HESI A2
HESI A2 Chemistry Questions
1. Which of the following is a characteristic of an exothermic reaction?
- A. It absorbs heat
- B. It releases heat
- C. It remains neutral
- D. It requires energy input
Correct answer: B
Rationale: An exothermic reaction is characterized by the release of heat. During an exothermic reaction, energy is released in the form of heat to the surroundings, resulting in a temperature increase. This distinguishes it from endothermic reactions, which absorb heat from the surroundings. Choice A is incorrect because exothermic reactions do not absorb heat; instead, they release heat. Choice C is incorrect as exothermic reactions do not remain neutral; they involve a net release of energy. Choice D is incorrect as exothermic reactions do not require energy input; instead, they release energy.
2. Why does fluorine have a higher ionization energy than oxygen?
- A. Fluorine has a smaller number of neutrons.
- B. Fluorine has a larger number of neutrons.
- C. Fluorine has a smaller nuclear charge.
- D. Fluorine has a larger nuclear charge.
Correct answer: D
Rationale: Fluorine has a higher ionization energy than oxygen because fluorine has a larger nuclear charge. The greater number of protons in the nucleus of fluorine attracts its electrons more strongly, making it harder to remove an electron from a fluorine atom compared to an oxygen atom. Choice A is incorrect as the number of neutrons does not directly affect ionization energy. Choice B is also incorrect for the same reason. Choice C is incorrect because a smaller nuclear charge would result in lower ionization energy, not higher.
3. Which of the following is the weakest intermolecular force?
- A. Dipole interactions
- B. Hydrogen bonding
- C. Van der Waals forces
- D. Dispersion forces
Correct answer: D
Rationale: Dispersion forces, also known as London dispersion forces, are the weakest intermolecular forces. They are temporary attractive forces that occur due to momentary shifts in electron distribution within molecules. While dipole interactions, hydrogen bonding, and Van der Waals forces are stronger intermolecular forces, dispersion forces are the weakest because they arise from short-lived fluctuations in electron density. Dipole interactions involve permanent dipoles in molecules, making them stronger than dispersion forces. Hydrogen bonding is stronger than dipole interactions and involves hydrogen atoms bonded to highly electronegative atoms. Van der Waals forces encompass dipole-dipole interactions and dispersion forces, making them stronger than dispersion forces alone.
4. Among the following elements, which is a nonmetal?
- A. Mercury
- B. Magnesium
- C. Sulfur
- D. Potassium
Correct answer: C
Rationale: Sulfur is a nonmetal as it is located on the right side of the periodic table. Nonmetals generally exhibit properties such as being brittle, poor conductors of heat and electricity, and having lower melting points compared to metals. Mercury (A), Magnesium (B), and Potassium (D) are all metals due to their metallic properties. Mercury is a liquid metal at room temperature, Magnesium is a solid metal, and Potassium is a solid metal as well. Therefore, the correct answer is C, Sulfur.
5. What is the mass number of an atom with 6 protons, 6 neutrons, and 6 electrons?
- A. 12
- B. 18
- C. 6
- D. 8
Correct answer: A
Rationale: The mass number of an atom is the sum of protons and neutrons. In this case, the atom has 6 protons and 6 neutrons, thus the mass number is 6 + 6 = 12. Therefore, choice A (12) is the correct answer. Choices B (18), C (6), and D (8) are incorrect because the mass number is determined by the sum of protons and neutrons, not the number of electrons or a different combination of particles.
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