chemical properties, while columns are vertical arrangements of elements known as groups or families.
5. What does the term amphoteric mean?
- A. A substance that only acts as a base
- B. A substance that can act as both a base and an acid
- C. A substance that only acts as an acid
- D. A substance that acts as neither a base nor an acid
Correct answer: B
Rationale: The term 'amphoteric' refers to substances that have the ability to act as both acids and bases depending on the surrounding conditions. This dual nature allows amphoteric substances to donate or accept protons, making them versatile in various chemical reactions. Choice A is incorrect because amphoteric substances can also act as acids. Choice C is incorrect as amphoteric substances can also act as bases. Choice D is incorrect as amphoteric substances can act as either a base or an acid.
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