HESI A2
Chemistry Hesi A2
1. What is the correct electron configuration for carbon?
- A. 1s²2s²2p¹
- B. 1s²2s²2p²
- C. 1s²2s²2p³
- D. 1s²2s²2p⁶3s¹
Correct answer: B
Rationale: The correct electron configuration for carbon is 1s²2s²2p². This configuration indicates that there are 2 electrons in the first energy level (1s²), 2 electrons in the second energy level (2s²), and 2 electrons in the second energy level (2p²). It adheres to the aufbau principle, which states that electrons fill orbitals starting from the lowest energy level, and the Pauli exclusion principle, which states that each electron in an atom must have a unique set of quantum numbers. Choice A is incorrect because it does not fill the 2p orbital correctly. Choice C is incorrect as it exceeds the number of possible electrons in the 2p orbital. Choice D is incorrect as it includes an electron in the 3s orbital, which is not part of the electron configuration for carbon.
2. On what concept is Kelvin based?
- A. Freezing point
- B. Absolute zero
- C. Boiling point
- D. Evaporation point
Correct answer: B
Rationale: The correct answer is B: Absolute zero. Kelvin is based on the concept of absolute zero, which is the point where molecular movement ceases entirely. This temperature scale starts at absolute zero (0K), where theoretically no molecular movement occurs. Choices A, C, and D are incorrect because Kelvin is not based on the freezing point, boiling point, or evaporation point, but rather on the absolute absence of molecular motion.
3. A radioactive isotope has a half-life of 20 years. How many grams of a 6-gram sample will remain after 40 years?
- A. 8
- B. 6
- C. 3
- D. 1.5
Correct answer: C
Rationale: The half-life of a radioactive isotope is the time it takes for half of the original sample to decay. After each half-life period, half of the initial sample remains. In this case, after the first 20 years, half of the 6-gram sample (3 grams) will remain. After another 20 years (total of 40 years), half of the remaining 3 grams will remain, which is 1.5 grams. Therefore, 3 grams will be left after 40 years. Choice A is incorrect as it doesn't consider the concept of half-life and incorrectly suggests an increase in the sample. Choice B is incorrect as it assumes no decay over time. Choice D is incorrect as it miscalculates the remaining amount after two half-life periods.
4. What charge do Group VA elements typically have?
- A. -1
- B. -2
- C. -3
- D. 0
Correct answer: C
Rationale: Group VA elements, also known as Group 15 elements, typically have a charge of -3. This is because they have five valence electrons and tend to gain three electrons to achieve a stable octet configuration, resulting in a -3 charge. Choice A (-1) and Choice B (-2) are incorrect because Group VA elements need to gain three electrons to reach a stable electron configuration, not just one or two. Choice D (0) is also incorrect because Group VA elements do not lose electrons to form a charge of 0.
5. How many electron pairs are shared to form a triple covalent bond?
- A. 1
- B. 2
- C. 3
- D. 4
Correct answer: C
Rationale: The correct answer is C. In a triple covalent bond, three pairs of electrons are shared between two atoms. This sharing results in a total of six electrons being shared, making the bond strong. Choice A (1) is incorrect because a single covalent bond involves the sharing of one pair of electrons. Choice B (2) is incorrect as a double covalent bond consists of the sharing of two pairs of electrons. Choice D (4) is incorrect because there are only three pairs of electrons shared in a triple covalent bond, not four.
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