HESI A2
HESI A2 Chemistry
1. What is the correct electron configuration for magnesium?
- A. 1s² 2s²
- B. 1s² 2s² 2pâ¶
- C. 1s² 2s² 2pⶠ3s²
- D. 1s² 2s² 2pⶠ3s² 3p¹
Correct answer: C
Rationale: The electron configuration of an element is determined by following the Aufbau principle, which states that electrons fill orbitals starting from the lowest energy level. Magnesium has an atomic number of 12, meaning it has 12 electrons. The electron configuration of magnesium fills the 1s, 2s, 2p, and 3s orbitals to accommodate all 12 electrons. Therefore, the correct electron configuration for magnesium is 1s² 2s² 2pⶠ3s². Choice A is incorrect as it only includes 4 electrons and stops at the 2s orbital. Choice B is incorrect as it includes 8 electrons and stops at the 2p orbital. Choice D is incorrect as it includes 13 electrons and extends to the 3p orbital, which is beyond the actual electron configuration of magnesium.
2. What type of bond is present in sodium chloride?
- A. Covalent
- B. Ionic
- C. Metallic
- D. Hydrogen
Correct answer: B
Rationale: Ionic bonds are found in sodium chloride. In an ionic bond, one atom donates an electron to another atom, resulting in the formation of positively and negatively charged ions that are held together by electrostatic forces of attraction. Sodium chloride is a classic example of an ionic compound, where sodium (Na) donates an electron to chlorine (Cl), forming Na+ and Cl- ions that are attracted to each other, creating a crystal lattice structure. Covalent bonds involve the sharing of electron pairs between atoms, which is not the case in sodium chloride. Metallic bonds occur in metals where electrons are delocalized and shared across a lattice, unlike the specific transfer seen in ionic bonds. Hydrogen bonds are a type of intermolecular force, not the primary bond type present in sodium chloride.
3. Which best defines the molarity of an aqueous sugar solution?
- A. Grams of sugar per milliliter of solution
- B. Moles of sugar per milliliter of solution
- C. Grams of sugar per liter of solution
- D. Moles of sugar per liter of solution
Correct answer: D
Rationale: The molarity of a solution is defined as the number of moles of solute per liter of solvent. In the case of an aqueous sugar solution, the molarity would be expressed as moles of sugar per liter of solution. This is because molarity is a measurement of the concentration of a solute in a solution based on the number of moles present in a given volume of the solution. Therefore, the correct answer is D. Choices A, B, and C are incorrect because the molarity is specifically defined in terms of moles of solute per liter of solution, not in grams per milliliter or grams per liter. Molarity is a unit of concentration that relates the amount of solute to the volume of the solution, not the mass of the solute.
4. What is a benefit of water's ability to make hydrogen bonds?
- A. Lack of cohesiveness
- B. Low surface tension
- C. Use as a nonpolar solvent
- D. High specific heat
Correct answer: D
Rationale: The correct answer is D, high specific heat. Water's ability to form hydrogen bonds results in a high specific heat capacity, allowing it to absorb and release a large amount of heat energy with minimal temperature change. This property is essential for moderating temperature changes in organisms and maintaining stable environmental conditions for life processes. Choices A, lack of cohesiveness, and C, use as a nonpolar solvent, are incorrect. Water actually has high cohesiveness due to its ability to form hydrogen bonds, and it is a polar solvent, not nonpolar. Choice B, low surface tension, is also incorrect as water's hydrogen bonding contributes to its relatively high surface tension.
5. What is stoichiometry?
- A. The study of energy changes in chemical reactions
- B. The study of the mass relationships in chemical reactions
- C. The study of atomic structure
- D. The study of molecular geometry
Correct answer: B
Rationale: Stoichiometry is the branch of chemistry that deals with the quantitative relationships between reactants and products in chemical reactions. It focuses on the calculation of the amounts of substances consumed and produced in a reaction based on the balanced chemical equation. Choice A is incorrect because the study of energy changes in chemical reactions falls under thermodynamics. Choice C is incorrect as atomic structure is related to the arrangement of atoms within molecules. Choice D is incorrect as molecular geometry deals with the spatial arrangement of atoms within molecules.
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