HESI A2
Chemistry HESI A2 Practice Test
1. What is the oxidation state of the chlorine atom in the compound HCl?
- A. +1
- B. -1
- C. +2
- D. -2
Correct answer: B
Rationale: In the compound HCl (hydrochloric acid), the hydrogen atom has an oxidation state of +1 based on the rules of assigning oxidation states. Since the overall compound is neutral, the oxidation state of chlorine must be -1 to balance the charge. Chlorine typically has an oxidation state of -1 in binary compounds with nonmetals, such as HCl. Therefore, the correct answer is -1. Choices A, C, and D are incorrect as the oxidation state of chlorine in HCl is -1, not +1, +2, or -2.
2. Here are the solubilities of four substances at 0°C, in grams of solute per 100 mL of water. If the temperature increases to 20°C, what would you expect to happen to the solubility figures?
- A. Citric acid and potassium phosphate will decrease; nitrogen and oxygen will increase.
- B. Citric acid and potassium phosphate will increase; nitrogen and oxygen will decrease.
- C. All four figures will increase.
- D. All four figures will decrease.
Correct answer: C
Rationale: Solubility generally tends to increase with temperature for most solid solutes in liquid solvents due to higher kinetic energy leading to better solute-solvent interactions. As the temperature increases from 0°C to 20°C, all four solubility figures are expected to increase. Choice A is incorrect because solubility tends to increase with temperature. Choice B is incorrect as well for the same reason. Choice D is incorrect because the solubility of solid solutes typically increases with temperature.
3. What are the products of combustion of a hydrocarbon in excess oxygen?
- A. Carbon dioxide and water
- B. Naphthalene
- C. Chlorine and bromine
- D. Carbonium ions
Correct answer: A
Rationale: The correct answer is A: Carbon dioxide and water. During the combustion of a hydrocarbon in excess oxygen, the hydrocarbon reacts to produce carbon dioxide and water vapor as the final products. This reaction is known as complete combustion, where the hydrocarbon combines with oxygen to form carbon dioxide and water. Choices B, C, and D are incorrect because naphthalene is a specific hydrocarbon compound, chlorine and bromine are not typically formed during the combustion of hydrocarbons in excess oxygen, and carbonium ions are not the products of this reaction.
4. If electrons are not shared equally in a covalent bond, the bond is what?
- A. Polar
- B. Non-polar
- C. Ionic
- D. Hydrogen
Correct answer: A
Rationale: A polar covalent bond occurs when electrons are shared unequally between atoms. In this type of bond, one atom has a stronger pull on the shared electrons, leading to a partial positive and partial negative charge distribution within the molecule. Choice B, non-polar, is incorrect because in non-polar covalent bonds, electrons are shared equally between atoms. Choice C, ionic, is incorrect as ionic bonds involve a transfer of electrons rather than sharing. Choice D, hydrogen, is incorrect as it does not describe the nature of a covalent bond.
5. Which two functional groups would you expect an amino acid to contain?
- A. R-NH2 and R-COOH
- B. R-CHO and R-CO-NH
- C. R-OH and R-COOR
- D. R-O-R and R-COOH
Correct answer: A
Rationale: Amino acids are organic compounds that are characterized by the presence of an amino group (NH2) and a carboxylic acid group (COOH) in their chemical structure. These two functional groups, found in option A, are fundamental components of amino acids and play crucial roles in their classification and biological functions. Option B contains an aldehyde group (CHO) and an amide group (CO-NH), which are not characteristic functional groups of amino acids. Option C includes a hydroxyl group (OH) and an ester group (COOR), which are not typically present in amino acids. Option D presents ether (R-O-R) and carboxylic acid (COOH) functional groups, which do not represent the functional groups commonly found in amino acids.
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