HESI A2
HESI A2 Chemistry Questions
1. Which of the following is a characteristic of a chemical change?
- A. Change in shape
- B. Production of gas
- C. Melting
- D. Freezing
Correct answer: B
Rationale: The production of gas is a characteristic of a chemical change. During a chemical change, new substances are formed, often with the release or absorption of energy. The production of gas is a significant indicator of a chemical change because it indicates the formation of new compounds through chemical reactions. Choices A, C, and D are not characteristics of chemical changes. Changes in shape, melting, and freezing are physical changes where the substance's identity remains the same, unlike in chemical changes where new substances with different properties are formed.
2. The molar mass of some gases is as follows: carbon monoxide—28.01 g/mol; helium—4.00 g/mol; nitrogen—28.01 g/mol; and oxygen—32.00 g/mol. Which would you expect to diffuse most rapidly?
- A. Carbon monoxide
- B. Helium
- C. Nitrogen
- D. Oxygen
Correct answer: B
Rationale: The rate of diffusion is inversely proportional to the molar mass of the gas. Helium has the lowest molar mass among the given gases, making it the lightest and fastest gas to diffuse. Therefore, helium would be expected to diffuse most rapidly compared to carbon monoxide, nitrogen, and oxygen. Carbon monoxide, nitrogen, and oxygen have higher molar masses than helium, so they would diffuse more slowly. Therefore, the correct answer is helium.
3. Which of the following is the weakest intermolecular force?
- A. Dipole interactions
- B. Hydrogen bonding
- C. Van der Waals forces
- D. Dispersion forces
Correct answer: D
Rationale: Dispersion forces, also known as London dispersion forces, are the weakest intermolecular forces. They are temporary attractive forces that occur due to momentary shifts in electron distribution within molecules. While dipole interactions, hydrogen bonding, and Van der Waals forces are stronger intermolecular forces, dispersion forces are the weakest because they arise from short-lived fluctuations in electron density. Dipole interactions involve permanent dipoles in molecules, making them stronger than dispersion forces. Hydrogen bonding is stronger than dipole interactions and involves hydrogen atoms bonded to highly electronegative atoms. Van der Waals forces encompass dipole-dipole interactions and dispersion forces, making them stronger than dispersion forces alone.
4. Which classification best describes B, Si, As, Te, At, Ge, and Sb that form a staircase pattern on the right side of the periodic table?
- A. Metals
- B. Semimetals
- C. Nonmetals
- D. Ultrametals
Correct answer: B
Rationale: B, Si, As, Te, At, Ge, and Sb are located in a staircase pattern on the periodic table's right side. Elements in this region are known as metalloids or semimetals because they exhibit properties of both metals and nonmetals. They possess characteristics of both metallic and non-metallic elements, making them valuable semiconductors with diverse applications in electronics. Choice A is incorrect because these elements are not considered true metals. Choice C is incorrect as these elements do not display typical nonmetal properties exclusively. Choice D, 'Ultrametals,' is not a recognized classification in chemistry and is therefore incorrect.
5. If gas A has four times the molar mass of gas B, you would expect it to diffuse through a plug ___________.
- A. at half the rate of gas B
- B. at twice the rate of gas B
- C. at a quarter the rate of gas B
- D. at four times the rate of gas B
Correct answer: A
Rationale: When comparing the diffusion rates of two gases, according to Graham's law of diffusion, the rate of diffusion is inversely proportional to the square root of the molar mass. If gas A has four times the molar mass of gas B, the square root of the molar masses ratio (4:1) is 2. This means that gas A would diffuse through a plug at half the rate of gas B. Therefore, the correct answer is A, at half the rate of gas B. Choices B, C, and D are incorrect because they do not reflect the correct relationship between the molar masses and the rates of diffusion according to Graham's law.
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