HESI A2
HESI A2 Chemistry
1. The three important allotropic forms of phosphorus are red, white, and ___________.
- A. green
- B. gray
- C. black
- D. silver
Correct answer: C
Rationale: The three important allotropic forms of phosphorus are red, white, and black. These forms indicate the different physical properties and reactivity of phosphorus under various conditions. Red phosphorus is more stable and less reactive than white phosphorus, while black phosphorus is the least reactive form. Choice C, 'black,' is the correct answer as it completes the sequence of allotropic forms of phosphorus. Choices A, 'green,' B, 'gray,' and D, 'silver,' are incorrect as they do not represent recognized forms of phosphorus.
2. Which of these intermolecular forces might represent attraction between atoms of a noble gas?
- A. Dipole-dipole interaction
- B. London dispersion force
- C. Keesom interaction
- D. Hydrogen bonding
Correct answer: B
Rationale: Noble gases are non-polar molecules without a permanent dipole moment. The only intermolecular force applicable to noble gases is the London dispersion force, also known as Van der Waals forces. This force is a temporary attractive force resulting from the formation of temporary dipoles in non-polar molecules. Dipole-dipole interactions, Keesom interactions, and hydrogen bonding involve significant dipoles or hydrogen atoms bonded to electronegative atoms, which do not apply to noble gases.
3. Which of the following elements is a noble gas?
- A. Hydrogen
- B. Fluorine
- C. Argon
- D. Nitrogen
Correct answer: C
Rationale: The correct answer is C: Argon. Argon is a noble gas, part of Group 18 in the periodic table. Noble gases are colorless, odorless, and typically non-reactive under normal conditions. Other elements in this group include helium, neon, krypton, xenon, and radon. Argon finds wide applications in welding, lighting, and scientific research. Choices A, B, and D are not noble gases. Hydrogen is a non-metal, Fluorine is a halogen, and Nitrogen is a diatomic non-metal gas.
4. Which element has the highest electronegativity?
- A. Fluorine
- B. Chlorine
- C. Nitrogen
- D. Oxygen
Correct answer: A
Rationale: Fluorine has the highest electronegativity among the elements listed. Electronegativity is a measure of an atom's ability to attract and hold onto electrons in a chemical bond. Fluorine, being the most electronegative element on the periodic table, has the strongest ability to attract electrons towards itself compared to chlorine, nitrogen, and oxygen. Therefore, fluorine is the correct answer. Chlorine, nitrogen, and oxygen have lower electronegativities compared to fluorine, making them incorrect choices for the element with the highest electronegativity.
5. Which branch of chemistry deals with the quantities and numeric relationships between compounds in a chemical reaction?
- A. Stoichiometry
- B. Molecular chemistry
- C. Atomic chemistry
- D. Thermodynamics
Correct answer: A
Rationale: Stoichiometry is the branch of chemistry that deals with the quantitative relationships between reactants and products in chemical reactions. It involves the calculation of quantities of substances consumed and produced in a chemical reaction based on the balanced chemical equation. Choice B, 'Molecular chemistry,' is incorrect as it focuses on the structure, properties, and reactions of molecules. Choice C, 'Atomic chemistry,' is incorrect as it primarily deals with the study of atoms and their interactions. Choice D, 'Thermodynamics,' is incorrect as it pertains to the study of energy and heat transfer in chemical and physical processes.
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