HESI A2
HESI A2 Chemistry Practice Test
1. If oxygen is in a compound, what would its oxidation number be?
- A. 2
- B. -2
- C. 0
- D. -1
Correct answer: B
Rationale: Oxygen typically has an oxidation number of -2 in compounds because it tends to gain electrons. This is due to its high electronegativity, which leads to oxygen attracting electrons towards itself in a chemical bond. Choice A (2) is incorrect because oxygen doesn't have a +2 oxidation number in compounds. Choice C (0) is incorrect as oxygen rarely has an oxidation number of 0 in compounds. Choice D (-1) is incorrect as oxygen's oxidation number in compounds is typically -2, not -1.
2. What does the mass of one mole of a substance represent?
- A. Atomic mass
- B. Mass number
- C. Molecular weight
- D. Molar mass
Correct answer: D
Rationale: The mass of one mole of a substance is represented by its molar mass. Molar mass is the mass of one mole of a substance and is expressed in grams per mole. It is calculated by summing the atomic masses of all atoms in a molecule. Therefore, the correct answer is D - 'Molar mass'. Choice A, 'Atomic mass', refers to the average mass of an atom of an element. Choice B, 'Mass number', is the total number of protons and neutrons in an atom's nucleus. Choice C, 'Molecular weight', is the average mass of a molecule relative to 1/12 of the mass of an atom of carbon-12.
3. Which of the following elements is a halogen?
- A. Oxygen
- B. Fluorine
- C. Sodium
- D. Carbon
Correct answer: B
Rationale: The correct answer is 'Fluorine' (Choice B) as it is a halogen. Halogens are a group of elements that include fluorine, chlorine, bromine, iodine, and astatine. They are highly reactive nonmetals located in Group 17 of the periodic table. Oxygen (Choice A) is a nonmetal but not a halogen. Sodium (Choice C) is a metal, and Carbon (Choice D) is a nonmetal, neither of which belong to the halogen group.
4. Which elements are typically involved in hydrogen bonding?
- A. Carbon, hydrogen, oxygen
- B. Fluorine, chlorine, oxygen
- C. Fluorine, chlorine, nitrogen
- D. Fluorine, oxygen, nitrogen
Correct answer: D
Rationale: Hydrogen bonding occurs between hydrogen and highly electronegative atoms such as fluorine, oxygen, and nitrogen. These atoms have a strong pull on the shared electrons, leading to a partial negative charge on them, which allows them to form hydrogen bonds with hydrogen or other electronegative atoms. Choice A is incorrect because carbon is not typically involved in hydrogen bonding. Choice B is incorrect because chlorine is not as electronegative as nitrogen, and choice C is incorrect because nitrogen is more electronegative than chlorine.
5. Here are the solubilities of four substances at 0°C, in grams of solute per 100 mL of water. If the temperature increases to 20°C, what would you expect to happen to the solubility figures?
- A. Citric acid and potassium phosphate will decrease; nitrogen and oxygen will increase.
- B. Citric acid and potassium phosphate will increase; nitrogen and oxygen will decrease.
- C. All four figures will increase.
- D. All four figures will decrease.
Correct answer: C
Rationale: Solubility generally tends to increase with temperature for most solid solutes in liquid solvents due to higher kinetic energy leading to better solute-solvent interactions. As the temperature increases from 0°C to 20°C, all four solubility figures are expected to increase. Choice A is incorrect because solubility tends to increase with temperature. Choice B is incorrect as well for the same reason. Choice D is incorrect because the solubility of solid solutes typically increases with temperature.
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