HESI A2
HESI A2 Chemistry
1. What is the correct electron configuration for magnesium?
- A. 1s² 2s²
- B. 1s² 2s² 2pâ¶
- C. 1s² 2s² 2pⶠ3s²
- D. 1s² 2s² 2pⶠ3s² 3p¹
Correct answer: C
Rationale: The electron configuration of an element is determined by following the Aufbau principle, which states that electrons fill orbitals starting from the lowest energy level. Magnesium has an atomic number of 12, meaning it has 12 electrons. The electron configuration of magnesium fills the 1s, 2s, 2p, and 3s orbitals to accommodate all 12 electrons. Therefore, the correct electron configuration for magnesium is 1s² 2s² 2pⶠ3s². Choice A is incorrect as it only includes 4 electrons and stops at the 2s orbital. Choice B is incorrect as it includes 8 electrons and stops at the 2p orbital. Choice D is incorrect as it includes 13 electrons and extends to the 3p orbital, which is beyond the actual electron configuration of magnesium.
2. Which of the following best describes an endothermic reaction?
- A. A reaction that absorbs heat
- B. A reaction that releases heat
- C. A reaction that does not involve heat
- D. A reaction that remains at a constant temperature
Correct answer: A
Rationale: An endothermic reaction is a process that absorbs heat from its surroundings. When a reaction absorbs heat, it leads to a decrease in the temperature of the surroundings, making choice A the correct description. In an endothermic reaction, energy is taken in from the surroundings, resulting in a decrease in temperature around the reaction site. Choice B is incorrect because a reaction that releases heat is known as an exothermic reaction. Choice C is incorrect as all reactions involve heat to some extent. Choice D is incorrect as an endothermic reaction does not remain at a constant temperature but rather absorbs heat, leading to a temperature decrease in the surroundings.
3. How many neutrons are in an atom of helium-4?
- A. 2
- B. 3
- C. 4
- D. 6
Correct answer: A
Rationale: The atomic number of helium is 2, indicating it has 2 protons. Helium-4, the most common isotope of helium, has 2 neutrons in addition to its 2 protons. Therefore, the correct answer is 2 neutrons in an atom of helium-4. Choice B, C, and D are incorrect as they do not match the correct composition of helium-4, which consists of 2 protons and 2 neutrons.
4. Which of the following is a colligative property of a solution?
- A. Freezing point depression
- B. Viscosity
- C. Surface tension
- D. Boiling point elevation
Correct answer: A
Rationale: A colligative property is a property that depends on the number of solute particles in a solution, not on the identity of the solute particles. Freezing point depression is one such property, where adding a solute to a solvent lowers the freezing point of the solution compared to the pure solvent. This phenomenon occurs because the presence of solute particles disrupts the formation of the regular crystal lattice structure, requiring a lower temperature for solidification to occur. Choices B, C, and D are not colligative properties. Viscosity and surface tension are not dependent on the number of solute particles but on intermolecular forces and molecular interactions. Boiling point elevation is another colligative property, but in this case, the question asked for a colligative property of a solution, making freezing point depression the correct answer.
5. Which state of matter has a definite volume but takes the shape of its container?
- A. Gas
- B. Liquid
- C. Solid
- D. Plasma
Correct answer: B
Rationale: The state of matter that has a definite volume but takes the shape of its container is a 'Liquid.' Liquids have a fixed volume but can change their shape to fit the container they are in. This property distinguishes liquids from solids, which have both a definite shape and volume, and gases, which do not have a fixed volume or shape. Therefore, the correct answer is 'Liquid.' Choice A, 'Gas,' is incorrect because gases do not have a definite volume or shape. Choice C, 'Solid,' is incorrect as solids have a definite shape and volume. Choice D, 'Plasma,' is incorrect because plasma is a state of matter where atoms have been ionized and do not have a fixed volume or shape.
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