HESI A2
HESI A2 Chemistry Practice Questions
1. Why does the diffusion rate increase as a substance is heated?
- A. The kinetic energy of particles increases.
- B. The space between particles increases.
- C. The density of particles decreases.
- D. The size of particles increases.
Correct answer: A
Rationale: The correct answer is A. When a substance is heated, the kinetic energy of particles increases, causing them to move faster. This increased movement allows the particles to spread out more rapidly, leading to a higher diffusion rate. Choice B is incorrect because heating does not directly affect the space between particles. Choice C is incorrect because heating does not necessarily lead to a decrease in the density of particles. Choice D is incorrect because the size of particles does not necessarily increase when a substance is heated. Therefore, the correct explanation for the increase in diffusion rate is the rise in kinetic energy of particles.
2. Which of these intermolecular forces might represent attraction between atoms of a noble gas?
- A. Dipole-dipole interaction
- B. London dispersion force
- C. Keesom interaction
- D. Hydrogen bonding
Correct answer: B
Rationale: Noble gases are non-polar molecules without a permanent dipole moment. The only intermolecular force applicable to noble gases is the London dispersion force, also known as Van der Waals forces. This force is a temporary attractive force resulting from the formation of temporary dipoles in non-polar molecules. Dipole-dipole interactions, Keesom interactions, and hydrogen bonding involve significant dipoles or hydrogen atoms bonded to electronegative atoms, which do not apply to noble gases.
3. On the periodic table, where are atoms with the largest atomic radius located?
- A. At the top of their group
- B. In the middle of their group
- C. At the bottom of their group
- D. Along the right-hand side
Correct answer: C
Rationale: Atoms with the largest atomic radius are located at the bottom of their group on the periodic table. This is because atomic radius increases down a group due to the addition of more energy levels or shells of electrons. As you move down a group, the outermost electrons are further away from the nucleus, leading to an increase in atomic radius. Choice A 'At the top of their group' is incorrect because atomic radius decreases going up within a group. Choice B 'In the middle of their group' is incorrect as the atomic radius generally increases as you go down a group, not in the middle. Choice D 'Along the right-hand side' is incorrect because atomic radius tends to decrease from left to right across a period on the periodic table due to increased nuclear charge and effective nuclear charge.
4. Which of the following factors would not affect rates of reaction?
- A. Temperature
- B. Surface area
- C. Pressure
- D. Time
Correct answer: D
Rationale: Time would not directly affect rates of reaction. The rate of a chemical reaction is determined by factors that affect the frequency of successful collisions between reactant molecules, leading to a reaction. Temperature, surface area, and pressure can influence reaction rates by impacting the kinetic energy of molecules, the exposed surface for collisions, and the concentration of reactants, respectively. However, time, in the context of this question, does not alter the rate of reaction but may affect the extent of the reaction or the amount of product formed over time.
5. Which is a triatomic allotrope of oxygen?
- A. Ozone
- B. Water
- C. Acidic oxide
- D. Carbon dioxide
Correct answer: A
Rationale: Ozone (O3) is a triatomic allotrope of oxygen. It differs from the common diatomic oxygen molecule (O2) by having three oxygen atoms bonded together. Ozone is known for its protective role in the Earth's atmosphere, absorbing most of the Sun's harmful ultraviolet radiation. Water (H2O) is a compound composed of two hydrogen atoms and one oxygen atom. Acidic oxide and carbon dioxide are not triatomic allotropes of oxygen. Carbon dioxide consists of one carbon atom and two oxygen atoms, while acidic oxides refer to compounds where oxygen is bonded with other elements to form oxides, and they are not allotropes of oxygen.
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