which of these intermolecular forces would have the lowest boiling point

HESI A2

HESI A2 Chemistry

1. Which of these intermolecular forces would result in the lowest boiling point?

A. Dipole-dipole interaction
B. London dispersion force
C. Keesom interaction
D. Hydrogen bonding

Correct answer: B

Rationale: The London dispersion force is the weakest intermolecular force among the options provided. These forces are present in all molecules and are caused by temporary fluctuations in electron density, resulting in temporary dipoles. Since London dispersion forces are generally weaker than dipole-dipole interactions, Keesom interactions, and hydrogen bonding, a substance with London dispersion forces as the primary intermolecular force would have the lowest boiling point due to the weaker intermolecular forces holding the molecules together. Dipole-dipole interactions, Keesom interactions, and hydrogen bonding are stronger intermolecular forces compared to London dispersion forces, resulting in higher boiling points for substances that exhibit these interactions.

2. What charge do Group VIA elements typically have?

A. -1
B. -2
C. -3
D. 0

Correct answer: B

Rationale: Group VIA elements, also known as Group 16 elements, typically have a charge of -2. This is because they have 6 valence electrons and tend to gain 2 electrons to achieve a stable octet configuration, resulting in a -2 charge. Choice A (-1) is incorrect as Group VIA elements need to gain 2 electrons for stability, not just 1. Choice C (-3) is incorrect because Group VIA elements do not need to gain 3 electrons to achieve stability. Choice D (0) is incorrect as Group VIA elements need to gain electrons to reach a stable configuration, resulting in a negative charge.

3. How much concentrated HCl should be used to prepare 500 mL of a 0.100 M HCl solution?

A. 75 mL
B. 100 mL
C. 125 mL
D. 150 mL

Correct answer: B

Rationale: To prepare a 0.100 M HCl solution with a volume of 500 mL, you can use the formula C1V1 = C2V2, where C1 is the concentration of the concentrated HCl solution, V1 is the volume of concentrated HCl solution used, C2 is the desired concentration (0.100 M), and V2 is the final volume (500 mL). Rearranging the formula to solve for V1, you get V1 = (C2V2) / C1. Plugging in the values (0.100 M)(500 mL) / C1 = 100 mL, which means 100 mL of concentrated HCl should be used to prepare 500 mL of a 0.100 M HCl solution. Therefore, the correct answer is 100 mL. Choice A (75 mL), Choice C (125 mL), and Choice D (150 mL) are incorrect as they do not match the calculated volume needed to prepare the desired concentration of HCl solution.

4. What is the primary function of enzymes?

A. To provide energy for reactions
B. To speed up reactions
C. To decrease activation energy
D. To act as a catalyst

Correct answer: B

Rationale: Enzymes function to speed up reactions by lowering the activation energy required for the reaction to occur. They act as biological catalysts, providing an alternative pathway for the reaction to proceed more rapidly without being consumed in the process. Choices A, C, and D are incorrect because enzymes do not provide energy for reactions (they do not generate energy), their primary function is not to decrease activation energy (though they do lower it), and while they act as catalysts, the primary function is to speed up reactions by lowering activation energy.

5. What is a mole?

A. 6.02 x 10^23
B. 1.00 x 10^24
C. 6.02 x 10^22
D. 6.02 x 10^25

Correct answer: A

Rationale: A mole is a unit used in chemistry to represent Avogadro's number, which is approximately 6.02 x 10^23. This number corresponds to the number of particles (atoms, molecules, ions) in one mole of a substance. Choice A, 6.02 x 10^23, is the correct answer as it accurately defines a mole. Choices B, C, and D provide values that are not equivalent to Avogadro's number, making them incorrect answers.