which of these intermolecular forces would have the lowest boiling point

HESI A2

HESI A2 Chemistry

1. Which of these intermolecular forces would result in the lowest boiling point?

A. Dipole-dipole interaction
B. London dispersion force
C. Keesom interaction
D. Hydrogen bonding

Correct answer: B

Rationale: The London dispersion force is the weakest intermolecular force among the options provided. These forces are present in all molecules and are caused by temporary fluctuations in electron density, resulting in temporary dipoles. Since London dispersion forces are generally weaker than dipole-dipole interactions, Keesom interactions, and hydrogen bonding, a substance with London dispersion forces as the primary intermolecular force would have the lowest boiling point due to the weaker intermolecular forces holding the molecules together. Dipole-dipole interactions, Keesom interactions, and hydrogen bonding are stronger intermolecular forces compared to London dispersion forces, resulting in higher boiling points for substances that exhibit these interactions.

2. Which one is not a hydrocarbon?

A. Methane (CH4)
B. Pyridine (C5H5N)
C. Ethane (C2H6)
D. Propane (C3H8)

Correct answer: B

Rationale: The correct answer is B, Pyridine (C5H5N). Pyridine is not a hydrocarbon because it contains nitrogen (N) in its molecular structure, in addition to carbon (C) and hydrogen (H) atoms. Hydrocarbons consist solely of carbon and hydrogen atoms. Methane (CH4), ethane (C2H6), and propane (C3H8) are all examples of hydrocarbons as they only contain carbon and hydrogen atoms, making them organic compounds known for their combustion properties.

3. What is a mole?

A. 6.02 x 10^23
B. 1.00 x 10^24
C. 6.02 x 10^22
D. 6.02 x 10^25

Correct answer: A

Rationale: A mole is a unit used in chemistry to represent Avogadro's number, which is approximately 6.02 x 10^23. This number corresponds to the number of particles (atoms, molecules, ions) in one mole of a substance. Choice A, 6.02 x 10^23, is the correct answer as it accurately defines a mole. Choices B, C, and D provide values that are not equivalent to Avogadro's number, making them incorrect answers.

4. If electrons are not shared equally in a covalent bond, the bond is what?

A. Polar
B. Non-polar
C. Ionic
D. Hydrogen

Correct answer: A

Rationale: A polar covalent bond occurs when electrons are shared unequally between atoms. In this type of bond, one atom has a stronger pull on the shared electrons, leading to a partial positive and partial negative charge distribution within the molecule. Choice B, non-polar, is incorrect because in non-polar covalent bonds, electrons are shared equally between atoms. Choice C, ionic, is incorrect as ionic bonds involve a transfer of electrons rather than sharing. Choice D, hydrogen, is incorrect as it does not describe the nature of a covalent bond.

5. How many electrons are in a neutral atom of neon?

A. 9
B. 10
C. 11
D. 12

Correct answer: B

Rationale: The atomic number of neon is 10, which represents the number of protons in its nucleus. In a neutral atom, the number of electrons is equal to the number of protons to maintain electrical neutrality. Therefore, a neutral atom of neon contains 10 electrons, matching the 10 protons within the nucleus. Choice A (9 electrons) is incorrect as it doesn't correspond to the atomic number of neon. Choices C (11 electrons) and D (12 electrons) are also incorrect as they do not align with the correct atomic number of neon.