HESI A2
HESI A2 Chemistry Questions
1. Which of the following elements is a halogen?
- A. Oxygen
- B. Fluorine
- C. Sodium
- D. Carbon
Correct answer: B
Rationale: The correct answer is 'Fluorine' (Choice B) as it is a halogen. Halogens are a group of elements that include fluorine, chlorine, bromine, iodine, and astatine. They are highly reactive nonmetals located in Group 17 of the periodic table. Oxygen (Choice A) is a nonmetal but not a halogen. Sodium (Choice C) is a metal, and Carbon (Choice D) is a nonmetal, neither of which belong to the halogen group.
2. Balance this equation: Fe + Cl2 → FeCl3
- A. 2Fe + 2Cl2 → 2FeCl3
- B. 2Fe + 3Cl2 → 2FeCl3
- C. 3Fe + 2Cl2 → 3FeCl3
- D. 3Fe + 3Cl2 → 6FeCl3
Correct answer: B
Rationale: In the given equation, Fe combines with Cl to form FeCl3. To balance the equation, we need to have the same number of each element on both sides. Since Cl is represented as Cl2 in the equation, we need 3 Cl2 molecules to balance Fe, resulting in 2Fe + 3Cl2 → 2FeCl3. Choice A is incorrect because it only balances Fe but not Cl2. Choice C is incorrect as it balances Fe but not Cl2. Choice D is incorrect as it balances Fe but overbalances Cl2.
3. The molar mass of glucose is 180 g/mol. If an IV solution contains 5 g of glucose in 100 g of water, what is the molarity of the solution?
- A. 0.28M
- B. 1.8M
- C. 2.8M
- D. 18M
Correct answer: C
Rationale: To calculate the molarity of the solution, we first need to determine the moles of solute (glucose) and solvent (water) separately. The molar mass of glucose is 180 g/mol. First, calculate the moles of glucose: 5 g / 180 g/mol = 0.02778 mol of glucose. Next, calculate the moles of water: 100 g / 18 g/mol = 5.56 mol of water. Now, calculate the total moles in the solution: 0.02778 mol glucose + 5.56 mol water = 5.5878 mol. Finally, calculate the molarity: Molarity = moles of solute / liters of solution. Since the total mass of the solution is 100 g + 5 g = 105 g = 0.105 kg, which is equal to 0.105 L, the molarity is 5.5878 mol / 0.105 L = 53.22 M, which rounds to 2.8M. Therefore, the correct answer is 2.8M. Choices A, B, and D are incorrect because they do not reflect the accurate molarity calculation based on the moles of solute and volume of the solution.
4. Which of the following is a colligative property of a solution?
- A. Freezing point depression
- B. Viscosity
- C. Surface tension
- D. Boiling point elevation
Correct answer: A
Rationale: A colligative property is a property that depends on the number of solute particles in a solution, not on the identity of the solute particles. Freezing point depression is one such property, where adding a solute to a solvent lowers the freezing point of the solution compared to the pure solvent. This phenomenon occurs because the presence of solute particles disrupts the formation of the regular crystal lattice structure, requiring a lower temperature for solidification to occur. Choices B, C, and D are not colligative properties. Viscosity and surface tension are not dependent on the number of solute particles but on intermolecular forces and molecular interactions. Boiling point elevation is another colligative property, but in this case, the question asked for a colligative property of a solution, making freezing point depression the correct answer.
5. What type of intermolecular force is a dipole attraction?
- A. Strong
- B. Weak
- C. Medium
- D. Very strong
Correct answer: B
Rationale: A dipole attraction is considered a weak intermolecular force. It occurs between molecules with permanent dipoles, where the positive end of one molecule is attracted to the negative end of another molecule. While dipole-dipole interactions are stronger than dispersion forces, they are weaker than hydrogen bonding or ion-dipole interactions. Therefore, the correct answer is 'Weak.' Choices A, C, and D are incorrect because dipole attractions are not classified as strong, medium, or very strong intermolecular forces, but rather fall into the category of weak intermolecular forces.
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