HESI A2
HESI A2 Chemistry
1. Which of these intermolecular forces would result in the lowest boiling point?
- A. Dipole-dipole interaction
- B. London dispersion force
- C. Keesom interaction
- D. Hydrogen bonding
Correct answer: B
Rationale: The London dispersion force is the weakest intermolecular force among the options provided. These forces are present in all molecules and are caused by temporary fluctuations in electron density, resulting in temporary dipoles. Since London dispersion forces are generally weaker than dipole-dipole interactions, Keesom interactions, and hydrogen bonding, a substance with London dispersion forces as the primary intermolecular force would have the lowest boiling point due to the weaker intermolecular forces holding the molecules together. Dipole-dipole interactions, Keesom interactions, and hydrogen bonding are stronger intermolecular forces compared to London dispersion forces, resulting in higher boiling points for substances that exhibit these interactions.
2. What is the name of the bond formed when two atoms share electrons?
- A. Covalent bond
- B. Ionic bond
- C. Metallic bond
- D. Hydrogen bond
Correct answer: A
Rationale: A covalent bond is formed when two atoms share electrons, creating a stable electron configuration. This sharing allows both atoms to achieve a full outer shell of electrons, leading to a stable molecule. In contrast, an ionic bond involves the transfer of electrons from one atom to another, resulting in the formation of ions with opposite charges. Metallic bonds are formed between metal atoms and involve a 'sea of electrons' that are delocalized and free to move. Hydrogen bonds are a type of intermolecular force, not a true chemical bond, and occur between a hydrogen atom and a highly electronegative atom like oxygen or nitrogen.
3. What are the columns of the periodic table called?
- A. Periods
- B. Families
- C. Groups
- D. Rows
Correct answer: C
Rationale: In the periodic table, columns are referred to as groups, not periods, families, or rows. These groups share similar chemical properties due to the arrangement of elements within each group, which is based on the number of valence electrons. The vertical columns help classify elements with similar characteristics. Periods refer to the rows of the periodic table, while families or groups are the vertical columns.
4. Which of the following is a characteristic of a chemical change?
- A. Change in shape
- B. Production of gas
- C. Melting
- D. Freezing
Correct answer: B
Rationale: The production of gas is a characteristic of a chemical change. During a chemical change, new substances are formed, often with the release or absorption of energy. The production of gas is a significant indicator of a chemical change because it indicates the formation of new compounds through chemical reactions. Choices A, C, and D are not characteristics of chemical changes. Changes in shape, melting, and freezing are physical changes where the substance's identity remains the same, unlike in chemical changes where new substances with different properties are formed.
5. Which of the following is a colligative property of a solution?
- A. Freezing point depression
- B. Viscosity
- C. Surface tension
- D. Boiling point elevation
Correct answer: A
Rationale: A colligative property is a property that depends on the number of solute particles in a solution, not on the identity of the solute particles. Freezing point depression is one such property, where adding a solute to a solvent lowers the freezing point of the solution compared to the pure solvent. This phenomenon occurs because the presence of solute particles disrupts the formation of the regular crystal lattice structure, requiring a lower temperature for solidification to occur. Choices B, C, and D are not colligative properties. Viscosity and surface tension are not dependent on the number of solute particles but on intermolecular forces and molecular interactions. Boiling point elevation is another colligative property, but in this case, the question asked for a colligative property of a solution, making freezing point depression the correct answer.
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