Nursing Elites

1. Which of these intermolecular forces would result in the lowest boiling point?

• A. Dipole-dipole interaction
• B. London dispersion force
• C. Keesom interaction
• D. Hydrogen bonding

Correct answer: B

Rationale: The London dispersion force is the weakest intermolecular force among the options provided. These forces are present in all molecules and are caused by temporary fluctuations in electron density, resulting in temporary dipoles. Since London dispersion forces are generally weaker than dipole-dipole interactions, Keesom interactions, and hydrogen bonding, a substance with London dispersion forces as the primary intermolecular force would have the lowest boiling point due to the weaker intermolecular forces holding the molecules together. Dipole-dipole interactions, Keesom interactions, and hydrogen bonding are stronger intermolecular forces compared to London dispersion forces, resulting in higher boiling points for substances that exhibit these interactions.

2. If gas A has four times the molar mass of gas B, you would expect it to diffuse through a plug ___________.

• A. at half the rate of gas B
• B. at twice the rate of gas B
• C. at a quarter the rate of gas B
• D. at four times the rate of gas B

Correct answer: A

Rationale: When comparing the diffusion rates of two gases, according to Graham's law of diffusion, the rate of diffusion is inversely proportional to the square root of the molar mass. If gas A has four times the molar mass of gas B, the square root of the molar masses ratio (4:1) is 2. This means that gas A would diffuse through a plug at half the rate of gas B. Therefore, the correct answer is A, at half the rate of gas B. Choices B, C, and D are incorrect because they do not reflect the correct relationship between the molar masses and the rates of diffusion according to Graham's law.

3. How can the reaction rate of a chemical reaction be increased?

• A. Increase the temperature
• B. Increase the surface area
• C. Increase the concentration of reactants
• D. Add a catalyst

Correct answer: A

Rationale: To increase the reaction rate of a chemical reaction, one effective method is to increase the temperature. Raising the temperature provides more energy to the reacting particles, enabling them to collide more frequently and with higher energy, leading to an increase in the reaction rate. While increasing the surface area, concentration of reactants, and adding a catalyst are strategies that can also enhance the reaction rate, raising the temperature has the most direct and immediate impact. Increasing the surface area allows for more contact between reactants, increasing the concentration provides more reactant particles to collide, and adding a catalyst lowers the activation energy required for the reaction to occur. However, these methods may not have as immediate and significant an effect as increasing the temperature.

4. What is the oxidation state of the nitrogen atom in the compound NH3?

• A. -3
• B. -1
• C. +1
• D. +3

Correct answer: B

Rationale: In the compound NH3, nitrogen is bonded to three hydrogen atoms. Hydrogen is always assigned an oxidation state of +1. Since the overall charge of NH3 is zero, the oxidation state of nitrogen must be -1 to balance out the hydrogen's +1 oxidation state. Therefore, the correct oxidation state of the nitrogen atom in NH3 is -1. Choice A (-3) is incorrect because it does not account for the electronegativity of hydrogen. Choice C (+1) and Choice D (+3) are incorrect as the nitrogen atom in NH3 needs to balance the +1 oxidation state of each hydrogen atom, resulting in a total of -3 to maintain the compound's charge neutrality.

5. Which two functional groups would you expect an amino acid to contain?

• A. R-NH2 and R-COOH
• B. R-CHO and R-CO-NH
• C. R-OH and R-COOR
• D. R-O-R and R-COOH

Correct answer: A

Rationale: Amino acids are organic compounds that are characterized by the presence of an amino group (NH2) and a carboxylic acid group (COOH) in their chemical structure. These two functional groups, found in option A, are fundamental components of amino acids and play crucial roles in their classification and biological functions. Option B contains an aldehyde group (CHO) and an amide group (CO-NH), which are not characteristic functional groups of amino acids. Option C includes a hydroxyl group (OH) and an ester group (COOR), which are not typically present in amino acids. Option D presents ether (R-O-R) and carboxylic acid (COOH) functional groups, which do not represent the functional groups commonly found in amino acids.

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