HESI A2
Chemistry HESI A2 Quizlet
1. Which of the following types of matter changes in volume with changes in temperature and pressure?
- A. Liquid
- B. Gas
- C. Solid
- D. Plasma
Correct answer: B
Rationale: A gas changes its volume with changes in temperature and pressure due to the particles moving more rapidly at higher temperatures, and pressure affects the space between particles. Liquids have a relatively fixed volume but take the shape of their container. Solids have a definite shape and volume, so they do not change volume with changes in temperature and pressure. Plasma is a state of matter where particles are highly energized and do not have a fixed volume, but it does not exhibit volume changes with temperature and pressure variations.
2. What does the term amphoteric mean?
- A. A substance that only acts as a base
- B. A substance that can act as both a base and an acid
- C. A substance that only acts as an acid
- D. A substance that acts as neither a base nor an acid
Correct answer: B
Rationale: The term 'amphoteric' refers to substances that have the ability to act as both acids and bases depending on the surrounding conditions. This dual nature allows amphoteric substances to donate or accept protons, making them versatile in various chemical reactions. Choice A is incorrect because amphoteric substances can also act as acids. Choice C is incorrect as amphoteric substances can also act as bases. Choice D is incorrect as amphoteric substances can act as either a base or an acid.
3. What is the oxidation state of the chlorine atom in the compound HCl?
- A. +1
- B. -1
- C. +2
- D. -2
Correct answer: B
Rationale: In the compound HCl (hydrochloric acid), the hydrogen atom has an oxidation state of +1 based on the rules of assigning oxidation states. Since the overall compound is neutral, the oxidation state of chlorine must be -1 to balance the charge. Chlorine typically has an oxidation state of -1 in binary compounds with nonmetals, such as HCl. Therefore, the correct answer is -1. Choices A, C, and D are incorrect as the oxidation state of chlorine in HCl is -1, not +1, +2, or -2.
4. Which one does not name a polar molecule?
- A. NH₃
- B. H₂S
- C. SO₂
- D. CO₂
Correct answer: A
Rationale: The correct answer is NH₃. The molecule NH₃ does not represent a polar molecule because nitrogen and hydrogen in this molecule have a small difference in electronegativity that does not result in a significant polar covalent bond. In contrast, molecules H₂S, SO₂, and CO₂ have polar covalent bonds due to larger electronegativity differences, making them polar molecules. Therefore, options B, C, and D are polar molecules, unlike option A.
5. When an acid is added to a base, water and a salt form. What kinds of bonds form in these two compounds?
- A. Liquid and metallic
- B. Polar and nonpolar covalent
- C. Polar covalent and ionic
- D. Ionic only
Correct answer: C
Rationale: In water, the bond formed between the oxygen atom and the hydrogen atoms is a polar covalent bond. The oxygen atom attracts the shared electrons more strongly, creating a partial negative charge on the oxygen and a partial positive charge on the hydrogen atoms. In the salt formed, the bond between the metal cation and the nonmetal anion is predominantly an ionic bond. The metal cation donates electrons to the nonmetal anion, resulting in the formation of oppositely charged ions that are held together by electrostatic attractions. Choices A and B are incorrect because water and salts do not form bonds that are liquid and metallic, or polar and nonpolar covalent. Choice D is incorrect as it oversimplifies the types of bonds present in water and salts, failing to differentiate between the covalent bond in water and the ionic bond in the salt.
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