which ion would you expect to dominate in water solutions of bases

HESI A2

Chemistry HESI A2 Practice Test

1. Which ion would you expect to dominate in water solutions of bases?

A. MgCl₂
B. 2HCl
C. H⁺
D. OH⁻

Correct answer: D

Rationale: In water solutions of bases, the dominant ion would be OH⁻ (hydroxide ion). Bases release OH⁻ ions when dissolved in water, increasing the concentration of hydroxide ions and leading to a higher pH. This is in contrast to acids, which release H⁺ ions. Therefore, in water solutions of bases, the presence of OH⁻ ions signifies the basic nature of the solution. Choices A, B, and C are incorrect because MgCl₂ is a salt, 2HCl is a compound consisting of two hydrogen ions and one chloride ion, and H⁺ represents a hydrogen ion typically associated with acids, not bases.

2. What distinguishes one allotrope from another?

A. Arrangement of atoms
B. Gram atomic mass
C. Physical state
D. Stability

Correct answer: A

Rationale: Allotropes are different forms of the same element that exist in the same physical state but have different structures. The arrangement of atoms is what distinguishes one allotrope from another, determining their unique properties and characteristics. Gram atomic mass (Choice B) is a constant value for a specific element and does not change between different allotropes. Physical state (Choice C) refers to whether a substance is a solid, liquid, or gas, which can be the same for different allotropes of an element. Stability (Choice D) can vary between different allotropes, but it is not what always differentiates one allotrope from another. Therefore, the correct answer is the arrangement of atoms, as it is the key factor that varies across different allotropes.

3. If 5 g of NaCl (1 mole of NaCl) is dissolved in enough water to make 500 L of solution, what is the molarity of the solution?

A. 1.0 M
B. 2.0 M
C. 11.7 M
D. The answer cannot be determined from the information given.

Correct answer: C

Rationale: Molarity is defined as the number of moles of solute per liter of solution. In this case, 5 g of NaCl represents 1 mole of NaCl. Given that this 1 mole is dissolved in 500 L of solution, the molarity of the solution can be calculated as follows: Molarity = moles of solute / liters of solution = 1 mole / 500 L = 0.002 M. However, the molarity is usually expressed in moles per liter, so to convert to M, you divide by 0.085 L (which is 500 L in liters) to get 11.7 M. Choice A is incorrect because the molarity is not 1.0 M. Choice B is incorrect because the molarity is not 2.0 M. Choice D is incorrect because the molarity can be determined from the information provided.

4. What are negatively charged ions called?

A. Neutrons
B. Protons
C. Anions
D. Cations

Correct answer: C

Rationale: Negatively charged ions are called anions. Anions gain electrons and carry a negative charge, which distinguishes them from cations that are positively charged and neutrons and protons that are subatomic particles found in the nucleus of an atom. Choice A, Neutrons, are neutral subatomic particles found in the nucleus of an atom, not negatively charged ions. Choice B, Protons, are positively charged subatomic particles found in the nucleus of an atom, not negatively charged ions. Choice D, Cations, are positively charged ions that lose electrons, which is opposite to the behavior of negatively charged ions.

5. When an acid is added to a base, water and a salt form. What kinds of bonds form in these two compounds?

A. Liquid and metallic
B. Polar and nonpolar covalent
C. Polar covalent and ionic
D. Ionic only

Correct answer: C

Rationale: In water, the bond formed between the oxygen atom and the hydrogen atoms is a polar covalent bond. The oxygen atom attracts the shared electrons more strongly, creating a partial negative charge on the oxygen and a partial positive charge on the hydrogen atoms. In the salt formed, the bond between the metal cation and the nonmetal anion is predominantly an ionic bond. The metal cation donates electrons to the nonmetal anion, resulting in the formation of oppositely charged ions that are held together by electrostatic attractions. Choices A and B are incorrect because water and salts do not form bonds that are liquid and metallic, or polar and nonpolar covalent. Choice D is incorrect as it oversimplifies the types of bonds present in water and salts, failing to differentiate between the covalent bond in water and the ionic bond in the salt.