what is always different from one allotrope to another
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HESI A2

HESI A2 Chemistry Practice Questions

1. What distinguishes one allotrope from another?

Correct answer: A

Rationale: Allotropes are different forms of the same element that exist in the same physical state but have different structures. The arrangement of atoms is what distinguishes one allotrope from another, determining their unique properties and characteristics. Gram atomic mass (Choice B) is a constant value for a specific element and does not change between different allotropes. Physical state (Choice C) refers to whether a substance is a solid, liquid, or gas, which can be the same for different allotropes of an element. Stability (Choice D) can vary between different allotropes, but it is not what always differentiates one allotrope from another. Therefore, the correct answer is the arrangement of atoms, as it is the key factor that varies across different allotropes.

2. A radioactive isotope has a half-life of 20 years. How many grams of a 6-gram sample will remain after 40 years?

Correct answer: C

Rationale: The half-life of a radioactive isotope is the time it takes for half of the original sample to decay. After each half-life period, half of the initial sample remains. In this case, after the first 20 years, half of the 6-gram sample (3 grams) will remain. After another 20 years (total of 40 years), half of the remaining 3 grams will remain, which is 1.5 grams. Therefore, 3 grams will be left after 40 years. Choice A is incorrect as it doesn't consider the concept of half-life and incorrectly suggests an increase in the sample. Choice B is incorrect as it assumes no decay over time. Choice D is incorrect as it miscalculates the remaining amount after two half-life periods.

3. On the periodic table, families of elements with similar properties appear in the same _________.

Correct answer: D

Rationale: Families of elements with similar properties appear in the same column on the periodic table. Columns are also known as groups, and elements within the same group have similar chemical and physical properties due to their identical number of valence electrons. Therefore, the correct answer is 'column.' Choice A, 'row,' is incorrect because rows on the periodic table are called periods, not families or groups of elements. Choice B, 'principal energy level,' is incorrect as it refers to the energy levels of electrons around the nucleus of an atom, not the arrangement of elements with similar properties on the periodic table. Choice C, 'period,' is incorrect as periods represent horizontal rows on the periodic table, where elements do not necessarily have similar properties compared to elements in the same column.

4. Cobalt-60 has a half-life of 5 years. If you start with 20 g of cobalt-60, how much is left after 10 years?

Correct answer: C

Rationale: Cobalt-60's half-life of 5 years means that after 5 years, half of the initial amount remains. Therefore, after 10 years, a quarter (half of a half) of the initial amount will remain. Starting with 20 g, after 10 years, 5 g of cobalt-60 will be left. Choice A (15 g) is incorrect because it assumes a linear decrease, not considering the exponential decay characteristic of radioactive substances. Choice B (10 g) is incorrect as it overlooks that after 10 years, more decay has occurred. Choice D (2.5 g) is incorrect as it represents only an eighth of the initial amount after 10 years, not a quarter.

5. What is the oxidation state of the sulfur atom in sulfuric acid H2SO4?

Correct answer: B

Rationale: In sulfuric acid (H2SO4), sulfur has an oxidation state of +6. The oxidation state is determined by considering the overall charge of the compound and the known oxidation states of other elements. In this case, hydrogen is typically +1, and oxygen is -2. To balance the charges and match the compound's overall charge of 0, sulfur must have an oxidation state of +6. Choice A (4) is incorrect because it doesn't balance the charges in the compound. Choices C (8) and D (10) are also incorrect as they are not valid oxidation states for sulfur in this compound.

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