matter that changes in volume with changes in temperature and pressure
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HESI A2

Chemistry HESI A2 Quizlet

1. Which of the following types of matter changes in volume with changes in temperature and pressure?

Correct answer: B

Rationale: A gas changes its volume with changes in temperature and pressure due to the particles moving more rapidly at higher temperatures, and pressure affects the space between particles. Liquids have a relatively fixed volume but take the shape of their container. Solids have a definite shape and volume, so they do not change volume with changes in temperature and pressure. Plasma is a state of matter where particles are highly energized and do not have a fixed volume, but it does not exhibit volume changes with temperature and pressure variations.

2. What is 119 K in degrees Celsius?

Correct answer: B

Rationale: To convert Kelvin (K) to Celsius (°C), you subtract 273.15 from the Kelvin value. Therefore, 119 K - 273.15 = -154.15°C. The negative sign indicates that the temperature is below freezing. When rounded to the nearest whole number, -154.15°C is approximately -154°C. Choice A and Choice C are incorrect as they do not reflect the correct conversion from Kelvin to Celsius. Choice D is incorrect as it corresponds to the freezing point of water in Celsius, not the conversion of 119 K.

3. What is stoichiometry?

Correct answer: B

Rationale: Stoichiometry is the branch of chemistry that deals with the quantitative relationships between reactants and products in chemical reactions. It focuses on the calculation of the amounts of substances consumed and produced in a reaction based on the balanced chemical equation. Choice A is incorrect because the study of energy changes in chemical reactions falls under thermodynamics. Choice C is incorrect as atomic structure is related to the arrangement of atoms within molecules. Choice D is incorrect as molecular geometry deals with the spatial arrangement of atoms within molecules.

4. What is the correct electron configuration for nitrogen?

Correct answer: C

Rationale: The electron configuration of nitrogen is determined by its atomic number, which is 7. Nitrogen has 7 electrons. Following the order of filling orbitals, the electron configuration for nitrogen is 1s² 2s² 2p³. This means the first energy level is filled with 2 electrons in the 1s orbital, the second energy level is filled with 2 electrons in the 2s orbital, and 3 electrons in the 2p orbital. Each orbital can hold a specific number of electrons, and nitrogen, with its 7 electrons, fits this configuration. Choice A is incorrect because it does not account for all the electrons in the nitrogen atom. Choice B is incorrect as it only represents 6 electrons, not the 7 electrons in nitrogen. Choice D is incorrect as it represents 8 electrons, which is not the correct electron configuration for nitrogen.

5. On the periodic table, where are atoms with the largest atomic radius located?

Correct answer: C

Rationale: Atoms with the largest atomic radius are located at the bottom of their group on the periodic table. This is because atomic radius increases down a group due to the addition of more energy levels or shells of electrons. As you move down a group, the outermost electrons are further away from the nucleus, leading to an increase in atomic radius. Choice A 'At the top of their group' is incorrect because atomic radius decreases going up within a group. Choice B 'In the middle of their group' is incorrect as the atomic radius generally increases as you go down a group, not in the middle. Choice D 'Along the right-hand side' is incorrect because atomic radius tends to decrease from left to right across a period on the periodic table due to increased nuclear charge and effective nuclear charge.

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