HESI A2
Chemistry HESI A2 Quizlet
1. Which number represents the number of protons in an element?
- A. Atomic mass
- B. Mass number
- C. Atomic number
- D. Proton number
Correct answer: C
Rationale: The correct answer is C: Atomic number. The atomic number corresponds to the number of protons in an element. Protons are positively charged subatomic particles found in the nucleus of an atom. Each element has a unique atomic number, which defines its identity based on the number of protons it contains. Choice A, Atomic mass, is incorrect as it refers to the average mass of an atom of an element. Choice B, Mass number, represents the total number of protons and neutrons in an atom's nucleus. Choice D, Proton number, is not a commonly used term in chemistry to indicate the number of protons.
2. Which of the following is the weakest intermolecular force?
- A. Dipole interactions
- B. Hydrogen bonding
- C. Van der Waals forces
- D. Dispersion forces
Correct answer: D
Rationale: Dispersion forces, also known as London dispersion forces, are the weakest intermolecular forces. They are temporary attractive forces that occur due to momentary shifts in electron distribution within molecules. While dipole interactions, hydrogen bonding, and Van der Waals forces are stronger intermolecular forces, dispersion forces are the weakest because they arise from short-lived fluctuations in electron density. Dipole interactions involve permanent dipoles in molecules, making them stronger than dispersion forces. Hydrogen bonding is stronger than dipole interactions and involves hydrogen atoms bonded to highly electronegative atoms. Van der Waals forces encompass dipole-dipole interactions and dispersion forces, making them stronger than dispersion forces alone.
3. What is the correct electron configuration for carbon?
- A. 1s²2s²2p¹
- B. 1s²2s²2p²
- C. 1s²2s²2p³
- D. 1s²2s²2p⁶3s¹
Correct answer: B
Rationale: The correct electron configuration for carbon is 1s²2s²2p². This configuration indicates that there are 2 electrons in the first energy level (1s²), 2 electrons in the second energy level (2s²), and 2 electrons in the second energy level (2p²). It adheres to the aufbau principle, which states that electrons fill orbitals starting from the lowest energy level, and the Pauli exclusion principle, which states that each electron in an atom must have a unique set of quantum numbers. Choice A is incorrect because it does not fill the 2p orbital correctly. Choice C is incorrect as it exceeds the number of possible electrons in the 2p orbital. Choice D is incorrect as it includes an electron in the 3s orbital, which is not part of the electron configuration for carbon.
4. If fifty-six kilograms of a radioactive substance has a half-life of 12 days, how many days will it take the substance to decay naturally to only 7 kilograms?
- A. 8
- B. 12
- C. 36
- D. 48
Correct answer: C
Rationale: To decay from 56 kg to 7 kg, the substance needs to go through 3 half-lives (56 kg ÷ 2 ÷ 2 ÷ 2 = 7 kg). Since each half-life is 12 days, the total time required is 12 days per half-life x 3 half-lives = 36 days. Choice A is incorrect because it does not consider the concept of half-lives. Choice B is incorrect because it represents the duration of a single half-life, not the total time required for the decay. Choice D is incorrect as it does not account for the multiple half-lives needed for the substance to decay from 56 kg to 7 kg.
5. What type of reaction involves atoms attempting to achieve stable electron configurations?
- A. Chemical
- B. Nuclear
- C. Physical
- D. Mechanical
Correct answer: A
Rationale: In a chemical reaction, atoms interact to achieve stable electron configurations through the formation of new chemical bonds or the breaking of existing ones. This process aims to reach a more stable state by filling or emptying electron orbitals, leading to the formation of new substances with more stable configurations. Choice B, nuclear reactions, involve changes in the atomic nucleus rather than electron configurations. Choice C, physical reactions, involve changes in physical state or appearance without changing the chemical makeup. Choice D, mechanical reactions, do not involve the rearrangement of electrons to achieve stable configurations.
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