HESI A2
HESI A2 Chemistry
1. What are the 3 types of radiation in nuclear chemistry?
- A. Alpha, Beta, Delta
- B. Alpha, Beta, Gamma
- C. Gamma, Beta, Delta
- D. Delta, Beta, Gamma
Correct answer: B
Rationale: The correct answer is B: Alpha, Beta, Gamma. In nuclear chemistry, the 3 types of radiation are alpha, beta, and gamma radiation. Alpha radiation consists of helium nuclei, beta radiation involves electrons or positrons, and gamma radiation is electromagnetic radiation of high frequency. Choice A is incorrect because 'Delta' is not a type of radiation in nuclear chemistry. Choice C is incorrect as it does not list alpha radiation. Choice D is incorrect as it lists the types in the wrong order and includes 'Delta' instead of alpha radiation.
2. How does increasing the concentration of reactants affect a chemical reaction?
- A. Decreases the reaction rate
- B. Increases the reaction rate
- C. Stops the reaction
- D. Has no effect
Correct answer: B
Rationale: Increasing the concentration of reactants leads to more reactant particles being available, which, in turn, increases the likelihood of successful collisions between particles. This higher frequency of collisions results in a higher reaction rate. Therefore, option B, 'Increases the reaction rate,' is the correct answer. Choice A, 'Decreases the reaction rate,' is incorrect because higher reactant concentration usually speeds up the reaction. Choice C, 'Stops the reaction,' is incorrect as increasing concentration promotes more collisions, enhancing the reaction. Choice D, 'Has no effect,' is incorrect because changing reactant concentration directly impacts the reaction rate in most cases.
3. Here are the solubilities of four substances at 0°C, in grams of solute per 100 mL of water. If the temperature increases to 20°C, what would you expect to happen to the solubility figures?
- A. Citric acid and potassium phosphate will decrease; nitrogen and oxygen will increase.
- B. Citric acid and potassium phosphate will increase; nitrogen and oxygen will decrease.
- C. All four figures will increase.
- D. All four figures will decrease.
Correct answer: C
Rationale: Solubility generally tends to increase with temperature for most solid solutes in liquid solvents due to higher kinetic energy leading to better solute-solvent interactions. As the temperature increases from 0°C to 20°C, all four solubility figures are expected to increase. Choice A is incorrect because solubility tends to increase with temperature. Choice B is incorrect as well for the same reason. Choice D is incorrect because the solubility of solid solutes typically increases with temperature.
4. What is the oxidation state of the nitrogen atom in the compound NH3?
- A. -3
- B. -1
- C. +1
- D. +3
Correct answer: B
Rationale: In the compound NH3, nitrogen is bonded to three hydrogen atoms. Hydrogen is always assigned an oxidation state of +1. Since the overall charge of NH3 is zero, the oxidation state of nitrogen must be -1 to balance out the hydrogen's +1 oxidation state. Therefore, the correct oxidation state of the nitrogen atom in NH3 is -1. Choice A (-3) is incorrect because it does not account for the electronegativity of hydrogen. Choice C (+1) and Choice D (+3) are incorrect as the nitrogen atom in NH3 needs to balance the +1 oxidation state of each hydrogen atom, resulting in a total of -3 to maintain the compound's charge neutrality.
5. Which of the following represents a hydride ion?
- A. H⁻
- B. H⁺
- C. OH⁻
- D. HCl
Correct answer: A
Rationale: The hydride ion is denoted by H⁻, indicating that it has gained an extra electron to complete its valence shell, resulting in a full octet and a net charge of -1. This ion is commonly found in metal hydrides and plays a significant role in various chemical reactions. Option B, H⁺, represents a proton with a positive charge. Option C, OH⁻, represents the hydroxide ion, consisting of oxygen and hydrogen. Option D, HCl, is a compound composed of hydrogen and chlorine ions, not a hydride ion.
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