HESI A2
HESI A2 Chemistry
1. Which of these intermolecular forces would result in the lowest boiling point?
- A. Dipole-dipole interaction
- B. London dispersion force
- C. Keesom interaction
- D. Hydrogen bonding
Correct answer: B
Rationale: The London dispersion force is the weakest intermolecular force among the options provided. These forces are present in all molecules and are caused by temporary fluctuations in electron density, resulting in temporary dipoles. Since London dispersion forces are generally weaker than dipole-dipole interactions, Keesom interactions, and hydrogen bonding, a substance with London dispersion forces as the primary intermolecular force would have the lowest boiling point due to the weaker intermolecular forces holding the molecules together. Dipole-dipole interactions, Keesom interactions, and hydrogen bonding are stronger intermolecular forces compared to London dispersion forces, resulting in higher boiling points for substances that exhibit these interactions.
2. Which law states that matter can neither be created nor destroyed during a chemical reaction?
- A. Law of Conservation of Energy
- B. Law of Conservation of Mass
- C. Law of Constant Composition
- D. Law of Multiple Proportions
Correct answer: B
Rationale: The correct answer is B, the Law of Conservation of Mass. This law, formulated by Antoine Lavoisier, states that matter cannot be created or destroyed in a chemical reaction. It is a fundamental principle in chemistry that explains the preservation of mass during chemical reactions, indicating that the total mass of the reactants is equal to the total mass of the products. The other choices are incorrect because: A: The Law of Conservation of Energy states that energy cannot be created or destroyed, not matter. C: The Law of Constant Composition refers to compounds having the same composition by mass regardless of their source or how they were prepared, not about the conservation of matter in reactions. D: The Law of Multiple Proportions describes the ratios in which elements combine to form compounds, not the conservation of mass.
3. If oxygen is in a compound, what would its oxidation number be?
- A. 2
- B. -2
- C. 0
- D. -1
Correct answer: B
Rationale: Oxygen typically has an oxidation number of -2 in compounds because it tends to gain electrons. This is due to its high electronegativity, which leads to oxygen attracting electrons towards itself in a chemical bond. Choice A (2) is incorrect because oxygen doesn't have a +2 oxidation number in compounds. Choice C (0) is incorrect as oxygen rarely has an oxidation number of 0 in compounds. Choice D (-1) is incorrect as oxygen's oxidation number in compounds is typically -2, not -1.
4. Aluminum (Al) has 13 protons in its nucleus. What is the number of electrons in an Al3+ ion?
- A. 16
- B. 13
- C. 10
- D. 3
Correct answer: C
Rationale: Aluminum (Al) has an atomic number of 13, which indicates it normally has 13 electrons to balance the 13 protons in its nucleus. When Al forms an Al3+ ion, it loses 3 electrons to achieve a stable electron configuration. Therefore, the Al3+ ion will have 13 - 3 = 10 electrons. Choice A (16) is incorrect as it doesn't take into account the charge of the Al3+ ion. Choice B (13) is incorrect because the Al3+ ion has lost electrons. Choice D (3) is incorrect as it doesn't reflect the total number of electrons lost by the Al atom to form the Al3+ ion.
5. What can stop the penetration of gamma radiation?
- A. Aluminum foil
- B. Glass
- C. Several feet of concrete
- D. Piece of paper
Correct answer: C
Rationale: Gamma radiation is highly penetrative and requires dense materials to block it effectively. While aluminum foil and glass are not sufficient to stop gamma radiation, several feet of concrete is needed due to its high density and ability to absorb gamma radiation effectively. A piece of paper is too thin and lacks the density required to block gamma radiation, making it an ineffective shield.
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