HESI A2
Chemistry HESI A2 Quizlet
1. Which of the following types of matter changes in volume with changes in temperature and pressure?
- A. Liquid
- B. Gas
- C. Solid
- D. Plasma
Correct answer: B
Rationale: A gas changes its volume with changes in temperature and pressure due to the particles moving more rapidly at higher temperatures, and pressure affects the space between particles. Liquids have a relatively fixed volume but take the shape of their container. Solids have a definite shape and volume, so they do not change volume with changes in temperature and pressure. Plasma is a state of matter where particles are highly energized and do not have a fixed volume, but it does not exhibit volume changes with temperature and pressure variations.
2. In the periodic table, which group contains the alkali metals?
- A. Group 7
- B. Group 1
- C. Group 2
- D. Group 3
Correct answer: B
Rationale: The correct answer is Group 1. Alkali metals are found in Group 1 of the periodic table, which includes elements such as lithium, sodium, and potassium. These elements are known for their high reactivity and tendency to form alkaline solutions when they react with water. Therefore, Group 1 is specifically designated as the group containing alkali metals. Choice A (Group 7) is incorrect as Group 7 contains the halogens. Choice C (Group 2) is incorrect as Group 2 contains the alkaline earth metals. Choice D (Group 3) is incorrect as Group 3 contains the scandium group of elements.
3. What creates a dipole in a covalent bond?
- A. Unequal sharing of electrons
- B. Equal sharing of electrons
- C. Exchange of electrons
- D. Transfer of electrons
Correct answer: A
Rationale: A dipole is created in a covalent bond when there is an unequal sharing of electrons between the atoms involved. This results in a partial positive charge on one atom and a partial negative charge on the other, leading to a separation of charges and the formation of a dipole. Choices B, C, and D are incorrect because a dipole is specifically formed due to unequal sharing of electrons, not equal sharing, exchange, or transfer of electrons in a covalent bond.
4. Which of the following substances is a base?
- A. Water
- B. Sodium chloride
- C. Ammonia
- D. Salt
Correct answer: C
Rationale: The correct answer is 'Ammonia' (Choice C) as it is a common example of a base. Bases are substances that release hydroxide ions (OH-) in aqueous solutions, helping to increase the pH level. Ammonia is a weak base that can accept a proton (H+) to form ammonium hydroxide. In contrast, water (Choice A), sodium chloride (Choice B), and salt (Choice D) are not bases; water is neutral, while sodium chloride and salt are neutral compounds composed of a cation and an anion.
5. Which of these types of intermolecular force is weakest?
- A. Dipole-dipole interaction
- B. London dispersion force
- C. Hydrogen bonding
- D. Ionic bonding
Correct answer: B
Rationale: The correct answer is B, London dispersion force. London dispersion forces are the weakest type of intermolecular force among the options provided. These forces arise from temporary fluctuations in electron distribution within molecules, leading to temporary dipoles. London dispersion forces are present in all molecules and are generally weaker than dipole-dipole interactions, hydrogen bonding, and ionic bonding. Dipole-dipole interactions are stronger than London dispersion forces as they involve permanent dipoles in molecules. Hydrogen bonding is stronger than both London dispersion and dipole-dipole interactions as it is a special type of dipole-dipole interaction that occurs when hydrogen is bonded to highly electronegative atoms like oxygen or nitrogen. Ionic bonding is the strongest type of intermolecular force among the options, but it is not the correct answer for the weakest type of force.
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