a chemist takes 100 ml of a 40 ml nacl solution she then dilutes it to 1l what is the concentration molarity of the new solution

HESI A2

Chemistry Hesi A2

1. A chemist takes 100 mL of a 40 g NaCl solution and dilutes it to 1L. What is the concentration (molarity) of the new solution?

A. 0.04 M NaCl
B. 0.25 M NaCl
C. 0.40 M NaCl
D. 2.5 M NaCl

Correct answer: C

Rationale: Initially, the chemist has 40 g of NaCl in 100 mL of solution. To find the initial molarity, we need to calculate the number of moles of NaCl using the molar mass of NaCl (58.44 g/mol). After dilution to 1 L, the molarity of the new solution can be calculated by dividing the moles of NaCl by the total volume in liters. Therefore, the concentration (molarity) of the new solution is 0.40 M NaCl. Choice A (0.04 M NaCl) is incorrect because it doesn't consider the correct molar concentration after dilution. Choice B (0.25 M NaCl) is incorrect as it also doesn't account for the correct molar concentration post-dilution. Choice D (2.5 M NaCl) is incorrect as it is too concentrated given the initial amount of NaCl and the dilution factor.

2. On what concept is Kelvin based?

A. Freezing point
B. Absolute zero
C. Boiling point
D. Evaporation point

Correct answer: B

Rationale: The correct answer is B: Absolute zero. Kelvin is based on the concept of absolute zero, which is the point where molecular movement ceases entirely. This temperature scale starts at absolute zero (0K), where theoretically no molecular movement occurs. Choices A, C, and D are incorrect because Kelvin is not based on the freezing point, boiling point, or evaporation point, but rather on the absolute absence of molecular motion.

3. What term refers to the average of the masses of each of its isotopes as they occur in nature?

A. Atomic number
B. Mass number
C. Atomic mass
D. Neutron number

Correct answer: C

Rationale: The correct answer is atomic mass. Atomic mass is the weighted average of the masses of an element's isotopes. It takes into account the abundance of each isotope in nature to provide a more accurate representation of the element's overall mass. Choice A, atomic number, represents the number of protons in an atom. Choice B, mass number, refers to the total number of protons and neutrons in an atom's nucleus. Choice D, neutron number, specifically focuses on the count of neutrons in an atom's nucleus. These choices do not directly relate to the average mass of isotopes as asked in the question.

4. Which ion would you expect to dominate in water solutions of bases?

A. MgCl₂
B. 2HCl
C. H⁺
D. OH⁻

Correct answer: D

Rationale: In water solutions of bases, the dominant ion would be OH⁻ (hydroxide ion). Bases release OH⁻ ions when dissolved in water, increasing the concentration of hydroxide ions and leading to a higher pH. This is in contrast to acids, which release H⁺ ions. Therefore, in water solutions of bases, the presence of OH⁻ ions signifies the basic nature of the solution. Choices A, B, and C are incorrect because MgCl₂ is a salt, 2HCl is a compound consisting of two hydrogen ions and one chloride ion, and H⁺ represents a hydrogen ion typically associated with acids, not bases.

5. When balanced, the reaction Fe + O₂ → FeO will be?

A. 2Fe + 2O₂ → 3FeO
B. 4Fe + 6O₂ → 6FeO
C. 2Fe + 3O₂ → 2FeO
D. 4Fe + 3O₂ → 2FeO

Correct answer: C

Rationale: To balance the chemical equation Fe + O₂ → FeO, the coefficients needed are 2 for Fe and 1 for O. Therefore, the balanced equation becomes 2Fe + O₂ → 2FeO, which translates into 2Fe + 3O₂ → 2FeO. This corresponds to option C. Choice A has the incorrect number of oxygen molecules. Choice B has an incorrect number of Fe atoms on the product side. Choice D also has an incorrect number of Fe atoms on the product side.