HESI A2
HESI A2 Chemistry
1. The three important allotropic forms of phosphorus are red, white, and ___________.
- A. green
- B. gray
- C. black
- D. silver
Correct answer: C
Rationale: The three important allotropic forms of phosphorus are red, white, and black. These forms indicate the different physical properties and reactivity of phosphorus under various conditions. Red phosphorus is more stable and less reactive than white phosphorus, while black phosphorus is the least reactive form. Choice C, 'black,' is the correct answer as it completes the sequence of allotropic forms of phosphorus. Choices A, 'green,' B, 'gray,' and D, 'silver,' are incorrect as they do not represent recognized forms of phosphorus.
2. What are the three types of intermolecular forces?
- A. Ionic, covalent, hydrogen
- B. Hydrogen bonding, dipole interactions, dispersion forces
- C. Van der Waals, ionic, covalent
- D. Hydrogen, Van der Waals, dispersion forces
Correct answer: B
Rationale: The three types of intermolecular forces are hydrogen bonding, dipole interactions, and dispersion forces. Option A includes ionic and covalent bonds, which are intramolecular forces, not intermolecular. Option C includes van der Waals forces, which encompass dipole interactions and dispersion forces, but also includes ionic and covalent bonds. Option D is close but misses dipole interactions, which are distinct from hydrogen bonding and dispersion forces. Therefore, option B is the correct choice as it includes the three specific types of intermolecular forces.
3. Which of the following factors would not affect rates of reaction?
- A. Temperature
- B. Surface area
- C. Pressure
- D. Time
Correct answer: D
Rationale: Time would not directly affect rates of reaction. The rate of a chemical reaction is determined by factors that affect the frequency of successful collisions between reactant molecules, leading to a reaction. Temperature, surface area, and pressure can influence reaction rates by impacting the kinetic energy of molecules, the exposed surface for collisions, and the concentration of reactants, respectively. However, time, in the context of this question, does not alter the rate of reaction but may affect the extent of the reaction or the amount of product formed over time.
4. Which compound contains a polar covalent bond?
- A. O
- B. F
- C. Br
- D. H₂O
Correct answer: D
Rationale: The compound 'H₂O' (water) contains a polar covalent bond. In a water molecule, the oxygen atom is more electronegative than the hydrogen atoms. As a result, the electrons in the O-H bonds are unevenly shared, leading to a partial negative charge on the oxygen atom and partial positive charges on the hydrogen atoms. This unequal sharing of electrons creates a polar covalent bond in water. Choices A, B, and C are incorrect because they represent individual elements, not compounds, and do not involve the concept of polar covalent bonds.
5. What are positively charged ions called?
- A. Neutrons
- B. Protons
- C. Cations
- D. Electrons
Correct answer: C
Rationale: Positively charged ions are called cations. When an atom loses electrons, it becomes positively charged and is referred to as a cation. Neutrons are neutral particles found in the nucleus of an atom, not charged. Protons are positively charged particles in the nucleus. Electrons are negatively charged particles orbiting the nucleus, not positively charged ions.
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