HESI A2
HESI A2 Chemistry
1. What is the name of the compound CH₃-CH₂-CH₂-CH₃?
- A. Cyclobutane
- B. Butane
- C. Butene
- D. Butyne
Correct answer: B
Rationale: The compound CH₃-CH₂-CH₂-CH₃ is named butane. Butane is a straight-chain alkane comprising four carbon atoms connected by single bonds. The prefix 'but-' denotes the presence of four carbon atoms, while the suffix '-ane' indicates it is an alkane with single bonds between the carbon atoms. Choice A, Cyclobutane, is incorrect as it refers to a cyclic hydrocarbon with four carbon atoms in a ring structure. Choice C, Butene, is incorrect because it is an alkene with a double bond between two carbon atoms, not a saturated hydrocarbon like butane. Choice D, Butyne, is also incorrect as it is an alkyne with a triple bond between two carbon atoms, unlike the single bonds in butane.
2. If electrons are not shared equally in a covalent bond, the bond is what?
- A. Polar
- B. Non-polar
- C. Ionic
- D. Hydrogen
Correct answer: A
Rationale: A polar covalent bond occurs when electrons are shared unequally between atoms. In this type of bond, one atom has a stronger pull on the shared electrons, leading to a partial positive and partial negative charge distribution within the molecule. Choice B, non-polar, is incorrect because in non-polar covalent bonds, electrons are shared equally between atoms. Choice C, ionic, is incorrect as ionic bonds involve a transfer of electrons rather than sharing. Choice D, hydrogen, is incorrect as it does not describe the nature of a covalent bond.
3. What is the coefficient of O after the following equation is balanced?
- A. 1
- B. 2
- C. 3
- D. 4
Correct answer: A
Rationale: In a balanced chemical equation, the coefficient of oxygen (O) in O2 is already 2, so there is no need to adjust its coefficient further. Therefore, the coefficient of O remains as 1. Since the coefficient of O2 is 2, each O atom is represented by the coefficient of 1, and it does not change during the balancing process. Choices B, C, and D are incorrect as they suggest changing the coefficient of oxygen, which is not necessary for O2 in a balanced equation.
4. What is the correct formula for sodium nitrate?
- A. NaNO
- B. Na NO
- C. NaNO₃
- D. Na NOâ‚‚
Correct answer: C
Rationale: The correct formula for sodium nitrate is NaNO₃. In this formula, 'Na' represents sodium, 'N' represents nitrogen, and 'O₃' represents three oxygen atoms. Sodium nitrate consists of one sodium ion (Naâº) and one nitrate ion (NO₃â»), which means the correct formula is NaNO₃. Choice A (NaNO) is incorrect as it lacks the subscript indicating the presence of three oxygen atoms. Choice B (Na NO) is incorrect as it includes a space between 'Na' and 'NO', which is not part of the standard chemical formula notation. Choice D (Na NOâ‚‚) is incorrect as it indicates a different compound with a nitrite ion (NOâ‚‚â») instead of nitrate ion.
5. The molar mass of glucose is 180 g/mol. If an IV solution contains 5 g of glucose in 100 g of water, what is the molarity of the solution?
- A. 0.28M
- B. 1.8M
- C. 2.8M
- D. 18M
Correct answer: C
Rationale: To calculate the molarity of the solution, we first need to determine the moles of solute (glucose) and solvent (water) separately. The molar mass of glucose is 180 g/mol. First, calculate the moles of glucose: 5 g / 180 g/mol = 0.02778 mol of glucose. Next, calculate the moles of water: 100 g / 18 g/mol = 5.56 mol of water. Now, calculate the total moles in the solution: 0.02778 mol glucose + 5.56 mol water = 5.5878 mol. Finally, calculate the molarity: Molarity = moles of solute / liters of solution. Since the total mass of the solution is 100 g + 5 g = 105 g = 0.105 kg, which is equal to 0.105 L, the molarity is 5.5878 mol / 0.105 L = 53.22 M, which rounds to 2.8M. Therefore, the correct answer is 2.8M. Choices A, B, and D are incorrect because they do not reflect the accurate molarity calculation based on the moles of solute and volume of the solution.
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