a chemist takes 100 ml of a 40 ml nacl solution she then dilutes it to 1l what is the concentration molarity of the new solution

HESI A2

Chemistry Hesi A2

1. A chemist takes 100 mL of a 40 g NaCl solution and dilutes it to 1L. What is the concentration (molarity) of the new solution?

A. 0.04 M NaCl
B. 0.25 M NaCl
C. 0.40 M NaCl
D. 2.5 M NaCl

Correct answer: C

Rationale: Initially, the chemist has 40 g of NaCl in 100 mL of solution. To find the initial molarity, we need to calculate the number of moles of NaCl using the molar mass of NaCl (58.44 g/mol). After dilution to 1 L, the molarity of the new solution can be calculated by dividing the moles of NaCl by the total volume in liters. Therefore, the concentration (molarity) of the new solution is 0.40 M NaCl. Choice A (0.04 M NaCl) is incorrect because it doesn't consider the correct molar concentration after dilution. Choice B (0.25 M NaCl) is incorrect as it also doesn't account for the correct molar concentration post-dilution. Choice D (2.5 M NaCl) is incorrect as it is too concentrated given the initial amount of NaCl and the dilution factor.

2. To the nearest whole number, what is the mass of one mole of hydrogen chloride?

A. 36 g/mol
B. 38 g/mol
C. 71 g/mol
D. 74 g/mol

Correct answer: C

Rationale: The molar mass of hydrogen chloride (HCl) is calculated by adding the atomic masses of hydrogen (H) and chlorine (Cl) together. The atomic mass of hydrogen is approximately 1 g/mol, and the atomic mass of chlorine is approximately 35.5 g/mol. Therefore, the molar mass of hydrogen chloride (HCl) is approximately 1 + 35.5 = 36.5 g/mol. When rounded to the nearest whole number, it is 36 g/mol. Therefore, the correct answer is 36 g/mol. Choices A, B, and D are incorrect as they do not reflect the accurate molar mass of hydrogen chloride.

3. What is the oxidation state of the oxygen atom in the compound NaOH?

A. -2
B. -1
C. 0
D. +2

Correct answer: B

Rationale: In the compound NaOH (sodium hydroxide), the oxidation state of the sodium ion (Na) is +1 as it commonly has a +1 charge in ionic compounds. Oxygen (O) typically has an oxidation state of -2 in most compounds. Since the compound is electrically neutral and the overall charge is zero, the sum of the oxidation states of all atoms in the compound must be zero. Therefore, considering that sodium has an oxidation state of +1, the oxygen atom in NaOH must have an oxidation state of -1 to balance the charges and overall neutrality of the compound. Choice A (-2) is incorrect as this is not the oxidation state of oxygen in this compound. Choice C (0) is incorrect as oxygen in NaOH does not have an oxidation state of 0. Choice D (+2) is incorrect as oxygen typically has a negative oxidation state in compounds, not a positive one.

4. On the periodic table, where are atoms with the largest atomic radius located?

A. At the top of their group
B. In the middle of their group
C. At the bottom of their group
D. Along the right-hand side

Correct answer: C

Rationale: Atoms with the largest atomic radius are located at the bottom of their group on the periodic table. This is because atomic radius increases down a group due to the addition of more energy levels or shells of electrons. As you move down a group, the outermost electrons are further away from the nucleus, leading to an increase in atomic radius. Choice A 'At the top of their group' is incorrect because atomic radius decreases going up within a group. Choice B 'In the middle of their group' is incorrect as the atomic radius generally increases as you go down a group, not in the middle. Choice D 'Along the right-hand side' is incorrect because atomic radius tends to decrease from left to right across a period on the periodic table due to increased nuclear charge and effective nuclear charge.

5. How many neutrons are in an atom of uranium-235?

A. 92
B. 125
C. 143
D. 235

Correct answer: A

Rationale: The correct answer is A: '92'. To determine the number of neutrons in an atom, you subtract the atomic number (number of protons) from the atomic mass number. For uranium-235, the atomic number is 92, and the atomic mass number is 235. Subtracting 92 from 235 gives us 143 neutrons in an atom of uranium-235. Therefore, options B, C, and D are incorrect as they do not represent the correct number of neutrons in an atom of uranium-235.