HESI A2
HESI A2 Chemistry Questions
1. Which state of matter has a definite volume but takes the shape of its container?
- A. Gas
- B. Liquid
- C. Solid
- D. Plasma
Correct answer: B
Rationale: The state of matter that has a definite volume but takes the shape of its container is a 'Liquid.' Liquids have a fixed volume but can change their shape to fit the container they are in. This property distinguishes liquids from solids, which have both a definite shape and volume, and gases, which do not have a fixed volume or shape. Therefore, the correct answer is 'Liquid.' Choice A, 'Gas,' is incorrect because gases do not have a definite volume or shape. Choice C, 'Solid,' is incorrect as solids have a definite shape and volume. Choice D, 'Plasma,' is incorrect because plasma is a state of matter where atoms have been ionized and do not have a fixed volume or shape.
2. The molar mass of glucose is 180 g/mol. If an IV solution contains 5 g of glucose in 100 g of water, what is the molarity of the solution?
- A. 0.28M
- B. 1.8M
- C. 2.8M
- D. 18M
Correct answer: C
Rationale: To calculate the molarity of the solution, we first need to determine the moles of solute (glucose) and solvent (water) separately. The molar mass of glucose is 180 g/mol. First, calculate the moles of glucose: 5 g / 180 g/mol = 0.02778 mol of glucose. Next, calculate the moles of water: 100 g / 18 g/mol = 5.56 mol of water. Now, calculate the total moles in the solution: 0.02778 mol glucose + 5.56 mol water = 5.5878 mol. Finally, calculate the molarity: Molarity = moles of solute / liters of solution. Since the total mass of the solution is 100 g + 5 g = 105 g = 0.105 kg, which is equal to 0.105 L, the molarity is 5.5878 mol / 0.105 L = 53.22 M, which rounds to 2.8M. Therefore, the correct answer is 2.8M. Choices A, B, and D are incorrect because they do not reflect the accurate molarity calculation based on the moles of solute and volume of the solution.
3. Which of the following is not an allotrope of carbon?
- A. Diamond
- B. Graphite
- C. Fluorine
- D. Buckminsterfullerene
Correct answer: C
Rationale: The correct answer is C: Fluorine. Allotropes of carbon are different forms of the same element. Diamonds, graphite, and buckminsterfullerene are all allotropes of carbon. However, fluorine is a separate chemical element and not an allotrope of carbon. Therefore, fluorine does not belong to the group of carbon allotropes.
4. Which of the following elements is the most electronegative?
- A. Oxygen
- B. Fluorine
- C. Nitrogen
- D. Sodium
Correct answer: B
Rationale: Fluorine is the most electronegative element on the periodic table. It has the highest electronegativity value, indicating its strong ability to attract electrons in a chemical bond. This property makes it highly reactive, explaining why it is the correct answer in this question. Oxygen and Nitrogen are also electronegative elements, but they are not as electronegative as Fluorine. Sodium, on the other hand, is not electronegative; it is an electropositive element.
5. What creates a dipole in a covalent bond?
- A. Unequal sharing of electrons
- B. Equal sharing of electrons
- C. Exchange of electrons
- D. Transfer of electrons
Correct answer: A
Rationale: A dipole is created in a covalent bond when there is an unequal sharing of electrons between the atoms involved. This results in a partial positive charge on one atom and a partial negative charge on the other, leading to a separation of charges and the formation of a dipole. Choices B, C, and D are incorrect because a dipole is specifically formed due to unequal sharing of electrons, not equal sharing, exchange, or transfer of electrons in a covalent bond.
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