HESI A2
Chemistry Hesi A2
1. A chemist takes 100 mL of a 40 g NaCl solution and dilutes it to 1L. What is the concentration (molarity) of the new solution?
- A. 0.04 M NaCl
- B. 0.25 M NaCl
- C. 0.40 M NaCl
- D. 2.5 M NaCl
Correct answer: C
Rationale: Initially, the chemist has 40 g of NaCl in 100 mL of solution. To find the initial molarity, we need to calculate the number of moles of NaCl using the molar mass of NaCl (58.44 g/mol). After dilution to 1 L, the molarity of the new solution can be calculated by dividing the moles of NaCl by the total volume in liters. Therefore, the concentration (molarity) of the new solution is 0.40 M NaCl. Choice A (0.04 M NaCl) is incorrect because it doesn't consider the correct molar concentration after dilution. Choice B (0.25 M NaCl) is incorrect as it also doesn't account for the correct molar concentration post-dilution. Choice D (2.5 M NaCl) is incorrect as it is too concentrated given the initial amount of NaCl and the dilution factor.
2. What determines polarity in a molecule?
- A. Bond length
- B. Bond strength
- C. Electronegativity
- D. Molecular weight
Correct answer: C
Rationale: Polarity in a molecule is determined by the difference in electronegativity between the atoms forming the bond. The greater the difference in electronegativity, the more polar the bond and molecule become. This difference leads to an uneven distribution of electron density within the bond, creating partial positive and negative charges on the atoms involved. Choices A, B, and D are incorrect. Bond length and strength do not determine polarity, and molecular weight is not directly related to the polarity of a molecule.
3. Which of the following is a property of an acid?
- A. Bitter taste
- B. Slippery feel
- C. Reacts with bases
- D. Sweet taste
Correct answer: C
Rationale: The correct property of an acid is that it 'reacts with bases.' Acids are known for their ability to react with bases to form salts and water through a process called neutralization. This unique reaction distinguishes acids from other substances and is a fundamental characteristic of acids in chemistry. Choices A, B, and D are incorrect. Acids do not have a bitter taste (Choice A), a slippery feel (Choice B), or a sweet taste (Choice D). These properties are not typical of acids and may lead to confusion if associated with acids.
4. What is the correct electron configuration for nitrogen?
- A. 1s² 2s²
- B. 1s² 2s² 2p²
- C. 1s² 2s² 2p³
- D. 1s² 2s² 2pâ´
Correct answer: C
Rationale: The electron configuration of nitrogen is determined by its atomic number, which is 7. Nitrogen has 7 electrons. Following the order of filling orbitals, the electron configuration for nitrogen is 1s² 2s² 2p³. This means the first energy level is filled with 2 electrons in the 1s orbital, the second energy level is filled with 2 electrons in the 2s orbital, and 3 electrons in the 2p orbital. Each orbital can hold a specific number of electrons, and nitrogen, with its 7 electrons, fits this configuration. Choice A is incorrect because it does not account for all the electrons in the nitrogen atom. Choice B is incorrect as it only represents 6 electrons, not the 7 electrons in nitrogen. Choice D is incorrect as it represents 8 electrons, which is not the correct electron configuration for nitrogen.
5. What is the charge of a gamma ray?
- A. -1
- B. +1
- C. +2
- D. No charge
Correct answer: D
Rationale: Gamma rays are a form of electromagnetic radiation with no charge. They are neutral particles that do not possess any electric charge. This characteristic allows them to be unaffected by electric or magnetic fields. Additionally, gamma rays travel at the speed of light in a vacuum. Choices A, B, and C are incorrect as gamma rays do not carry a charge of -1, +1, or +2; they are neutral entities.
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