which of these intermolecular forces would have the lowest boiling point

HESI A2

HESI A2 Chemistry

1. Which of these intermolecular forces would result in the lowest boiling point?

A. Dipole-dipole interaction
B. London dispersion force
C. Keesom interaction
D. Hydrogen bonding

Correct answer: B

Rationale: The London dispersion force is the weakest intermolecular force among the options provided. These forces are present in all molecules and are caused by temporary fluctuations in electron density, resulting in temporary dipoles. Since London dispersion forces are generally weaker than dipole-dipole interactions, Keesom interactions, and hydrogen bonding, a substance with London dispersion forces as the primary intermolecular force would have the lowest boiling point due to the weaker intermolecular forces holding the molecules together. Dipole-dipole interactions, Keesom interactions, and hydrogen bonding are stronger intermolecular forces compared to London dispersion forces, resulting in higher boiling points for substances that exhibit these interactions.

2. Which element would you expect to be least reactive?

A. Li
B. Cr
C. Nd
D. Xe

Correct answer: D

Rationale: Xenon (Xe) is a noble gas located in Group 18 of the periodic table. Noble gases are known for their stable and unreactive nature due to having a full outer shell of electrons. Therefore, xenon would be expected to be the least reactive among the given elements. Choice A (Li) is a metal in Group 1 of the periodic table, which tends to be reactive, especially with water. Choice B (Cr) is a transition metal known for its reactivity in some forms. Choice C (Nd) is a rare earth element, which can exhibit varying reactivity depending on the compound or environment.

3. What charge do Group VIA elements typically have?

A. -1
B. -2
C. -3
D. 0

Correct answer: B

Rationale: Group VIA elements, also known as Group 16 elements, typically have a charge of -2. This is because they have 6 valence electrons and tend to gain 2 electrons to achieve a stable octet configuration, resulting in a -2 charge. Choice A (-1) is incorrect as Group VIA elements need to gain 2 electrons for stability, not just 1. Choice C (-3) is incorrect because Group VIA elements do not need to gain 3 electrons to achieve stability. Choice D (0) is incorrect as Group VIA elements need to gain electrons to reach a stable configuration, resulting in a negative charge.

4. Which of the following elements does not exist as a diatomic molecule?

A. boron
B. fluorine
C. oxygen
D. nitrogen

Correct answer: A

Rationale: The correct answer is 'boron.' Diatomic molecules consist of two atoms of the same element bonded together. Boron is an exception and does not exist naturally as a diatomic molecule. On the other hand, fluorine, oxygen, and nitrogen commonly exist as diatomic molecules in their natural states. Fluorine, for example, exists as F2, oxygen exists as O2, and nitrogen exists as N2.

5. Which of the following is a property of an acid?

A. Bitter taste
B. Slippery feel
C. Reacts with bases
D. Sweet taste

Correct answer: C

Rationale: The correct property of an acid is that it 'reacts with bases.' Acids are known for their ability to react with bases to form salts and water through a process called neutralization. This unique reaction distinguishes acids from other substances and is a fundamental characteristic of acids in chemistry. Choices A, B, and D are incorrect. Acids do not have a bitter taste (Choice A), a slippery feel (Choice B), or a sweet taste (Choice D). These properties are not typical of acids and may lead to confusion if associated with acids.