which of these intermolecular forces would have the lowest boiling point

HESI A2

HESI A2 Chemistry

1. Which of these intermolecular forces would result in the lowest boiling point?

A. Dipole-dipole interaction
B. London dispersion force
C. Keesom interaction
D. Hydrogen bonding

Correct answer: B

Rationale: The London dispersion force is the weakest intermolecular force among the options provided. These forces are present in all molecules and are caused by temporary fluctuations in electron density, resulting in temporary dipoles. Since London dispersion forces are generally weaker than dipole-dipole interactions, Keesom interactions, and hydrogen bonding, a substance with London dispersion forces as the primary intermolecular force would have the lowest boiling point due to the weaker intermolecular forces holding the molecules together. Dipole-dipole interactions, Keesom interactions, and hydrogen bonding are stronger intermolecular forces compared to London dispersion forces, resulting in higher boiling points for substances that exhibit these interactions.

2. What is the charge of noble gases?

A. -1
B. 0
C. 1
D. 2

Correct answer: B

Rationale: The correct answer is B: 0. Noble gases have a charge of 0 because they have full valence shells and are inert. This makes them stable and unreactive, resulting in a charge of 0 as they do not readily gain or lose electrons. Choices A, C, and D are incorrect because noble gases do not typically form ions by gaining or losing electrons, so they do not carry a charge of -1, 1, or 2.

3. If fifty-six kilograms of a radioactive substance has a half-life of 12 days, how many days will it take the substance to decay naturally to only 7 kilograms?

A. 8
B. 12
C. 36
D. 48

Correct answer: C

Rationale: To decay from 56 kg to 7 kg, the substance needs to go through 3 half-lives (56 kg ÷ 2 ÷ 2 ÷ 2 = 7 kg). Since each half-life is 12 days, the total time required is 12 days per half-life x 3 half-lives = 36 days. Choice A is incorrect because it does not consider the concept of half-lives. Choice B is incorrect because it represents the duration of a single half-life, not the total time required for the decay. Choice D is incorrect as it does not account for the multiple half-lives needed for the substance to decay from 56 kg to 7 kg.

4. When an acid is added to a base, water and a salt form. What kinds of bonds form in these two compounds?

A. Liquid and metallic
B. Polar and nonpolar covalent
C. Polar covalent and ionic
D. Ionic only

Correct answer: C

Rationale: In water, the bond formed between the oxygen atom and the hydrogen atoms is a polar covalent bond. The oxygen atom attracts the shared electrons more strongly, creating a partial negative charge on the oxygen and a partial positive charge on the hydrogen atoms. In the salt formed, the bond between the metal cation and the nonmetal anion is predominantly an ionic bond. The metal cation donates electrons to the nonmetal anion, resulting in the formation of oppositely charged ions that are held together by electrostatic attractions. Choices A and B are incorrect because water and salts do not form bonds that are liquid and metallic, or polar and nonpolar covalent. Choice D is incorrect as it oversimplifies the types of bonds present in water and salts, failing to differentiate between the covalent bond in water and the ionic bond in the salt.

5. What is 0 K equal to in °C?

A. -300°C
B. -273°C
C. -250°C
D. -200°C

Correct answer: B

Rationale: 0 Kelvin, also known as absolute zero, is equal to -273°C. This is the point at which all molecular motion stops, making it the lowest possible temperature on the Kelvin scale. Choice A (-300°C) is incorrect as it is not the correct conversion of 0 K to °C. Choice C (-250°C) and Choice D (-200°C) are also incorrect as they do not correspond to the accurate conversion of 0 K to °C.