which ion would you expect to dominate in water solutions of bases

HESI A2

Chemistry HESI A2 Practice Test

1. Which ion would you expect to dominate in water solutions of bases?

A. MgCl₂
B. 2HCl
C. H⁺
D. OH⁻

Correct answer: D

Rationale: In water solutions of bases, the dominant ion would be OH⁻ (hydroxide ion). Bases release OH⁻ ions when dissolved in water, increasing the concentration of hydroxide ions and leading to a higher pH. This is in contrast to acids, which release H⁺ ions. Therefore, in water solutions of bases, the presence of OH⁻ ions signifies the basic nature of the solution. Choices A, B, and C are incorrect because MgCl₂ is a salt, 2HCl is a compound consisting of two hydrogen ions and one chloride ion, and H⁺ represents a hydrogen ion typically associated with acids, not bases.

2. Aluminum (Al) has 13 protons in its nucleus. What is the number of electrons in an Al3+ ion?

A. 16
B. 13
C. 10
D. 3

Correct answer: C

Rationale: Aluminum (Al) has an atomic number of 13, which indicates it normally has 13 electrons to balance the 13 protons in its nucleus. When Al forms an Al3+ ion, it loses 3 electrons to achieve a stable electron configuration. Therefore, the Al3+ ion will have 13 - 3 = 10 electrons. Choice A (16) is incorrect as it doesn't take into account the charge of the Al3+ ion. Choice B (13) is incorrect because the Al3+ ion has lost electrons. Choice D (3) is incorrect as it doesn't reflect the total number of electrons lost by the Al atom to form the Al3+ ion.

3. Which of the following elements is the most electronegative?

A. Oxygen
B. Fluorine
C. Nitrogen
D. Sodium

Correct answer: B

Rationale: Fluorine is the most electronegative element on the periodic table. It has the highest electronegativity value, indicating its strong ability to attract electrons in a chemical bond. This property makes it highly reactive, explaining why it is the correct answer in this question. Oxygen and Nitrogen are also electronegative elements, but they are not as electronegative as Fluorine. Sodium, on the other hand, is not electronegative; it is an electropositive element.

4. Why does fluorine have a higher ionization energy than oxygen?

A. Fluorine has a smaller number of neutrons.
B. Fluorine has a larger number of neutrons.
C. Fluorine has a smaller nuclear charge.
D. Fluorine has a larger nuclear charge.

Correct answer: D

Rationale: Fluorine has a higher ionization energy than oxygen because fluorine has a larger nuclear charge. The greater number of protons in the nucleus of fluorine attracts its electrons more strongly, making it harder to remove an electron from a fluorine atom compared to an oxygen atom. Choice A is incorrect as the number of neutrons does not directly affect ionization energy. Choice B is also incorrect for the same reason. Choice C is incorrect because a smaller nuclear charge would result in lower ionization energy, not higher.

5. Which type of chemical bond is the strongest?

A. Ionic
B. Hydrogen
C. Covalent
D. Metallic

Correct answer: C

Rationale: Covalent bonds, especially those formed between non-metals, are the strongest type of chemical bond. In covalent bonds, atoms share electrons, creating a strong bond that requires a significant amount of energy to break. Choice A, ionic bonds, are strong but generally weaker than covalent bonds as they involve the transfer of electrons rather than sharing. Choice B, hydrogen bonds, are relatively weak intermolecular forces, not true chemical bonds. Choice D, metallic bonds, are strong but typically not as strong as covalent bonds. Metallic bonds involve a 'sea of electrons' shared between metal atoms, providing strength but with less directional bonding compared to covalent bonds.