HESI A2
Chemistry HESI A2 Quizlet
1. Which of the following is the weakest intermolecular force?
- A. Dipole interactions
- B. Hydrogen bonding
- C. Van der Waals forces
- D. Dispersion forces
Correct answer: D
Rationale: Dispersion forces, also known as London dispersion forces, are the weakest intermolecular forces. They are temporary attractive forces that occur due to momentary shifts in electron distribution within molecules. While dipole interactions, hydrogen bonding, and Van der Waals forces are stronger intermolecular forces, dispersion forces are the weakest because they arise from short-lived fluctuations in electron density. Dipole interactions involve permanent dipoles in molecules, making them stronger than dispersion forces. Hydrogen bonding is stronger than dipole interactions and involves hydrogen atoms bonded to highly electronegative atoms. Van der Waals forces encompass dipole-dipole interactions and dispersion forces, making them stronger than dispersion forces alone.
2. What is the name of the compound CH₃-CH₂-CH₂-CH₃?
- A. Cyclobutane
- B. Butane
- C. Butene
- D. Butyne
Correct answer: B
Rationale: The compound CH₃-CH₂-CH₂-CH₃ is named butane. Butane is a straight-chain alkane comprising four carbon atoms connected by single bonds. The prefix 'but-' denotes the presence of four carbon atoms, while the suffix '-ane' indicates it is an alkane with single bonds between the carbon atoms. Choice A, Cyclobutane, is incorrect as it refers to a cyclic hydrocarbon with four carbon atoms in a ring structure. Choice C, Butene, is incorrect because it is an alkene with a double bond between two carbon atoms, not a saturated hydrocarbon like butane. Choice D, Butyne, is also incorrect as it is an alkyne with a triple bond between two carbon atoms, unlike the single bonds in butane.
3. How can water be boiled at room temperature?
- A. By lowering the pressure
- B. By increasing the pressure
- C. By decreasing the volume
- D. By raising the boiling point
Correct answer: A
Rationale: The boiling point of water is directly affected by pressure. By lowering the pressure, water can boil at a lower temperature, even at room temperature. This occurs because at lower pressures, the molecules of water have less resistance to escaping into the vapor phase, thus enabling boiling to occur at lower temperatures. Choices B, C, and D are incorrect because increasing the pressure, decreasing the volume, or raising the boiling point would actually require higher temperatures to boil water rather than achieving boiling at room temperature.
4. Which branch of chemistry deals with the quantities and numeric relationships between compounds in a chemical reaction?
- A. Stoichiometry
- B. Molecular chemistry
- C. Atomic chemistry
- D. Thermodynamics
Correct answer: A
Rationale: Stoichiometry is the branch of chemistry that deals with the quantitative relationships between reactants and products in chemical reactions. It involves the calculation of quantities of substances consumed and produced in a chemical reaction based on the balanced chemical equation. Choice B, 'Molecular chemistry,' is incorrect as it focuses on the structure, properties, and reactions of molecules. Choice C, 'Atomic chemistry,' is incorrect as it primarily deals with the study of atoms and their interactions. Choice D, 'Thermodynamics,' is incorrect as it pertains to the study of energy and heat transfer in chemical and physical processes.
5. What is the correct electron configuration for magnesium?
- A. 1s² 2s²
- B. 1s² 2s² 2pâ¶
- C. 1s² 2s² 2pⶠ3s²
- D. 1s² 2s² 2pⶠ3s² 3p¹
Correct answer: C
Rationale: The electron configuration of an element is determined by following the Aufbau principle, which states that electrons fill orbitals starting from the lowest energy level. Magnesium has an atomic number of 12, meaning it has 12 electrons. The electron configuration of magnesium fills the 1s, 2s, 2p, and 3s orbitals to accommodate all 12 electrons. Therefore, the correct electron configuration for magnesium is 1s² 2s² 2pⶠ3s². Choice A is incorrect as it only includes 4 electrons and stops at the 2s orbital. Choice B is incorrect as it includes 8 electrons and stops at the 2p orbital. Choice D is incorrect as it includes 13 electrons and extends to the 3p orbital, which is beyond the actual electron configuration of magnesium.
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