matter that changes in volume with changes in temperature and pressure
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HESI A2

Chemistry HESI A2 Quizlet

1. Which of the following types of matter changes in volume with changes in temperature and pressure?

Correct answer: B

Rationale: A gas changes its volume with changes in temperature and pressure due to the particles moving more rapidly at higher temperatures, and pressure affects the space between particles. Liquids have a relatively fixed volume but take the shape of their container. Solids have a definite shape and volume, so they do not change volume with changes in temperature and pressure. Plasma is a state of matter where particles are highly energized and do not have a fixed volume, but it does not exhibit volume changes with temperature and pressure variations.

2. Why does fluorine have a higher ionization energy than oxygen?

Correct answer: D

Rationale: Fluorine has a higher ionization energy than oxygen because fluorine has a larger nuclear charge. The greater number of protons in the nucleus of fluorine attracts its electrons more strongly, making it harder to remove an electron from a fluorine atom compared to an oxygen atom. Choice A is incorrect as the number of neutrons does not directly affect ionization energy. Choice B is also incorrect for the same reason. Choice C is incorrect because a smaller nuclear charge would result in lower ionization energy, not higher.

3. What is the molarity of a solution containing 45 moles of NaCl in 4 liters?

Correct answer: A

Rationale: To calculate the molarity of a solution, you use the formula: Molarity (M) = moles of solute / liters of solution. In this case, M = 45 moles / 4 L = 11.25 M. The correct answer is 0.11 M NaCl. Choice B is incorrect as it doesn't match the calculated value. Choice C is also incorrect as it is significantly higher than the correct molarity. Choice D is incorrect as it is excessively high compared to the calculated value.

4. Which factor does not affect the reaction rate of a chemical reaction?

Correct answer: D

Rationale: The color of reactants is not a factor that affects the rate of a chemical reaction. Temperature, surface area, and concentration of reactants are known factors that influence the reaction rate. Temperature plays a significant role in altering the reaction rate by affecting the kinetic energy of molecules. Surface area impacts the rate by providing more area for collisions to occur. Concentration affects the frequency of effective collisions. On the other hand, the color of reactants is a physical property that does not directly affect the speed of a chemical reaction.

5. What is the pH of acids?

Correct answer: B

Rationale: The correct answer is B: < 7. Acids have a pH lower than 7, indicating higher acidity. A pH below 7 signifies an acidic solution, with lower values indicating stronger acids. Choice A (7.5) is incorrect as it is greater than 7, which is alkaline. Choice C (> 7) is incorrect as values greater than 7 represent alkaline/basic solutions. Choice D (7) is incorrect because a pH of 7 is neutral, not acidic.

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