HESI A2
HESI A2 Chemistry
1. What is the name of the compound CH₃-CH₂-CH₂-CH₃?
- A. Cyclobutane
- B. Butane
- C. Butene
- D. Butyne
Correct answer: B
Rationale: The compound CH₃-CH₂-CH₂-CH₃ is named butane. Butane is a straight-chain alkane comprising four carbon atoms connected by single bonds. The prefix 'but-' denotes the presence of four carbon atoms, while the suffix '-ane' indicates it is an alkane with single bonds between the carbon atoms. Choice A, Cyclobutane, is incorrect as it refers to a cyclic hydrocarbon with four carbon atoms in a ring structure. Choice C, Butene, is incorrect because it is an alkene with a double bond between two carbon atoms, not a saturated hydrocarbon like butane. Choice D, Butyne, is also incorrect as it is an alkyne with a triple bond between two carbon atoms, unlike the single bonds in butane.
2. In what type of covalent compounds are dispersion forces typically found?
- A. Polar
- B. Non-polar
- C. Ionic
- D. Hydrogen
Correct answer: B
Rationale: Dispersion forces, also known as London dispersion forces, are the weakest intermolecular forces that occur in non-polar covalent compounds. These forces result from temporary shifts in electron density within molecules, creating temporary dipoles. As a result, non-polar molecules, which lack a permanent dipole moment, can experience these dispersion forces. Polar compounds exhibit stronger intermolecular forces such as dipole-dipole interactions or hydrogen bonding, while ionic compounds involve electrostatic interactions between ions. Therefore, the correct answer is non-polar (choice B). Choices A, C, and D are incorrect because dispersion forces are typically found in non-polar covalent compounds, not polar, ionic, or hydrogen-bonded compounds.
3. What does the mass number minus the atomic number equal?
- A. Number of electrons
- B. Number of neutrons
- C. Number of protons
- D. Number of isotopes
Correct answer: B
Rationale: The mass number of an atom represents the total number of protons and neutrons in its nucleus. The atomic number indicates the number of protons in the nucleus. The difference between the mass number and the atomic number provides the number of neutrons present in the nucleus of an atom. Therefore, mass number minus atomic number equals the number of neutrons. Choice A is incorrect because the number of electrons is not determined by the mass number and atomic number. Choice C is incorrect as it represents the number of protons, not the difference between the mass number and atomic number. Choice D is incorrect as isotopes refer to atoms of the same element with different numbers of neutrons, not the difference between mass number and atomic number.
4. Which element has the highest electronegativity?
- A. Fluorine
- B. Chlorine
- C. Nitrogen
- D. Oxygen
Correct answer: A
Rationale: Fluorine has the highest electronegativity among the elements listed. Electronegativity is a measure of an atom's ability to attract and hold onto electrons in a chemical bond. Fluorine, being the most electronegative element on the periodic table, has the strongest ability to attract electrons towards itself compared to chlorine, nitrogen, and oxygen. Therefore, fluorine is the correct answer. Chlorine, nitrogen, and oxygen have lower electronegativities compared to fluorine, making them incorrect choices for the element with the highest electronegativity.
5. Which of the following is a characteristic of a chemical change?
- A. Change in shape
- B. Production of gas
- C. Melting
- D. Freezing
Correct answer: B
Rationale: The production of gas is a characteristic of a chemical change. During a chemical change, new substances are formed, often with the release or absorption of energy. The production of gas is a significant indicator of a chemical change because it indicates the formation of new compounds through chemical reactions. Choices A, C, and D are not characteristics of chemical changes. Changes in shape, melting, and freezing are physical changes where the substance's identity remains the same, unlike in chemical changes where new substances with different properties are formed.
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