HESI A2
HESI A2 Chemistry
1. Which of these intermolecular forces would result in the lowest boiling point?
- A. Dipole-dipole interaction
- B. London dispersion force
- C. Keesom interaction
- D. Hydrogen bonding
Correct answer: B
Rationale: The London dispersion force is the weakest intermolecular force among the options provided. These forces are present in all molecules and are caused by temporary fluctuations in electron density, resulting in temporary dipoles. Since London dispersion forces are generally weaker than dipole-dipole interactions, Keesom interactions, and hydrogen bonding, a substance with London dispersion forces as the primary intermolecular force would have the lowest boiling point due to the weaker intermolecular forces holding the molecules together. Dipole-dipole interactions, Keesom interactions, and hydrogen bonding are stronger intermolecular forces compared to London dispersion forces, resulting in higher boiling points for substances that exhibit these interactions.
2. Which compound is a Hydrogen or proton donor, corrosive to metals, causes blue litmus paper to become red, and becomes less acidic when mixed with a base?
- A. Base
- B. Acid
- C. Salt
- D. Hydroxide
Correct answer: B
Rationale: The correct answer is 'Acid.' An acid is a compound that donates protons (H+), is corrosive to metals, and turns blue litmus paper red. When an acid is mixed with a base, they react to form salts and water, resulting in a decrease in acidity. Choices A, C, and D are incorrect because bases accept protons rather than donate them, salts are the products of acid-base reactions, and hydroxides are typically bases, not acids.
3. When an acid is added to a base, water and a salt form. What kinds of bonds form in these two compounds?
- A. Liquid and metallic
- B. Polar and nonpolar covalent
- C. Polar covalent and ionic
- D. Ionic only
Correct answer: C
Rationale: In water, the bond formed between the oxygen atom and the hydrogen atoms is a polar covalent bond. The oxygen atom attracts the shared electrons more strongly, creating a partial negative charge on the oxygen and a partial positive charge on the hydrogen atoms. In the salt formed, the bond between the metal cation and the nonmetal anion is predominantly an ionic bond. The metal cation donates electrons to the nonmetal anion, resulting in the formation of oppositely charged ions that are held together by electrostatic attractions. Choices A and B are incorrect because water and salts do not form bonds that are liquid and metallic, or polar and nonpolar covalent. Choice D is incorrect as it oversimplifies the types of bonds present in water and salts, failing to differentiate between the covalent bond in water and the ionic bond in the salt.
4. What type of starch is glycogen?
- A. Plant starch
- B. Animal starch
- C. Glucose
- D. Cellulose
Correct answer: B
Rationale: Glycogen is classified as animal starch, not plant starch. It is the storage form of glucose in animals, primarily found in the liver and muscles. Choice A (Plant starch) is incorrect because glycogen is not derived from plants. Choice C (Glucose) is incorrect as glucose is a monosaccharide and not a type of starch. Choice D (Cellulose) is incorrect as cellulose is a structural polysaccharide found in plant cell walls, not the same as glycogen.
5. What are negatively charged ions called?
- A. Neutrons
- B. Protons
- C. Anions
- D. Cations
Correct answer: C
Rationale: Negatively charged ions are called anions. Anions gain electrons and carry a negative charge, which distinguishes them from cations that are positively charged and neutrons and protons that are subatomic particles found in the nucleus of an atom. Choice A, Neutrons, are neutral subatomic particles found in the nucleus of an atom, not negatively charged ions. Choice B, Protons, are positively charged subatomic particles found in the nucleus of an atom, not negatively charged ions. Choice D, Cations, are positively charged ions that lose electrons, which is opposite to the behavior of negatively charged ions.
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