HESI A2
HESI A2 Chemistry
1. If fifty-six kilograms of a radioactive substance has a half-life of 12 days, how many days will it take the substance to decay naturally to only 7 kilograms?
- A. 8
- B. 12
- C. 36
- D. 48
Correct answer: C
Rationale: To decay from 56 kg to 7 kg, the substance needs to go through 3 half-lives (56 kg ÷ 2 ÷ 2 ÷ 2 = 7 kg). Since each half-life is 12 days, the total time required is 12 days per half-life x 3 half-lives = 36 days. Choice A is incorrect because it does not consider the concept of half-lives. Choice B is incorrect because it represents the duration of a single half-life, not the total time required for the decay. Choice D is incorrect as it does not account for the multiple half-lives needed for the substance to decay from 56 kg to 7 kg.
2. The three important allotropic forms of phosphorus are red, white, and ___________.
- A. green
- B. gray
- C. black
- D. silver
Correct answer: C
Rationale: The three important allotropic forms of phosphorus are red, white, and black. These forms indicate the different physical properties and reactivity of phosphorus under various conditions. Red phosphorus is more stable and less reactive than white phosphorus, while black phosphorus is the least reactive form. Choice C, 'black,' is the correct answer as it completes the sequence of allotropic forms of phosphorus. Choices A, 'green,' B, 'gray,' and D, 'silver,' are incorrect as they do not represent recognized forms of phosphorus.
3. Which of the following elements does not exist as a diatomic molecule?
- A. boron
- B. fluorine
- C. oxygen
- D. nitrogen
Correct answer: A
Rationale: The correct answer is 'boron.' Diatomic molecules consist of two atoms of the same element bonded together. Boron is an exception and does not exist naturally as a diatomic molecule. On the other hand, fluorine, oxygen, and nitrogen commonly exist as diatomic molecules in their natural states. Fluorine, for example, exists as F2, oxygen exists as O2, and nitrogen exists as N2.
4. Which of these types of intermolecular force is the strongest?
- A. Dipole-dipole interaction
- B. London dispersion force
- C. Keesom interaction
- D. Hydrogen bonding
Correct answer: D
Rationale: Hydrogen bonding is the strongest type of intermolecular force among the options provided. It occurs when a hydrogen atom is covalently bonded to a highly electronegative atom (such as nitrogen, oxygen, or fluorine) and forms a strong electrostatic attraction with an unshared pair of electrons on another electronegative atom. This type of bond is stronger than dipole-dipole interactions, London dispersion forces, and Keesom interactions due to the significant electronegativity difference between the hydrogen and the electronegative atom involved in the bond. The presence of hydrogen bonding contributes to unique properties in substances, such as high boiling and melting points, making it a crucial force in various biological and chemical processes.
5. How does increasing the concentration of reactants affect a chemical reaction?
- A. Decreases the reaction rate
- B. Increases the reaction rate
- C. Stops the reaction
- D. Has no effect
Correct answer: B
Rationale: Increasing the concentration of reactants leads to more reactant particles being available, which, in turn, increases the likelihood of successful collisions between particles. This higher frequency of collisions results in a higher reaction rate. Therefore, option B, 'Increases the reaction rate,' is the correct answer. Choice A, 'Decreases the reaction rate,' is incorrect because higher reactant concentration usually speeds up the reaction. Choice C, 'Stops the reaction,' is incorrect as increasing concentration promotes more collisions, enhancing the reaction. Choice D, 'Has no effect,' is incorrect because changing reactant concentration directly impacts the reaction rate in most cases.
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