HESI A2
HESI A2 Chemistry Questions
1. What type of bond is present in sodium chloride?
- A. Covalent
- B. Ionic
- C. Metallic
- D. Hydrogen
Correct answer: B
Rationale: Ionic bonds are found in sodium chloride. In an ionic bond, one atom donates an electron to another atom, resulting in the formation of positively and negatively charged ions that are held together by electrostatic forces of attraction. Sodium chloride is a classic example of an ionic compound, where sodium (Na) donates an electron to chlorine (Cl), forming Na+ and Cl- ions that are attracted to each other, creating a crystal lattice structure. Covalent bonds involve the sharing of electron pairs between atoms, which is not the case in sodium chloride. Metallic bonds occur in metals where electrons are delocalized and shared across a lattice, unlike the specific transfer seen in ionic bonds. Hydrogen bonds are a type of intermolecular force, not the primary bond type present in sodium chloride.
2. Which chemical reaction involves the formation of a single product from two or more reactants?
- A. Synthesis reaction
- B. Combustion reaction
- C. Decomposition reaction
- D. Double displacement reaction
Correct answer: A
Rationale: A synthesis reaction involves the combination of two or more reactants to form a single product. This type of reaction is characterized by the merging of substances to create a more complex compound. In a synthesis reaction, the reactants bond together to form a new product, making it the correct choice for this scenario. Combustion reactions involve the rapid combination of oxygen with another substance, resulting in the release of energy in the form of heat and light. Decomposition reactions entail the breakdown of a compound into simpler substances, often through the application of heat or electricity. Double displacement reactions involve the exchange of ions between two compounds, leading to the formation of two new compounds.
3. Which of these intermolecular forces would result in the lowest boiling point?
- A. Dipole-dipole interaction
- B. London dispersion force
- C. Keesom interaction
- D. Hydrogen bonding
Correct answer: B
Rationale: The London dispersion force is the weakest intermolecular force among the options provided. These forces are present in all molecules and are caused by temporary fluctuations in electron density, resulting in temporary dipoles. Since London dispersion forces are generally weaker than dipole-dipole interactions, Keesom interactions, and hydrogen bonding, a substance with London dispersion forces as the primary intermolecular force would have the lowest boiling point due to the weaker intermolecular forces holding the molecules together. Dipole-dipole interactions, Keesom interactions, and hydrogen bonding are stronger intermolecular forces compared to London dispersion forces, resulting in higher boiling points for substances that exhibit these interactions.
4. To the nearest whole number, what is the mass of one mole of sodium chloride?
- A. 36 g/mol
- B. 43 g/mol
- C. 58 g/mol
- D. 72 g/mol
Correct answer: C
Rationale: The molar mass of sodium chloride (NaCl) is calculated by adding the atomic masses of sodium (Na) and chlorine (Cl). The atomic mass of sodium is approximately 23 g/mol and chlorine is approximately 35.5 g/mol. Adding these two atomic masses gives us a molar mass of approximately 58 g/mol for sodium chloride (NaCl). Therefore, the correct answer is C, 58 g/mol. Choice A (36 g/mol) is incorrect as it does not account for the individual atomic masses of sodium and chlorine. Choice B (43 g/mol) and choice D (72 g/mol) are also incorrect as they do not reflect the accurate molar mass of sodium chloride.
5. What is the correct electron configuration for lithium?
- A. 1s²2s¹
- B. 1s²2s²
- C. 1s²2s¹2p¹
- D. 1s¹2s¹2p²
Correct answer: A
Rationale: The electron configuration for lithium is 1s²2s¹. Lithium has 3 electrons, and the configuration indicates that the first two electrons fill the 1s orbital, while the third electron fills the 2s orbital. Therefore, the correct electron configuration for lithium is 1s²2s¹. Choice B (1s²2s²) is incorrect as it represents the electron configuration for beryllium, not lithium. Choice C (1s²2s¹2p¹) includes the 2p orbital, which is not involved in lithium's electron configuration. Choice D (1s¹2s¹2p²) is incorrect as it does not accurately represent lithium's electron configuration.
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